A facile method to construct a 2,4,9-triazaadamantane skeleton and synthesize nitramine derivatives,Organic Chemistry Frontiers

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A facile method to construct a 2,4,9-triazaadamantane skeleton and synthesize nitramine derivatives
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-06-13 00:00:00 , DOI: 10.1039/c7qo00357a
Tianjiao Hou _{1,

2,

3,

4} , Jian Zhang _{1,

2,

3,

4} , Chenjiao Wang _{1,

2,

3,

4} , Jun Luo _{1,

2,

3,

4}

Affiliation

An unusual protocol for a “one-pot” three-step reaction to build a 2,4,9-triazaadamantane skeleton from triallylcarbinol was developed. The design and execution of these tactics are described in detail. Then a novel high energy density compound 2,4,9-trinitro-2,4,9-triazaadamantane-7-yl nitrate was prepared and fully characterized. The results indicate that this compound exhibits high thermal stability and high density (1.840 g cm⁻³).

中文翻译：

构造2,4,9-三氮杂金刚烷骨架并合成硝胺衍生物的简便方法

开发了一种不寻常的协议，可以通过三烯丙基甲醇构建“一锅”三步反应来构建2,4,9-三氮杂金刚烷骨架。详细描述了这些策略的设计和执行。然后制备了一种新型的高能量密度化合物2,4,9-三硝基-2,4,9-三氮杂金刚烷-7-基硝酸盐，并对其进行了充分表征。结果表明该化合物表现出高的热稳定性和高的密度（1.840g cm ^-3）。

更新日期：2017-08-23

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