Click Co sandwich-terminated dendrimers as polyhydride reservoirs and micellar templates,Chemical Communications

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Click Co sandwich-terminated dendrimers as polyhydride reservoirs and micellar templates
Chemical Communications ( IF 4.9 ) Pub Date : 2017-05-19 00:00:00 , DOI: 10.1039/c7cc03311g
Amalia Rapakousiou _{1,

2,

3,

4,

5} , Colette Belin _{1,

2,

3,

4,

5} , Lionel Salmon _{5,

6,

7,

8} , Jaime Ruiz _{1,

2,

3,

4,

5} , Didier Astruc _{1,

2,

3,

4,

5}

Affiliation

Neutral click metallodendrimers with [Co^I(η⁴-cyclopentadiene)(η⁵-cyclopentadienyl)] termini are synthesized by reduction of dendrimers with 9, 27 or 81 cobalticenium termini and serve as polyhydride reservoirs and reductants; for instance, they reduce proton sources to H₂ and Au^III to micellized capsules of gold nanoparticles.

中文翻译：

单击Co夹心终止的树枝状大分子作为多聚体储层和胶束模板

中性点击metallodendrimers用[CO^我（η ⁴环戊二烯）（η ⁵ -环戊二烯基）]末端通过与图9，27或81 cobalticenium末端还原树枝状的合成，并作为polyhydride水库和还原剂; 例如，它们将质子源还原为金纳米颗粒胶束的H ₂和Au ^III。

更新日期：2017-05-27

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