We report an enantioselective coupling between alkynes and indoles. A Rh-hydride catalyst isomerizes alkynes to generate a metal-allyl species that can be trapped with both aromatic and heteroaromatic nucleophiles.

中文翻译：

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炔烃氢杂芳基化：通过 Rh-氢化物催化吲哚和炔烃的对映选择性偶联

我们报告了炔烃和吲哚之间的对映选择性偶联。Rh-氢化物催化剂使炔烃异构化以生成金属烯丙基物种，该物种可以被芳香族和杂芳香族亲核试剂捕获。