Click Chemistry in Functional Aliphatic Polycarbonates,Macromolecular Rapid Communications

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Click Chemistry in Functional Aliphatic Polycarbonates
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2017-08-10 , DOI: 10.1002/marc.201700357
Yu Dai ₁ , Xiaojin Zhang ₁ , Fan Xia _{1,

2}

Affiliation

Click chemistry, one of the most important methods in conjugation, plays an extremely significant role in the synthesis of functional aliphatic polycarbonates, which are a group of biodegradable polymers containing carbonate bonds in their main chains. To date, more than 75 articles have been reported on the topic of click chemistry in functional aliphatic polycarbonates. However, these efforts have not yet been highlighted. Six categories of click reactions (alkyne‐azide reaction, thiol‐ene reaction, Michael addition, epoxy‐amine/thiol reaction, Diels‐Alder reaction, and imine formation) that have been afforded for further post‐polymerization modification of polycarbonates are reviewed. Through this review, a comprehensive understanding of functional aliphatic polycarbonates aims to afford insight on the design of polycarbonates for further post‐polymerization modification via click chemistry and the expectation of the practical application.

中文翻译：

功能性脂肪族聚碳酸酯中的点击化学

点击化学是共轭过程中最重要的方法之一，在功能性脂肪族聚碳酸酯的合成中起着极其重要的作用，脂肪族聚碳酸酯是一类可生物降解的聚合物，在其主链中含有碳酸酯键。迄今为止，已经报道了功能性脂族聚碳酸酯中点击化学这一主题的超过75篇文章。但是，这些努力尚未得到强调。审查了六种类型的点击反应（炔烃-叠氮化物反应，硫醇-烯反应，迈克尔加成反应，环氧胺/硫醇反应，狄尔斯-阿尔德反应和亚胺形成），这些反应可用于聚碳酸酯的进一步聚合后改性。通过这次审核，

更新日期：2017-08-10

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