The self-assembly of small and well-defined molecules using noncovalent interactions to generate various nano- and microarchitectures has been extensively studied. Among various architectures, one-dimensional (1-D) nano-objects have garnered significant attention. It has become increasingly evident that a cooperative or nucleation–elongation mechanism of polymerization leads to highly ordered 1-D supramolecular polymers, analogous to shape-persistent biopolymers such as actin. With this in mind, achieving cooperativity in self-assembled structures has been actively pursued with significant success. Only recently, researchers are focusing on the origin of the mechanism at the molecular level in different synthetic systems. Taking a step further, a thorough quantitative structure–mechanism correlation is crucial to control the size, shape, and functions of supramolecular polymers, and this is currently lacking in the literature.

中文翻译：

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合作规模：苯-1,3,5-三羧酸酰胺自组装的结构-机理相关性

已经广泛研究了使用非共价相互作用产生各种纳米结构和微结构的小分子和自定义分子的自组装。在各种体系结构中，一维（1-D）纳米对象已引起广泛关注。越来越明显的是，聚合的合作或成核-伸长机理导致了高度有序的一维超分子聚合物，类似于形状持久性生物聚合物，如肌动蛋白。考虑到这一点，积极地追求在自组装结构中实现合作性并取得了巨大的成功。直到最近，研究人员才在不同合成系统的分子水平上关注该机理的起源。再往前走，彻底的定量结构与机理的相关性对于控制尺寸，形状，