Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocynaninato quadruple-decker complex,Chemical Communications

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Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocynaninato quadruple-decker complex
Chemical Communications ( IF 4.3 ) Pub Date : 2017-07-10 00:00:00 , DOI: 10.1039/c7cc03553e
Yoji Horii _{1,

2,

3,

4,

5} , Keiichi Katoh _{1,

2,

3,

4,

5} , Brian K. Breedlove _{1,

2,

3,

4,

5} , Masahiro Yamashita _{1,

2,

3,

4,

5}

Affiliation

A clamshell-type terbium(III)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb–Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.

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