A deciduous directing group approach for the addition of aryl and vinyl nucleophiles to maleimides,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

A deciduous directing group approach for the addition of aryl and vinyl nucleophiles to maleimides
Chemical Communications ( IF 4.3 ) Pub Date : 2017-05-15 00:00:00 , DOI: 10.1039/c7cc02392h
Kiran R. Bettadapur _{1,

2,

3,

4} , Veeranjaneyulu Lanke _{1,

2,

3,

4} , Kandikere Ramaiah Prabhu _{1,

2,

3,

4}

Affiliation

A Rh(III)-catalyzed C–H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally furnish a C_sp²–C_sp³ bond is presented. For the first time, derivatives of acrylic acid have been shown as surrogates for the unstable and expensive alkenyl boronic acids.

中文翻译：