Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2,Chemical Reviews

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Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-08-17 00:00:00 , DOI: 10.1021/acs.chemrev.7b00167
Konstantin P. Bryliakov _{1,

2}

Affiliation

The discovery of simple and efficient catalyst systems for the asymmetric oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this paper, we give an overview of catalyst systems capable of conducting asymmetric oxygenative transformations of organic molecules and, in line with the major trend to sustainability, relying on green oxidants H₂O₂ and O₂ as the ultimate oxygen source. The full historical period of asymmetric oxidation catalysis (1970 to the present day) is covered; both transition-metal-based and organocatalytic systems are considered. The focus of this review is the catalytic properties of the existing catalyst systems, in particular stereoselectivity, activity, efficiency, and synthetic outlook. At the same time, mechanistic peculiarities of stereoselective oxygen transfer are given attention.

中文翻译：

环境良性氧化剂H ₂ O ₂和O ₂催化不对称氧化

对于烃类的不对称氧官能化，发现简单有效的催化剂体系是催化化学的一项艰巨任务。在本文中，我们概述了能够进行有机分子不对称氧化转化的催化剂体系，并根据可持续性发展的主要趋势，依靠绿色氧化剂H ₂ O ₂和O ₂作为最终的氧气源。涵盖了不对称氧化催化的整个历史时期（1970年至今）；基于过渡金属的催化体系和有机催化体系都被考虑在内。本文的重点是现有催化剂体系的催化性能，特别是立体选择性，活性，效率和合成前景。同时，立体选择性氧转移的机械特性受到关注。

更新日期：2017-08-17

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