个人简介

Assistant Professor of Chemistry. Diploma, 2007, Technical University of Berlin. Ph.D., 2011, University of Wisconsin - Madison. Inorganic Chemistry. Synthetic molecular and supramolecular chemistry. Electrocatalysis. Spectroscopic and magnetic properties of heterometallic systems at various size regimes.

研究领域

Catalysis/Molecular Structure/Supramolecular Chemistry/Synthesis

Our research focuses on inorganic molecular approaches to contribute to the development of novel systems for solar to energy conversion, small molecule activation, and molecules for information storage. Synthetic methods build the foundation of the group and are complimented by a broad array of spectroscopic and electrochemical techniques.

近期论文

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King, A.E.; Nippe, M.; Atanasov, M.; Chantarojsiri, T.; Wray, C.A.; Bill, E.; Neese, F.; Long, J.R.; Chang, C.J. "A Well-​Defined Terminal Vanadium(III) Oxo Complex" Inorg. Chem. 2014, 53, 11388-11395. Demir, S.; Nippe, M.; Gonzalez, M.I.; Long, J.R. "Exchange coupling and magnetic blocking in dilanthanide complexes bridged by the multi-​electron redox-​active ligand 2,​3,​5,​6-​tetra(2-​pyridyl)​pyrazine" Chem. Sci. 2014, 5, 4701-4711. Brogden, D.W.; Turov, Y.; Nippe, M.; Li Manni, G.; Hillard, E.A.; Clerac, R.; Gagliardi, L.; Berry, J.F. "Oxidative Stretching of Metal-​Metal Bonds to Their Limits" Inorg. Chem. 2014, 53, 4777-4790. Khnayzer, R.S.; Thoi, V.S.; Nippe, M.; King, A.E.; Jurss, J.W.; El Roz, K.A.; Long, J.R.; Chang, C.J.; Castellano, F.N. "Towards a comprehensive understanding of visible-​light photogeneration of hydrogen from water using cobalt(ii) polypyridyl catalysts" Energy Environ. Sci. 2014, 7, 1477-1488. Nippe, M.; Khnayzer, R.S.; Panetier, J.A.; Zee, D.Z.; Olaiya, B.S.; Head-Gordon, M.; Chang, C.J.; Castellano, F.N.; Long, J.R. "Catalytic proton reduction with transition metal complexes of the redox-​active ligand bpy2PYMe" Chem. Sci. 2013, 4, 3934-3945. Kashif, M.K.; Nippe, M.; Duffy, N.W.; Forsyth, C.M.; Chang, C.J.; Long, J.R.; Spiccia, L.; Bach, U. "Stable dye-​sensitized solar cell electrolytes based on cobalt(II)​/(III) complexes of a hexadentate pyridyl ligand" Angew. Chem. Int. Ed. 2013, 52, 5527-5531. Demir, S.; Zadrozny, J.M.; Nippe, M.; Long, J.R. "Exchange coupling and magnetic blocking in bipyrimidyl radical-​bridged dilanthanide complexes" J. Am. Chem. Soc. 2012, 134, 18546-18549. Nippe, M.; Goodman, S.M.; Fry, C.G.; Berry, J.F. "Chemically reversible four-​electron oxidation and reduction utilizing two inorganic functional groups" J. Am. Chem. Soc. 2011, 133, 2856-2859. Nippe, M.; Bill, E.; Berry, J.F. "Group 6 Complexes with Iron and Zinc Heterometals: Understanding the Structural, Spectroscopic, and Electrochemical Properties of a Complete Series of MM≡���M' Compounds" Inorg. Chem. 2011, 50, 7650-7661. Nippe, M.; Turov, Y., Berry, J.F. "Remote Effects of Axial Ligand Substitution in Heterometallic CrCr���M Chains" Inorg. Chem. 2011, 50, 10592-10599. Nippe, M.; Wang, J.; Bill, E.; Hope, H.; Dalal, N.S.; Berry, J.F. "Crystals in Which Some Metal Atoms are More Equal Than Others: Inequalities From Crystal Packing and Their Spectroscopic​/Magnetic Consequences" J. Am. Chem. Soc. 2010, 132, 14261-14272. Nippe. M.; Victor, E.; Berry, J.F. "Oxidation Chemistry of Axially Protected Mo2 and W2 Quadruply Bonded Compounds" Inorg. Chem. 2009, 48, 11889-11895. Nippe, M.; Timmer, G.H.; Berry, J.F. "Remarkable regioselectivity in the preparation of the first heterotrimetallic MoW���Cr chain" Chem. Commun. 2009, 4357-4359. Nippe, M.; Victor, E.; Berry, J.F. "Do metal-​metal multiply-​bonded "ligands" have a trans influence? Structural and magnetic comparisons of heterometallic Cr≡Cr���Co and Mo≡Mo���Co interactions" Eur. J. Inorg. Chem. 2008, 5569-5572. Nippe, M.; Berry, J.F. "Introducing a Metal-​Metal Multiply Bonded Group as an "Axial Ligand" to Iron: Synthetic Design of a Linear Cr-​Cr���Fe Framework" J. Am. Chem. Soc. 2007, 129, 12684-12685.