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Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly
Journal of the American Chemical Society ( IF 15.0 ) Pub Date : 2017-05-17 , DOI: 10.1021/jacs.7b02208
Daliao Tao 1 , Chun Feng 1 , Yinan Cui 1 , Xian Yang 1 , Ian Manners 2 , Mitchell A. Winnik 3 , Xiaoyu Huang 1
Affiliation  

We report the preparation of a series of fiber-like micelles of narrow length distribution with an oligo(p-phenylenevinylene) (OPV)-core and a poly(N-isopropylacrylamide) (PNIPAM) corona via two different crystallization-driven self-assembly (CDSA) strategies. The average length Ln of these micelles can be varied up to 870 nm by varying the temperature in self-seeding experiments. In addition, seeded growth was employed not only to prepare uniform micelles of controlled length, but also to form fiber-like A-B-A triblock comicelles with an OPV-core.

中文翻译:

通过“活性”结晶驱动自组装,具有低聚(对亚苯基亚乙烯基)核的可控长度和组成的单分散纤维状胶束

我们报告了通过两种不同的结晶驱动自组装制备一系列具有低聚(对亚苯基亚乙烯基)(OPV)核和聚(N-异丙基丙烯酰胺)(PNIPAM)电晕的窄长度分布的纤维状胶束(CDSA) 策略。通过改变自接种实验中的温度,这些胶束的平均长度 Ln 可以变化到 870 nm。此外,种子生长不仅用于制备长度可控的均匀胶束,还用于形成具有 OPV 核心的纤维状 ABA 三嵌段胶束。
更新日期:2017-05-17
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