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Xylomexicanins I and J: Limonoids with Unusual B/C Rings from Xylocarpus granatum
Journal of Natural Products ( IF 5.1 ) Pub Date : 2017-08-22 00:00:00 , DOI: 10.1021/acs.jnatprod.7b00305
Yi-Bing Wu , Ya-Zhen Wang 1 , Zhi-Yu Ni , Xia Qing , Qing-Wen Shi , Françoise Sauriol 2 , Christopher J. Vavricka 3 , Yu-Cheng Gu 4 , Hiromasa Kiyota 5
Affiliation  

Two tetranortriterpenoids with new skeletons, xylomexicanins I and J (1 and 2), were isolated during the investigation of chemical constituents from seeds of the Chinese mangrove, Xylocarpus granatum. Xylomexicanin I (1) is an unprecedented limonoid with bridged B- and C-rings. A biosynthesis pathway for 1 from xylomexicanin F is proposed.

中文翻译:

Xylomexicanins I和J:来自果木的带有异常B / C环的柠檬苦素

在研究红树林种子木果种子化学成分的过程中,分离出了两个具有新骨架的四降三萜类化合物,即木糖喜树碱I和J(12)。Xylomexicanin I(1)是一种前所未有的柠檬苦素,具有桥连的B环和C环。提出了木糖美西宁F的1的生物合成途径。
更新日期:2017-08-22
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