当前位置：
X-MOL 学术
›
J. Am. Chem. Soc.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2017-03-20 , DOI: 10.1021/jacs.7b01098 Yu Zheng 1 , Yuqi Tan 1 , Klaus Harms 1 , Michael Marsch 1 , Radostan Riedel 1 , Lilu Zhang 1 , Eric Meggers 1
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2017-03-20 , DOI: 10.1021/jacs.7b01098 Yu Zheng 1 , Yuqi Tan 1 , Klaus Harms 1 , Michael Marsch 1 , Radostan Riedel 1 , Lilu Zhang 1 , Eric Meggers 1
Affiliation
|
A novel ruthenium catalyst is introduced which contains solely achiral ligands and acquires its chirality entirely from octahedral centrochirality. The configurationally stable catalyst is demonstrated to catalyze the alkynylation of trifluoromethyl ketones with very high enantioselectivity (up to >99% ee) at low catalyst loadings (down to 0.2 mol%).
中文翻译：
具有独特金属中心手性的八面体钌配合物用于高效不对称催化
介绍了一种新的钌催化剂，它仅包含非手性配体，并完全从八面体中心手性获得手性。结构稳定的催化剂被证明可以在低催化剂负载量（低至 0.2 mol%）下以非常高的对映选择性（高达 > 99% ee）催化三氟甲基酮的炔基化。
更新日期：2017-03-20
中文翻译：
具有独特金属中心手性的八面体钌配合物用于高效不对称催化
介绍了一种新的钌催化剂，它仅包含非手性配体，并完全从八面体中心手性获得手性。结构稳定的催化剂被证明可以在低催化剂负载量（低至 0.2 mol%）下以非常高的对映选择性（高达 > 99% ee）催化三氟甲基酮的炔基化。
京公网安备 11010802027423号