当前位置：
X-MOL 学术
›
Macromol. Rapid Commun.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Supramolecular Polymerization from Controllable Fabrication to Living Polymerization
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2017-07-28 , DOI: 10.1002/marc.201700312 Zehuan Huang 1 , Bo Qin 1 , Linghui Chen 1 , Jiang-Fei Xu 1 , Charl F. J. Faul 2 , Xi Zhang 1
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2017-07-28 , DOI: 10.1002/marc.201700312 Zehuan Huang 1 , Bo Qin 1 , Linghui Chen 1 , Jiang-Fei Xu 1 , Charl F. J. Faul 2 , Xi Zhang 1
Affiliation
|
Supramolecular polymers have attracted plenty of interest in the scientific community; however, developing controllable methods of supramolecular polymerization remains a serious challenge. This article reviews some recent developments of methods for supramolecular polymerization from controllable fabrication to living polymerization. Three facile methods with general applicability for controllable fabrication of supramolecular polymers have been established recently: the first method is a self‐sorting approach by manipulating ring–chain equilibrium based on noncovalent control over rigidity of monomers; the second is covalent polymerization from supramonomers formed by noncovalent interactions; and the third is supramolecular interfacial polymerization. More excitingly, living supramolecular polymerization has been achieved by two elegant strategies, including seeded supramolecular polymerization under pathway complexity control and chain‐growth supramolecular polymerization by metastable monomers. It is anticipated that this review may provide some guidance for precise fabrication of supramolecular polymers, leading to the construction of supramolecular polymeric materials with controllable architectures and functions.
中文翻译：
从可控制的制备到活性聚合的超分子聚合
超分子聚合物引起了科学界的广泛兴趣。然而，开发可控的超分子聚合方法仍然是一个严峻的挑战。本文回顾了从可控制的制备到活性聚合的超分子聚合方法的一些最新进展。最近建立了三种可通用地用于超分子聚合物的可控制制造的简便方法：第一种方法是通过基于对单体刚性的非共价控制来操纵环链平衡的自分选方法。第二种是由非共价相互作用形成的超单体的共价聚合。第三是超分子界面聚合。更令人兴奋的是 活性超分子聚合已通过两种出色的策略实现，包括在路径复杂性控制下的种子超分子聚合和亚稳单体的链增长超分子聚合。预期该综述可以为超分子聚合物的精确制造提供一些指导，从而导致具有可控结构和功能的超分子聚合物材料的构建。
更新日期：2017-07-28
中文翻译：
从可控制的制备到活性聚合的超分子聚合
超分子聚合物引起了科学界的广泛兴趣。然而，开发可控的超分子聚合方法仍然是一个严峻的挑战。本文回顾了从可控制的制备到活性聚合的超分子聚合方法的一些最新进展。最近建立了三种可通用地用于超分子聚合物的可控制制造的简便方法：第一种方法是通过基于对单体刚性的非共价控制来操纵环链平衡的自分选方法。第二种是由非共价相互作用形成的超单体的共价聚合。第三是超分子界面聚合。更令人兴奋的是 活性超分子聚合已通过两种出色的策略实现，包括在路径复杂性控制下的种子超分子聚合和亚稳单体的链增长超分子聚合。预期该综述可以为超分子聚合物的精确制造提供一些指导，从而导致具有可控结构和功能的超分子聚合物材料的构建。
京公网安备 11010802027423号