Nickel‐Catalyzed Intermolecular Carbosulfonylation of Alkynes via Sulfonyl Radicals,Angewandte Chemie International Edition

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Nickel‐Catalyzed Intermolecular Carbosulfonylation of Alkynes via Sulfonyl Radicals
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-07-17 , DOI: 10.1002/anie.201704862
Andrés García‐Domínguez ₁ , Simona Müller ₁ , Cristina Nevado ₁

Affiliation

β,β‐Disubstituted vinyl sulfones were obtained with complete regio‐ and stereocontrol in a multicomponent reaction involving alkynes, organoboronic acids, and sulfonyl chlorides in the presence of a nickel catalyst. The reaction proceeds via sulfonyl radicals generated in situ under mild reaction conditions.

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