Recent Advances in the Chemistry of Pentafulvenes,Chemical Reviews

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Recent Advances in the Chemistry of Pentafulvenes
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-02-02 00:00:00 , DOI: 10.1021/acs.chemrev.6b00210
Preethanuj Preethalayam ₁ , K. Syam Krishnan ₁ , Sreeja Thulasi ₁ , S. Sarath Chand ₁ , Jomy Joseph ₂ , Vijay Nair ₁ , Florian Jaroschik ₂ , K. V. Radhakrishnan ₁

Affiliation

Pentafulvenes are a unique class of compounds that originally attracted attention due to their propensity to display nonbenzenoid aromaticity. Subsequently, they were recognized as valuable synthons for the construction of a wide range of compounds by virtue of their ability to display multiple cycloaddition profiles. Naturally, this area of organic chemistry has experienced rapid growth over the last five decades, fueled by elegant work showcasing the unique reactivity of pentafulvenes in a plethora of cycloaddition reactions. In this Review, we have attempted to provide a systematic account of the methods for the generation of pentafulvenes, their rich and varied cycloaddition chemistry, organometallic reactions, and theoretical studies that support their versatility. Further, we have highlighted their applications in the synthesis of a variety of complex structural frameworks. It is our conviction that this Review will be useful to a wide range of chemists, and will spur further research in this promising area.

中文翻译：

五叶黄酮化学的最新进展

五叶黄酮是一类独特的化合物，由于它们倾向于表现出非苯甲酸酯类芳香性，因此最初引起了人们的注意。随后，由于它们显示多种环加成曲线的能力，它们被认为是用于构建多种化合物的有价值的合成子。自然地，在过去的五十年中，有机化学领域经历了快速的增长，优雅的工作推动了五氟戊烯在大量环加成反应中的独特反应性，从而推动了该领域的发展。在本综述中，我们试图提供系统的方法来解释五碳戊二烯的生成方法，其丰富多样的环加成化学，有机金属反应以及支持其多功能性的理论研究。进一步，我们着重介绍了它们在各种复杂结构框架的综合中的应用。我们相信，本综述对许多化学家都将是有用的，并且将推动这一有前途的领域的进一步研究。

更新日期：2017-02-02

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