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Coordination-Driven Syntheses of Compact Supramolecular Metallacycles toward Extended Metallo-organic Stacked Supramolecular Assemblies
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2017-03-06 00:00:00 , DOI: 10.1021/acs.accounts.6b00624
Christophe Lescop 1, 2
Affiliation  

One important concept associated with supramolecular chemistry is supramolecular self-assembly, which deals with the way discrete individual components interact via intermolecular interactions in order to build, upon their spontaneous association, high order functional assemblies. The accumulation of these very simple and localized noncovalent interactions (such as H-bonding, dipole–dipole, hydrophobic/hydrophilic, van der Waals, π–π, π–CH, etc.) is ubiquitous in the complexity of natural systems (such as DNA, proteins, membranes, micelles, etc.). It can also be transposed to the directed synthesis of intricate artificial scaffolds, which have anticipated geometries and properties.

中文翻译:

紧凑型超分子金属环向扩展的金属有机堆叠式超分子组装体的配位驱动合成。

与超分子化学有关的一个重要概念是超分子自组装,其涉及离散的单个组分通过分子间相互作用相互作用的方式,以便在其自发缔合时建立高阶功能性组装。这些非常简单和局部的非共价相互作用(例如氢键,偶极-偶极,疏水/亲水,范德华,π–π,π–CH等)的积累在自然系统的复杂性(例如如DNA,蛋白质,膜,胶束等)。也可以将其转换为具有预期几何形状和特性的复杂人工支架的定向合成。
更新日期:2017-03-06
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