Programmable self-assembly of water-soluble organo-heterometallic cages [M12M'4L12] using 3-(3,5-dimethyl-1H-pyrazol-4-yl)pentane-2,4-dione (H2L),Chemical Communications

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Programmable self-assembly of water-soluble organo-heterometallic cages [M12M'4L12] using 3-(3,5-dimethyl-1H-pyrazol-4-yl)pentane-2,4-dione (H2L)
Chemical Communications ( IF 4.9 ) Pub Date : 2017-03-20 00:00:00 , DOI: 10.1039/c7cc00425g
Zi-Man Chen _{1,

2,

3,

4,

5} , Yu Cui _{1,

2,

3,

4,

5} , Xuan-Feng Jiang _{1,

2,

3,

4,

5} , Jin Tong _{1,

2,

3,

4,

5} , Shu-Yan Yu _{1,

2,

3,

4,

5}

Affiliation

Bifunctional ligand H2L featuring the primary (pyrazole) and secondary (acetylacetone) coordination sites was preferentially reacted with dimetallic [M2(NO3)2](NO3)2 linkers at the pyrazolyl end of H2L, giving rise to dimetallic corners....

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