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Construction of the septahydroxylated ABC-ring system of dihydro-[small beta]-agarofurans: Application of 6-exo-dig radical cyclization
Chemical Communications ( IF 4.9 ) Pub Date : 2017-03-20 00:00:00 , DOI: 10.1039/c7cc00507e
Hiroki Fujisawa 1, 2, 3, 4 , Tomochika Ishiyama 1, 2, 3, 4 , Daisuke Urabe 1, 2, 3, 4 , Masayuki Inoue 1, 2, 3, 4
Affiliation  

A synthetic route to the septahydroxylated ABC-ring system of dihydro-[small beta]-agarofurans was established. The B-ring was formed by a base-promoted diastereoselective Diels-Alder reaction between 3-hydroxy-2-pyrone and a D-glyceraldehyde-derived dienophile, while the...

中文翻译:

二氢-[小β] -agarofurans的间隔羟基化ABC环系统的构建:6-exo-dig自由基环化的应用

建立了二氢-小β-agarofurans的间隔羟基化ABC环系统的合成途径。B环是由3-羟基-2-吡喃酮和D-甘油醛衍生的双亲物之间的碱促进的非对映选择性Diels-Alder反应形成的,而...
更新日期:2017-03-21
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