Inside Back Cover: Synthesis and Bowl-in-Bowl Assembly of a Geodesic Phenylene Bowl (Angew. Chem. Int. Ed. 23/2017),Angewandte Chemie International Edition

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Inside Back Cover: Synthesis and Bowl-in-Bowl Assembly of a Geodesic Phenylene Bowl (Angew. Chem. Int. Ed. 23/2017)
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-05-03 08:25:31 , DOI: 10.1002/anie.201703999
Koki Ikemoto ₁ , Ryo Kobayashi ₂ , Sota Sato ₁ , Hiroyuki Isobe _{1,

2}

Affiliation

A carbon-rich geodesic dome has been synthesized by linking 20 trigonal planar 1,3,5-linked phenylenes through 25 biaryl linkages. H. Isobe et al. describe in their Communication on page 6511 ff. how the geodesic, corannulenoidal combination of one pentagon and five hexagons leads to the nanometer-sized bowl. Concave–convex molecular recognition results in the formation of a bowl-in-bowl dimer in both the crystalline state and in solution.

中文翻译：

内部封底：测地线苯乙稀碗的合成和碗中组装（Angew。Chem。Int。Ed。23/2017）

通过将20个三角形的平面1,3,5-连接的亚苯基通过25个联芳基连接起来，可以合成出富碳的大地穹顶。H. Isobe等。请参阅第6511页ff的“通讯”中的说明。一个五边形和五个六边形的测地线，环形螺线管组合如何导致纳米尺寸的碗。凹凸的分子识别可导致碗形二聚体在结晶态和溶液态均形成。

更新日期：2017-05-24

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