Hybrid micro-/nano-structures derived from metal–organic frameworks: preparation and applications in energy storage and conversion,Chemical Society Reviews

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Hybrid micro-/nano-structures derived from metal–organic frameworks: preparation and applications in energy storage and conversion
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-04-18 00:00:00 , DOI: 10.1039/c6cs00426a
Xiehong Cao _{1,

2,

3,

4} , Chaoliang Tan _{5,

6,

7,

8,

9} , Melinda Sindoro _{5,

6,

7,

8,

9} , Hua Zhang _{5,

6,

7,

8,

9}

Affiliation

Metal–organic frameworks (MOFs), an important class of inorganic–organic hybrid crystals with intrinsic porous structures, can be used as versatile precursors or sacrificial templates for preparation of numerous functional nanomaterials for various applications. Recent developments of MOF-derived hybrid micro-/nano-structures, constructed by more than two components with varied functionalities, have revealed their extensive capabilities to overcome the weaknesses of the individual counterparts and thus give enhanced performance for energy storage and conversion. In this tutorial review, we summarize the recent advances in MOF-derived hybrid micro-/nano-structures. The synthetic strategies for preparing MOF-derived hybrid micro-/nano-structures are first introduced. Focusing on energy storage and conversion, we then discuss their potential applications in lithium-ion batteries, lithium–sulfur batteries, supercapacitors, lithium–oxygen batteries and fuel cells. Finally, we give our personal insights into the challenges and opportunities for the future research of MOF-derived hybrid micro-/nano-structures.

中文翻译：

从金属-有机框架衍生的混合微/纳米结构：在能量存储和转换中的制备和应用

金属有机骨架（MOF）是一类重要的具有固有多孔结构的无机有机杂化晶体，可以用作制备各种功能性纳米材料的通用前体或牺牲模板。由MOF衍生的混合微/纳米结构的最新发展（由两个以上具有不同功能的组件构成）揭示了其克服单个对应对象的弱点的广泛功能，从而提高了能量存储和转换的性能。在本教程的复习中，我们总结了MOF衍生的混合微/纳米结构的最新进展。首先介绍了制备MOF衍生的混合微/纳米结构的合成策略。专注于储能和转化，然后，我们讨论它们在锂离子电池，锂硫电池，超级电容器，锂氧电池和燃料电池中的潜在应用。最后，我们对MOF衍生的混合微/纳米结构的未来研究提出了挑战和机遇，并提出了自己的见解。

更新日期：2017-05-04

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