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Metal–organic frameworks: functional luminescent and photonic materials for sensing applications
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-05-02 00:00:00 , DOI: 10.1039/c6cs00930a William P. Lustig 1, 2, 3, 4 , Soumya Mukherjee 5, 6, 7, 8 , Nathan D. Rudd 1, 2, 3, 4 , Aamod V. Desai 5, 6, 7, 8 , Jing Li 1, 2, 3, 4 , Sujit K. Ghosh 5, 6, 7, 8
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-05-02 00:00:00 , DOI: 10.1039/c6cs00930a William P. Lustig 1, 2, 3, 4 , Soumya Mukherjee 5, 6, 7, 8 , Nathan D. Rudd 1, 2, 3, 4 , Aamod V. Desai 5, 6, 7, 8 , Jing Li 1, 2, 3, 4 , Sujit K. Ghosh 5, 6, 7, 8
Affiliation
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Metal–organic frameworks (MOFs) or porous coordination polymers (PCPs) are open, crystalline supramolecular coordination architectures with porous facets. These chemically tailorable framework materials are the subject of intense and expansive research, and are particularly relevant in the fields of sensory materials and device engineering. As the subfield of MOF-based sensing has developed, many diverse chemical functionalities have been carefully and rationally implanted into the coordination nanospace of MOF materials. MOFs with widely varied fluorometric sensing properties have been developed using the design principles of crystal engineering and structure–property correlations, resulting in a large and rapidly growing body of literature. This work has led to advancements in a number of crucial sensing domains, including biomolecules, environmental toxins, explosives, ionic species, and many others. Furthermore, new classes of MOF sensory materials utilizing advanced signal transduction by devices based on MOF photonic crystals and thin films have been developed. This comprehensive review summarizes the topical developments in the field of luminescent MOF and MOF-based photonic crystals/thin film sensory materials.
中文翻译：
金属有机框架：用于传感应用的功能性发光和光子材料
金属有机骨架（MOF）或多孔配位聚合物（PCP）是具有多孔小面的开放式晶体超分子配位结构。这些化学可定制的框架材料是广泛而广泛的研究主题，并且在传感材料和设备工程领域特别重要。随着基于MOF的传感子领域的发展，已经将许多不同的化学功能小心地和合理地植入了MOF材料的配位纳米空间中。具有广泛变化的荧光传感特性的MOF是使用晶体工程的设计原理以及结构与属性的关联关系开发的，从而产生了大量且迅速增长的文献。这项工作已导致包括生物分子在内的许多关键传感领域的发展，环境毒素，炸药，离子物质和许多其他物质。此外，已经开发了利用基于MOF光子晶体和薄膜的设备进行的高级信号转导的新型MOF传感材料。这份全面的综述总结了发光MOF和基于MOF的光子晶体/薄膜传感材料领域的主题发展。
更新日期：2017-05-04
中文翻译：
金属有机框架：用于传感应用的功能性发光和光子材料
金属有机骨架（MOF）或多孔配位聚合物（PCP）是具有多孔小面的开放式晶体超分子配位结构。这些化学可定制的框架材料是广泛而广泛的研究主题，并且在传感材料和设备工程领域特别重要。随着基于MOF的传感子领域的发展，已经将许多不同的化学功能小心地和合理地植入了MOF材料的配位纳米空间中。具有广泛变化的荧光传感特性的MOF是使用晶体工程的设计原理以及结构与属性的关联关系开发的，从而产生了大量且迅速增长的文献。这项工作已导致包括生物分子在内的许多关键传感领域的发展，环境毒素，炸药，离子物质和许多其他物质。此外，已经开发了利用基于MOF光子晶体和薄膜的设备进行的高级信号转导的新型MOF传感材料。这份全面的综述总结了发光MOF和基于MOF的光子晶体/薄膜传感材料领域的主题发展。
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