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3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids
Chemical Communications ( IF 4.3 ) Pub Date : 2017-05-02 00:00:00 , DOI: 10.1039/c7cc02050c
Tonghao Zhu 1, 2, 3, 4 , Shengming Ma 1, 2, 3, 4, 5
Affiliation  

In this communication, we report a palladium-catalyzed decarboxylative allenylation of benzyl carbonates and tert-butyl carbonates of 2,3-allenols with 3-oxocarboxylic acids. The reaction provides a new and straightforward approach to 3,4-dienyl ketones under mild conditions.

中文翻译:

通过3-氧代羧酸的钯催化的脱羧烯丙基化作用的3,4-烷二烯基酮

在此通讯中,我们报告了钯催化的3-氧代羧酸的2,3-烯丙基碳酸苄酯和碳酸丁基碳酸酯的脱羧烯丙基化。该反应在温和条件下为3,4-二烯基酮提供了一种新的直接方法。
更新日期:2017-05-20
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