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Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-03-15 00:00:00 , DOI: 10.1021/acs.chemrev.6b00834 Zachary G Brill 1 , Matthew L Condakes 1 , Chi P Ting 1 , Thomas J Maimone 1
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-03-15 00:00:00 , DOI: 10.1021/acs.chemrev.6b00834 Zachary G Brill 1 , Matthew L Condakes 1 , Chi P Ting 1 , Thomas J Maimone 1
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The pool of abundant chiral terpene building blocks (i.e., “chiral pool terpenes”) has long served as a starting point for the chemical synthesis of complex natural products, including many terpenes themselves. As inexpensive and versatile starting materials, such compounds continue to influence modern synthetic chemistry. This review highlights 21st century terpene total syntheses which themselves use small, terpene-derived materials as building blocks. An outlook to the future of research in this area is highlighted as well.
中文翻译：
探索复杂萜烯天然产物全合成中的手性库
丰富的手性萜烯结构单元（即“手性池萜烯”）长期以来一直是复杂天然产物（包括许多萜烯本身）化学合成的起点。作为廉价且用途广泛的起始材料，此类化合物继续影响着现代合成化学。这篇综述重点介绍了 21 世纪的萜烯全合成，其本身使用小型萜烯衍生材料作为构建模块。还强调了对该领域研究的未来展望。
更新日期：2017-03-15
中文翻译：
探索复杂萜烯天然产物全合成中的手性库
丰富的手性萜烯结构单元（即“手性池萜烯”）长期以来一直是复杂天然产物（包括许多萜烯本身）化学合成的起点。作为廉价且用途广泛的起始材料，此类化合物继续影响着现代合成化学。这篇综述重点介绍了 21 世纪的萜烯全合成，其本身使用小型萜烯衍生材料作为构建模块。还强调了对该领域研究的未来展望。
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