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In situ control of polymer helicity with a non-covalently bound photoresponsive molecular motor dopant
Chemical Communications ( IF 4.3 ) Pub Date : 2017-05-19 00:00:00 , DOI: 10.1039/c7cc03188b Thomas van Leeuwen , G. Henrieke Heideman , Depeng Zhao , Sander J. Wezenberg , Ben L. Feringa
Chemical Communications ( IF 4.3 ) Pub Date : 2017-05-19 00:00:00 , DOI: 10.1039/c7cc03188b Thomas van Leeuwen , G. Henrieke Heideman , Depeng Zhao , Sander J. Wezenberg , Ben L. Feringa
The transfer of chirality from a molecular motor to a dynamic helical polymer via ionic interactions was investigated. A dopant with photoswitchable chirality was able to induce a preferred helicity in a poly(phenylacetylene) polymer and the helicity is inverted upon irradiation. The findings described herein will advance the development of functional and responsive polymeric systems.
中文翻译:
用非共价键合的光响应分子马达掺杂剂原位控制聚合物的螺旋度
通过离子相互作用研究了手性从分子马达到动态螺旋聚合物的转移。具有光可切换手性的掺杂剂能够在聚(苯乙炔)聚合物中诱导优选的螺旋度,并且在照射时螺旋度被反转。本文所述的发现将促进功能性和响应性聚合物系统的开发。
更新日期:2017-05-19
中文翻译:
用非共价键合的光响应分子马达掺杂剂原位控制聚合物的螺旋度
通过离子相互作用研究了手性从分子马达到动态螺旋聚合物的转移。具有光可切换手性的掺杂剂能够在聚(苯乙炔)聚合物中诱导优选的螺旋度,并且在照射时螺旋度被反转。本文所述的发现将促进功能性和响应性聚合物系统的开发。