Quantifying Hydrogen-Bond Populations in Dimethyl Sulfoxide/Water Mixtures,Angewandte Chemie International Edition

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Quantifying Hydrogen-Bond Populations in Dimethyl Sulfoxide/Water Mixtures
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-07-20 04:45:34 , DOI: 10.1002/anie.201706567
Carmen Carrasquilla ₁ , Emily Kapteyn ₁ , Yingfu Li ₁ , John D. Brennan ₁

Affiliation

Water–dimethyl sulfoxide interactions are dissected using IR spectroscopy. In their Communication (DOI: 10.1002/anie.201704162, C. R. Baiz et al. show that hydrogen-bond populations in binary mixtures can be directly quantified and molecular ensembles can be correlated to macroscopic solution properties. The fishes represent DMSO molecules jumping out of the water in groups to portray the strong DMSO–DMSO self-interaction.

中文翻译：

定量二甲基亚砜/水混合物中的氢键数量

水-二甲基亚砜的相互作用使用红外光谱进行了分析。CR Baiz等人在其通讯（DOI：10.1002 / anie.201704162）中显示，可以直接定量二元混合物中的氢键种群，并且可以将分子集合与宏观溶液性质相关。集体浇灌水，以表现出强烈的DMSO–DMSO自相互作用。

更新日期：2017-07-21

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