当前位置：
X-MOL 学术
›
Chem. Rev.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-01-19 00:00:00 , DOI: 10.1021/acs.chemrev.6b00636 Courtney E Elwell 1 , Nicole L Gagnon 1 , Benjamin D Neisen 1 , Debanjan Dhar 1 , Andrew D Spaeth 1 , Gereon M Yee 1 , William B Tolman 1
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-01-19 00:00:00 , DOI: 10.1021/acs.chemrev.6b00636 Courtney E Elwell 1 , Nicole L Gagnon 1 , Benjamin D Neisen 1 , Debanjan Dhar 1 , Andrew D Spaeth 1 , Gereon M Yee 1 , William B Tolman 1
Affiliation
|
A longstanding research goal has been to understand the nature and role of copper–oxygen intermediates within copper-containing enzymes and abiological catalysts. Synthetic chemistry has played a pivotal role in highlighting the viability of proposed intermediates and expanding the library of known copper–oxygen cores. In addition to the number of new complexes that have been synthesized since the previous reviews on this topic in this journal (Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P. Chem. Rev.2004, 104, 1013–1046 and Lewis, E. A.; Tolman, W. B. Chem. Rev.2004, 104, 1047–1076), the field has seen significant expansion in the (1) range of cores synthesized and characterized, (2) amount of mechanistic work performed, particularly in the area of organic substrate oxidation, and (3) use of computational methods for both the corroboration and prediction of proposed intermediates. The scope of this review has been limited to well-characterized examples of copper–oxygen species but seeks to provide a thorough picture of the spectroscopic characteristics and reactivity trends of the copper–oxygen cores discussed.
中文翻译：
铜氧配合物重温：结构、光谱和反应性
长期的研究目标是了解含铜酶和非生物催化剂中铜氧中间体的性质和作用。合成化学在强调所提出的中间体的可行性和扩大已知铜氧核心库方面发挥了关键作用。除了自本期刊之前关于该主题的评论以来合成的新配合物数量之外（Mirica, LM; Ottenwaelder, X.; Stack, TDP Chem. Rev. 2004, 104, 1013–1046 和 Lewis, EA ; Tolman, WB Chem. Rev. 2004, 104, 1047–1076)，该领域在 (1) 合成和表征的核心范围，(2) 进行的机械工作量方面取得了显着扩展，特别是在有机领域底物氧化，以及（3）使用计算方法来验证和预测所提出的中间体。本综述的范围仅限于铜氧物质的充分表征的例子，但旨在提供所讨论的铜氧核心的光谱特征和反应性趋势的全面图片。
更新日期：2017-01-19
中文翻译：
铜氧配合物重温：结构、光谱和反应性
长期的研究目标是了解含铜酶和非生物催化剂中铜氧中间体的性质和作用。合成化学在强调所提出的中间体的可行性和扩大已知铜氧核心库方面发挥了关键作用。除了自本期刊之前关于该主题的评论以来合成的新配合物数量之外（Mirica, LM; Ottenwaelder, X.; Stack, TDP Chem. Rev. 2004, 104, 1013–1046 和 Lewis, EA ; Tolman, WB Chem. Rev. 2004, 104, 1047–1076)，该领域在 (1) 合成和表征的核心范围，(2) 进行的机械工作量方面取得了显着扩展，特别是在有机领域底物氧化，以及（3）使用计算方法来验证和预测所提出的中间体。本综述的范围仅限于铜氧物质的充分表征的例子，但旨在提供所讨论的铜氧核心的光谱特征和反应性趋势的全面图片。
京公网安备 11010802027423号