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Complexes of Ni(I): a “rare” oxidation state of growing importance
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-07-04 00:00:00 , DOI: 10.1039/c7cs00216e Chun-Yi Lin 1, 2, 3, 4 , Philip P. Power 1, 2, 3, 4
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-07-04 00:00:00 , DOI: 10.1039/c7cs00216e Chun-Yi Lin 1, 2, 3, 4 , Philip P. Power 1, 2, 3, 4
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Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as well as in chemical applications such as the catalytic transformation of organic substrates. Despite nickel's importance, the investigation of its compounds in various oxidation states remains uneven and those in the +1 oxidation are less common than those in the neighboring 0 and +2 oxidation states. Nonetheless, in recent years, the volume of work on Ni(I) complexes has increased to the extent that they can be no longer regarded as rare. This review focuses on the syntheses and structures of Ni(I) complexes and shows that they display a range of structures, reactivity and magnetic behavior that places them in the forefront of current nickel chemistry research.
中文翻译：
Ni（I）的络合物：越来越重要的“稀有”氧化态
镍在冶金，磁性和生物学等领域以及化学应用（例如有机底物的催化转化）中发挥着重要作用。尽管镍很重要，但在各种氧化态下对其化合物的研究仍不平衡，+ 1氧化态的化合物比相邻的0和+2氧化态的化合物更不常见。然而，近年来，Ni（I）配合物的工作量已经增加到一定程度，以至于它们不再被认为是稀有的。这篇综述着重于Ni（I）配合物的合成和结构，并表明它们显示出一系列的结构，反应性和磁行为，这使它们处于当前镍化学研究的最前沿。
更新日期：2017-07-05
中文翻译：
Ni（I）的络合物：越来越重要的“稀有”氧化态
镍在冶金，磁性和生物学等领域以及化学应用（例如有机底物的催化转化）中发挥着重要作用。尽管镍很重要，但在各种氧化态下对其化合物的研究仍不平衡，+ 1氧化态的化合物比相邻的0和+2氧化态的化合物更不常见。然而，近年来，Ni（I）配合物的工作量已经增加到一定程度，以至于它们不再被认为是稀有的。这篇综述着重于Ni（I）配合物的合成和结构，并表明它们显示出一系列的结构，反应性和磁行为，这使它们处于当前镍化学研究的最前沿。
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