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Dissipative out-of-equilibrium assembly of man-made supramolecular materials
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-07-13 00:00:00 , DOI: 10.1039/c7cs00246g Susan A. P. van Rossum 1, 2, 3, 4 , Marta Tena-Solsona 5, 6, 7, 8, 9 , Jan H. van Esch 1, 2, 3, 4 , Rienk Eelkema 1, 2, 3, 4 , Job Boekhoven 5, 6, 7, 8, 9
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-07-13 00:00:00 , DOI: 10.1039/c7cs00246g Susan A. P. van Rossum 1, 2, 3, 4 , Marta Tena-Solsona 5, 6, 7, 8, 9 , Jan H. van Esch 1, 2, 3, 4 , Rienk Eelkema 1, 2, 3, 4 , Job Boekhoven 5, 6, 7, 8, 9
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The use of dissipative self-assembly driven by chemical reaction networks for the creation of unique structures is gaining in popularity. In dissipative self-assembly, precursors are converted into self-assembling building blocks by the conversion of a source of energy, typically a photon or a fuel molecule. The self-assembling building block is intrinsically unstable and spontaneously reverts to its original precursor, thus giving the building block a limited lifetime. As a result, its presence is kinetically controlled, which gives the associated supramolecular material unique properties. For instance, formation and properties of these materials can be controlled over space and time by the kinetics of the coupled reaction network, they are autonomously self-healing and they are highly adaptive to small changes in their environment. By means of an example of a biological dissipative self-assembled material, the unique concepts at the basis of these supramolecular materials will be discussed. We then review recent efforts towards man-made dissipative assembly of structures and how their unique material properties have been characterized. In order to help further the field, we close with loosely defined design rules that are at the basis of the discussed examples.
中文翻译：
人造超分子材料的耗散失衡组装
由化学反应网络驱动的耗散自组装用于形成独特结构的方法正变得越来越流行。在耗散自组装中，前体通过能量源（通常是光子或燃料分子）的转换而转换为自组装的构建基块。自组装构件本质上是不稳定的，并且自发地恢复为其原始前体，因此使构件寿命有限。结果，其存在受到动力学控制，这赋予了相关的超分子材料独特的性能。例如，这些材料的形成和性质可以通过耦合反应网络的动力学在空间和时间上进行控制，它们具有自主自我修复功能，并且高度适应环境中的细微变化。通过生物耗散自组装材料的例子，将讨论基于这些超分子材料的独特概念。然后，我们回顾了最近对人造耗散结构的努力以及如何表征其独特的材料特性。为了进一步帮助该领域，我们以讨论的示例为基础，以松散定义的设计规则作为结尾。
更新日期：2017-07-13
中文翻译：
人造超分子材料的耗散失衡组装
由化学反应网络驱动的耗散自组装用于形成独特结构的方法正变得越来越流行。在耗散自组装中，前体通过能量源（通常是光子或燃料分子）的转换而转换为自组装的构建基块。自组装构件本质上是不稳定的，并且自发地恢复为其原始前体，因此使构件寿命有限。结果，其存在受到动力学控制，这赋予了相关的超分子材料独特的性能。例如，这些材料的形成和性质可以通过耦合反应网络的动力学在空间和时间上进行控制，它们具有自主自我修复功能，并且高度适应环境中的细微变化。通过生物耗散自组装材料的例子，将讨论基于这些超分子材料的独特概念。然后，我们回顾了最近对人造耗散结构的努力以及如何表征其独特的材料特性。为了进一步帮助该领域，我们以讨论的示例为基础，以松散定义的设计规则作为结尾。
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