Desorption of CO from individual ruthenium porphyrin molecules on a copper surface via an inelastic tunnelling process,Chemical Communications

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Desorption of CO from individual ruthenium porphyrin molecules on a copper surface via an inelastic tunnelling process
Chemical Communications ( IF 4.3 ) Pub Date : 2017-04-26 00:00:00 , DOI: 10.1039/c7cc01310h
Takuma Omiya _{1,

2,

3,

4,

5} , Paolo Poli _{5,

6,

7,

8} , Heike Arnolds _{5,

6,

7,

8} , Rasmita Raval _{5,

6,

7,

8} , Mats Persson _{5,

6,

7,

8} , Yousoo Kim _{1,

2,

3,

4}

Affiliation

The coordination of CO to metalloporphyrins changes their electronic and magnetic properties. Here we locally desorb CO molecules from a single ruthenium tetraphenylporphyrin carbonyl (CO–RuTPP) on Cu(110) using STM. The desorption is triggered by the injection of holes into the occupied states of the adsorbate using an unusual two-carrier process.

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