The reuse of treated wastewater or wastewater-impacted river water is growing, particularly in arid areas, due to the climate change. As well, the disposal of sludges, biosolids or biochar as soil amendments to improve agricultural output is widely implemented in the EU. These practices can be a source of emerging contaminants and engineering nanomaterials (ENMs) to the environment and condition their incorporation to food chain that could affect human beings. This review covers current analytical techniques, instruments and methodologies used to determine emerging contaminants and ENMs from irrigation water and/or soil amendments in plants. Trends regarding sample treatment, separation and detection approaches are addressed. Special emphasis is placed on in-situ characterization of ENMs (e.g. particle size distribution, shape, aggregation state, etc.). We also discuss the advantages and disadvantages of the analytical methods and techniques for determining emerging contaminants and fully ENMs characterization, and cover promising future prospects.

中文翻译：

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从土壤中吸收后分析植物材料中新出现的污染物和纳米材料

由于气候变化，经过处理的废水或受废水影响的河水的回用正在增加，特别是在干旱地区。同样，在欧盟广泛采用污泥，生物固体或生物碳作为土壤改良剂以提高农业产量的处置方法。这些做法可能成为环境中新出现的污染物和工程纳米材料（ENM）的来源，并限制其掺入可能影响人类的食物链中。这篇综述涵盖了当前的分析技术，仪器和方法，这些技术，工具和方法可用于确定植物中灌溉用水和/或土壤改良剂中新出现的污染物和ENM。解决了有关样品处理，分离和检测方法的趋势。特别强调现场ENM的特征（例如粒度分布，形状，聚集状态等）。我们还将讨论确定新兴污染物和完全ENM表征的分析方法和技术的优缺点，并涵盖有希望的未来前景。