Metal–organic and covalent organic frameworks as single-site catalysts,Chemical Society Reviews

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Metal–organic and covalent organic frameworks as single-site catalysts
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-03-24 00:00:00 , DOI: 10.1039/c7cs00033b
S. M. J. Rogge _{1,

2,

3,

4} , A. Bavykina _{5,

6,

7,

8,

9} , J. Hajek _{1,

2,

3,

4} , H. Garcia _{10,

11,

12,

13,

14} , A. I. Olivos-Suarez _{5,

6,

7,

8,

9} , A. Sepúlveda-Escribano _{14,

15,

16,

17,

18} , A. Vimont _{19,

20,

21,

22,

23} , G. Clet _{19,

20,

21,

22,

23} , P. Bazin _{19,

20,

21,

22,

23} , F. Kapteijn _{5,

6,

7,

8,

9} , M. Daturi _{19,

20,

21,

22,

23} , E. V. Ramos-Fernandez _{14,

15,

16,

17,

18} , F. X. Llabrés i Xamena _{10,

11,

12,

13,

14} , V. Van Speybroeck _{1,

2,

3,

4} , J. Gascon _{5,

6,

7,

8,

9}

Affiliation

Center for Molecular Modeling
Ghent University
9052 Zwijnaarde
Belgium
Delft University of Technology
Chemical Engineering Department
Catalysis Engineering
2629 HZ Delft
The Netherlands
Instituto de Tecnología Química UPV-CSIC
Universitat Politècnica de Valencia
Consejo Superior de Investigaciones Científicas
Valencia
Spain
Inorganic Chemistry Department
University Institute of Materials
University of Alicante
Alicante
Normandie Université
ENSICAEN
UNICAEN
CNRS
Laboratoire Catalyse et Spectrochimie

Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.

中文翻译：

金属-有机和共价有机框架作为单中心催化剂

多相单中心催化剂由孤立的，定义明确的活性中心组成，这些活性中心在空间上分隔成给定的固体，理想情况下在结构上是相同的。在这篇综述中，金属-有机骨架（MOFs）和共价有机骨架（COFs）作为开发非均相单中心催化剂的平台的潜力得到了彻底的综述。在本文的第一部分中，讨论了这两类材料中的综合策略以及此类站点的实现进展。由于这些固体是出色的游乐场，可以更好地理解催化功能，因此我们重点介绍了基于这些材料的单中心催化剂的建模和光谱表征方面最重要的最新进展。最后，我们讨论了MOF作为材料的潜力，其中几种单点催化功能可以在一个框架内结合起来，以及它们作为强大的酶模拟材料的潜力。这篇评论总结了我们对未来研究方向的个人见解。

更新日期：2017-05-04

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