A bidirectional synthesis of spiroacetals via Rh(II)-catalysed C-H insertion,Chemical Communications

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A bidirectional synthesis of spiroacetals via Rh(II)-catalysed C-H insertion
Chemical Communications ( IF 4.3 ) Pub Date : 2017-03-24 00:00:00 , DOI: 10.1039/c7cc00459a
Romain J. Lepage _{1,

2,

3,

4} , Jonathan M. White _{4,

5,

6,

7} , Mark J. Coster _{1,

2,

3,

4}

Affiliation

Acyclic methylene acetals bearing two diazoester subunits have been converted to [5,5]-spiroacetals via bidirectional C-H insertion under Rh(II) catalysis. Using a chiral Rh(II) catalyst, the major diastereomer can be produced...

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