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Impact of the Metallic Crystalline Structure on the Properties of Nanocrystals and Their Mesoscopic Assemblies
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2017-07-20 00:00:00 , DOI: 10.1021/acs.accounts.7b00093
Marie-Paule Pileni 1
Affiliation  

The spontaneous assembly of uniform-sized globular entities into ordered arrays is a universal phenomenon observed for objects with diameters spanning a broad range of length scales. These extend from the atomic scale (10–8 cm), through molecular and macromolecular scales with proteins, synthetic low polymers, and colloidal crystals (∼10–6 cm), to the wavelength of visible light (∼10–5 cm). The associated concepts of sphere packing have had an influence in diverse fields ranging from pure geometrical analysis to architectural models or ideals. Self-assembly of atoms, supramolecules, or nanocrystals into ordered functional superstructures is a universal process and prevalent topic in science.

中文翻译:

金属晶体结构对纳米晶体及其介观组装性质的影响

均匀大小的球状实体自发组装成有序阵列是一种普遍现象,对于直径范围很广的长度刻度范围的对象来说,这种现象是普遍存在的。这些范围从原子尺度(10 – 8 cm),到具有蛋白质,合成低聚物和胶体晶体的分子和大分子尺度(约10 6 cm),到可见光的波长(约10 –5 cm)。球体填充的相关概念已在从纯几何分析到建筑模型或理想的各个领域产生了影响。原子,超分子或纳米晶体的自组装成有序的功能上层结构是一个普遍的过程,也是科学界的普遍话题。
更新日期:2017-07-20
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