Development and photocatalytic mechanism of monolayer Bi2MoO6 nanosheets for the selective oxidation of benzylic alcohols,Chemical Communications

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Development and photocatalytic mechanism of monolayer Bi2MoO6 nanosheets for the selective oxidation of benzylic alcohols
Chemical Communications ( IF 4.3 ) Pub Date : 2017-07-06 00:00:00 , DOI: 10.1039/c7cc04052k
Kaiqiang Jing _{1,

2,

3,

4} , Jinhua Xiong _{1,

2,

3,

4} , Na Qin _{1,

2,

3,

4} , Yujie Song _{1,

2,

3,

4} , Liuyi Li _{2,

3,

4,

5,

6} , Yan Yu _{2,

3,

4,

5,

6} , Shijing Liang _{1,

2,

3,

4} , Ling Wu _{1,

2,

3,

4,

5}

Affiliation

Monolayer Bi₂MoO₆ nanosheets have been successfully prepared for the first time via a bottom-top approach with surfactant assistance, and show 8 times higher activity than bulk Bi₂MoO₆ for the selective oxidation of benzyl alcohol. Ultrafast charge separation and more acid–base active sites on the monolayer nanosheets are considered to be responsible for the robust photoactivity.

中文翻译：

Bi ₂ MoO ₆纳米单分子膜选择性氧化苯甲醇的研究进展及其光催化机理。

单层Bi ₂ MoO ₆纳米片材是通过自底向上方法在表面活性剂的辅助下成功地首次制备的，显示出比本体Bi ₂ MoO ₆高8倍的选择性氧化苄醇的活性。单层纳米片上的超快电荷分离和更多的酸碱活性位点被认为是强大的光活性的原因。

更新日期：2017-07-28

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