Asymmetric Hydrogenation of Maleic Anhydrides Catalyzed by Rh/Bisphosphine-Thiourea: Efficient Construction of Chiral Succinic Anhydrides,Chemical Communications

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Asymmetric Hydrogenation of Maleic Anhydrides Catalyzed by Rh/Bisphosphine-Thiourea: Efficient Construction of Chiral Succinic Anhydrides
Chemical Communications ( IF 4.9 ) Pub Date : 2017-03-20 00:00:00 , DOI: 10.1039/c7cc01626c
Zhengyu Han _{1,

2,

3,

4} , Rui Wang _{1,

2,

3,

4} , Guoxian Gu _{4,

5,

6,

7} , Xiu-Qin Dong _{1,

2,

3,

4} , Xumu Zhang _{1,

2,

3,

4,

5}

Affiliation

Asymmetric hydrogenation of various 3-substituted maleic anhydrides catalyzed by Rh/bisphosphine-thiourea (ZhaoPhos) under mild conditions was successfully developed. A wide range of 3-alkyl and 3-aryl maleic anhydrides was hydrogenated well to...

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