Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability,Chemical Communications

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Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability
Chemical Communications ( IF 4.9 ) Pub Date : 2017-07-06 00:00:00 , DOI: 10.1039/c7cc05068b
J. Hynek _{1,

2,

3} , S. Ondrušová _{1,

2,

3} , D. Bůžek _{1,

2,

3} , P. Kovář _{3,

4,

5,

6} , J. Rathouský _{3,

7,

8} , J. Demel _{1,

2,

3}

Affiliation

A zirconium metal–organic framework (MOF) PCN-222 was postsynthetically modified with diphenylphosphinic acid, resulting in an increased stability when activated from water and 4 times higher photosensitizing properties for singlet oxygen production. The phosphinic acid did not compromise the crystallinity of the MOF but made strong bonds with the zirconia secondary building units.

中文翻译：

在无机二级建筑单元中用二苯基次膦酸对锆金属-有机骨架进行后合成修饰，以提高光敏性能和稳定性

锆金属-有机骨架（MOF）PCN-222用二苯基次膦酸进行了后期合成修饰，从水中活化后稳定性提高，单线态氧生产的光敏性能提高了4倍。次膦酸不会损害MOF的结晶度，但会与氧化锆二级结构单元形成牢固的键。

更新日期：2017-07-28

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