Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations,Chemical Reviews

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Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-02-06 00:00:00 , DOI: 10.1021/acs.chemrev.6b00731
Vikram Bhat ₁ , Eric R Welin ₁ , Xuelei Guo ₁ , Brian M Stoltz ₁

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Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.

中文翻译：

2005年至2015年立体会聚催化进展：过渡金属介导的立体消融反应、动态动力学分辨率和动态动力学不对称变换

立体会聚催化是不对称合成的一个重要子集，包括立体烧蚀变换、动态动力学分辨率和动态动力学不对称变换。最初，人们只知道酶可以催化动态动力学过程，但最近已经开发出各种合成催化剂。本综述总结了 2005 年至 2015 年间报道的非酶、过渡金属促进的动态不对称转化的主要进展。

更新日期：2017-02-06

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