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个人简介

Guo-Xin Jin was born in April 1959. He studied chemistry at Nanjing University and received his M.S. in organic chemistry in 1984 and his Ph.D. degree in inorganic Chemistry in 1987 at the same University. After post-doctor stay at University of Bayreuth with Prof. M.Herberhold (Alexander von Humboldt Fellow) in Germany, in 1996 he joined the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences to start his independent research and became professor. He moved to Shanghai and works in Chemistry Department of Fudan University and become the chair professor in Inorganic Chemistry Institute. Jin also joined the editorial board of some professional journals, such as Coordination Chemistry Reviews, Organometallics, Journal of Organometallic Chemistry, Chinese Journal of Inorganic Chemistry, Chinese Journal of Applied Chemistry and Chinese Science Bulletin. Jin's research interests are catalysts for olefin polymerization and organometallic complexes. He has published more than 300 papers, reviews, and communications, and have 7 US Patents, 41 China Patents.

研究领域

Coordination-Driven Self-assembly Carborane Chemistry Polymerization MOF Material

近期论文

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The Topological Transformation of 41 Knot to 412 Link through Supramolecular Fusion Pan-Pan Hua, Jun-Hua Bai,Hui-Jun Feng,*Jun-Wen Wang,Li-Fang Zhang, and Guo-Xin Jin* J. Am. Chem. Soc. 2024, Synergizing Steric Hindrance and Stacking Interactions to Facilitate the Controlled Assembly of Multiple 41 Metalla-Knots and Pseudo-Solomon Links Yan Zou,+ Shu-Jin Bao,+ Haitong Tang, Hai-Ning Zhang, and Guo-Xin Jin* Angew. Chem. Int. Ed. 2024, e202410722. The codriven assembly of molecular metalla-links (631, 632)and metalla-knots (41, 31) via coordination and noncovalentinteractions Shu-Jin Bao,1 Yan Zou,1 Hai- Ning Zhang, and Guo- Xin Jin* PNAS 2024, 121, e2407570121. The Topological Transformation of Trefoil Knots to Solomon Links via Diels−Alder Click Reaction Haitong Tang, Hai-Ning Zhang, Xiang Gao, Yan Zou, Guo-Xin Jin*DOI: 10.1021/jacs.4c03019 Efficient and Selective Construction of 421 Metalla-links Using Weak C-H···Halogen Interactions Hai-Ning Zhang†, Xi Huang†, Guo-Xin Jin*Angew. Chem. Int. Ed. 2024, 63, e202405399 Selective Construction and Structural Transformation of Homogeneous Linear Metalla[4]catenane and Metalla[2]catenane Assemblies Wei-Long Shan*, Huan-Huan Hou, Nian Si, Cai-Xia Wang, Guozan Yuan, Xiang Gao, Guo-Xin Jin* Angew.Chem.Int.Ed. 2024, 63, DOI:10.1002/anie.202402198 Stereoselective Self-Assembly of Chiral Metalla[2]Catenanes and Lemniscular Macrocycles Shu-Jin Bao, Hai-Ning Zhang, Guo-Xin Jin* CCS Chem. 2024, 6, DOI:10.31635/ccschem.024.202303525. A synthetic strategy of organometallic supramolecular bridged compounds and spirocyclic compounds featuring half-sandwich Cp*Rh units Xiang Gao, Qiu-Shui Mu, Yue-Jian Lin, Guo-Xin Jin* Chinese J. Inorg. Chem. 2024, 40, 164-172. Controllable Topological Transformations of 818 Molecular Metalla-knots via Oxidation of Thiazole-based Ligands Hai-Ning Zhang, Guo-Xin Jin* Angew. Chem. Int. Ed. 2023, 62, e202313605. Selective construction of molecular Solomon links and figure-eight knots by fine-tuning unsymmetrical ligands Qiu-Shui Mu, Xiang Gao, Zheng Cui, Yue-Jian Lin, Guo-Xin Jin* Sci. China. Chem. 2023, 66, 2885-2891. Supramolecular Architectures Bearing Half-Sandwich Iridium- or Rhodium-Based Carboranes: Design, Synthesis, and Applications Peng-Fei Cui, Xin-Ran Liu, Guo-Xin Jin* J. Am. Chem. Soc. 2023, 145, 19440 - 19457. “Cage Walking” Synthetic Strategy for Unusual Unsymmetrical Supramolecular Cages Xin-Ran Liu, Peng-Fei Cui, Shu-Ting Guo, Yue-Jian Lin, Guo-Xin Jin* J. Am. Chem. Soc. 2023, 145, 8569–8575. Selective Synthesis and Structural Transformation of a 4-Ravel Containing Four Crossings and Featuring Cp*Rh/Ir Fragments Li-Long Dang*, Ting-Ting Zhang, Tian Chen, Ying Zhao, Xiang Gao, Francisco Aznarez, Lu-Fang Ma, Guo-Xin Jin* Angew. Chem. Int. Ed. 2023, 62, e2023015. Cation-Templated Assembly of 613 and 623 Metalla-Links Hai-Ning Zhang, Hui-Jun Feng, Yue-Jian Lin, Guo-Xin Jin* J. Am. Chem. Soc. 2023, 145, 4746-4756. Stereoselective Construction of Chiral Linear [3]Catenanes and [2]Catenanes Zheng Cui, Qiu-Shui Mu, Xiang Gao, Guo-Xin Jin* J. Am. Chem. Soc. 2023, 145, 1, 725–731. Organometallic Borromean Rings and [2]Catenanes Featuring Di- NHC Ligands Ye Lu, Patrick D. Dutsc;hke, Jenny Kinas, Alexander Hepp, Guo-Xin Jin, F. Ekkehardt Hahn* Angew. Chem.Int. Ed.2023,e20221768. Selective Construction of Borromean Rings and Tweezer-Like Molecular Assembly Featuring Cp*Rh/Ir Clips for Near-Infrared Photothermal Conversion Yan Zou, Hai-Ning Zhang, Qiu-Shui Mu, Li-Long Dang, Guo-Xin Jin*. Chin. J. Chem. 2023, 41, 3229—3237. Selective Construction Of Molecular Borromean Rings And [2]catenane Utilizing Ether Bipyridyl Ligands Xin Yi, Hai-Ning Zhang, Yue-Jian Lin, Guo-Xin Jin* Chem. Eur. J.2023, e202204038. Pincer-type complexes with B(3)-H selective bond activation of m-carborane Run-Ze Yuan, Peng-Fei Cui, Guo-Xin Jin* J. Organomet. Chem.2023, 122867. Construction of a molecular prime link by interlocking two trefoil knots Zheng Cui, Guo-Xin Jin* Nat. Synth. 2022, 1, 635 - 640.(https://rdcu.be/cPyvF) Synthesis of Carborane-Backbone Metallacycles for Highly Selective Capture of n?Pentane Shu-Ting Guo, Peng-Fei Cui, Xin-Ran Liu, Guo-Xin Jin* J. Am. Chem. Soc. 2022, 144, DOI:10.1021/jacs.2c10201 . Highly Selective Separation of Benzene and Cyclohexane in a Spatially Confined Carborane Metallacage Peng-Fei Cui, Xin-Ran Liu, Yue-Jian Lin, Zhen-Hua Li, Guo-Xin Jin* J. Am. Chem. Soc. 2022, 144, 6558–6565. Stereoselective Self-Assembly of Complex Chiral Radial [5]Catenanes Using Half-Sandwich Rhodium/Iridium Building Blocks Zheng Cui, Xiang Gao, Yue-Jian Lin, Guo-Xin Jin* J. Am. Chem. Soc. 2022, 144, 2379–2386. Highly selective synthesis and near-infrared photothermal conversion of metalla-Borromean ring and [2]catenane assemblies Li-Long Dang, Ting-Ting Li, Ting-Ting Zhang, Ying Zhao, Tian Chen, Xiang Gao, Lu-Fang Ma, Guo-Xin Jin Chem. Sci. 2022, 13, 5130-5140. Octanuclear Palladacycles With B(3)-H Bond Activation of o-Carborane Run-Ze Yuan, Peng-Fei Cui, Yue-Jian Lin, Guo-Xin Jin* Chin. J. Chem. 2022, DOI:10.1002/cjoc.202200622. Rational Design and Integrative Assembly of Heteromeric Metalla[2]Catenanes Featuring Cp*Ir/Rh Fragments Dong Liu, Ye Lu, Yue-Jian Lin, Guo-Xin Jin* Chem. Eur. J. 2022, 28, e202104617. Guest encapsulation and self-assembly of a box-like metalla-rectangle featuring Cp*Rh fragments Dong Liu, Yue-Jian Lin, Guo-Xin Jin* Journal of Organometallic Chemistry 2022, 967, 122353. Synthesis and Near-Infrared Photothermal Conversion of Discrete Supramolecular Topologies Featuring Half-Sandwich [Cp*Rh] Units Xiang Gao, Zheng Cui, Yue-Rong Shen, Dong Liu, Yue-Jian Lin, Guo-Xin Jin* J. Am. Chem. Soc. 2021, 143, 17833 - 17842. An “All-in-One” Synthetic Strategy for Linear Metalla[4]Catenanes Ye Lu,* Dong Liu, Yue-Jian Lin, Zhen-Hua Li, F. Ekkehardt Hahn, Guo-Xin Jin* J. Am. Chem. Soc. 2021, 143, 12404–12411. Stimuli‐Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties Hai-Ning Zhang Wei-Bin Yu Yue-Jian Lin, Guo-Xin Jin* Angew. Chem. Int. Ed. 2021, 60,15466–15471 .(Inside cover) Steric-Effects-Directed B–H Bond Activation of para-Carboranes Peng-Fei Cui, Xin-Ran Liu, Shu-Ting Guo, Yue-Jian Lin, Guo-Xin Jin* J. Am. Chem. Soc. 2021, 143, 13, 5099–5105.Img Selective Construction of Very Large Stacking-Interaction-Induced Molecular 818 Metalla-knots and Borromean Ring Using Curved Dipyridyl Ligands Hai-Ning Zhang, Yue-Jian Lin, Guo-Xin Jin* J. Am. Chem. Soc. 2021, 143, 1119?1125.Img Stepwise B-H Bond Activation of a meta-Carborane Xin-Ran Liu, Peng-Fei Cui, Shu-Ting Guo, Run-Ze Yuan, Guo-Xin Jin* Inorg. Chem. Front. 2021, DOI: 10.1039/D1QI00732G. Same knot, longer rope: altering ligand geometry provides control over nuclearity in self-assembled trefoil knots Qi-Li-Sha Wang, Yue-Jian Lin, Guo-Xin Jin* Chem. Commun. 2021, 57, DOI:10.1039/d1cc03699h. Transition Metal-Mediated B(4)-H Hydroxylation/Halogenation of o-Carboranes Bearing a 2-Pyridylsulfenyl Ligand Shu-Ting Guo, Peng-Fei Cui, Run-Ze Yuan, Guo-Xin Jin* Chem. Commun. 2021, 57, 2412 - 2415.Img Construction of organometallic trefoil knots and one-dimensional chains featuring half-sandwich Cp*Rh corner units and an abnormal zwitterion ligand Xiang Gao, Zheng Cui, Yue-Jian Lin, Guo-Xin Jin* Org. Chem. Front. 2021, 8, 231-238.Img Coordination‐Driven Selective Formation of D2 Symmetric Octanuclear Organometallic Cages Long Zhang*, Yue-Jian Lin, Zhen-Hua Li, J.Fraser Stoddart*, Guo-Xin Jin* Chem. Eur. J. 2021, DOI:10.1002/chem.202101204. Selective Construction of Trefoil knots and a Molecular Borromean Ring Induced by Steric Hindrance of Thioether Ligands Hai-Ning Zhang, Yue-Jian Lin, Guo-Xin Jin* Chem. Asian J. 2021, DOI:10.1002/asia.202100450. Selective construction and stability studies of molecular trefoil knot and Solomon link Li-Long Dang*, Ting-Ting Li, Zheng Cui, Sui Dong, Lufang Ma, Guo-Xin Jin* Dalton Trans. 2021, 50, DOI: 10.1039/D1DT02755G. Regioselective B(3)–H bond activation based on an o-carboranyl dithiocarboxylate ligand and its derivatives Run-Ze Yuan, Peng-Fei Cui, Shu-Ting Guo, Guo-Xin Jin* Dalton Trans. 2021, 50, 1060-1068.Img Rational design and synthesis of interlocked [2]catenanes featuring half-sandwich Cp*Rh/Ir units and pyrene-based ligands Yue-Rong Shen, Xiang Gao, Zheng Cui, Guo-Xin Jin* Chin. J. Chem. 2021, 39, DOI:10.1002/cjoc.202100546. Regioselective B–H/C–H Bond Activation at Azo‐Substituted Carboranes Induced by Half‐Sandwich Iridium(III) Complex Peng‐Fei Cui, Yang Gao, Shu‐Ting Guo, Guo‐Xin Jin* Chin. J. Chem. 2021, 39, 281-287.Img Adaptive Self‐Assembly and Induced‐Fit Interconversions between Molecular Borromean Rings, Russian Dolls and Ring‐in‐Ring Complexes Ye Lu, Dong Liu, Zheng Cui, Yue‐Jian Lin, Guo‐Xin Jin* Chin. J. Chem. 2021, 39, 360-366.Img From Prediction to Realization: Synthesis and X-Ray Characterization of 15- and 16-Vertex closo-Carboranes Peng-Fei Cui, Guo‐Xin Jin* Chem. Res. Chinese. Universities. 2021, DOI:10.1007/s40242-021-0432-z.Img Self-Assembly of Molecular Figure-Eight Knots Induced by Quadruple Stacking Interactions Li-Long Dang, Hui-Jun Feng, Yue-Jian Lin, and Guo-Xin Jin* J. Am. Chem. Soc. 2020, 142, 18946-18954.Img Dihydrogen Bond-Interaction-Induced Separation of Hexane Isomers by Self-Assembled Carborane Metallacycles Peng-Fei Cui, Yue-Jian Lin, Zhen-Hua Li and Guo-Xin Jin* J. Am. Chem. Soc. 2020, 142, 18, 8532-8538.Img Coordination-Directed Construction of Molecular Links Wen-Xi Gao, Hui-Jun Feng, Bei-Bei Guo, Ye Lu and Guo-Xin Jin* Chem. Rev. 2020, 120, 13, 6288-6325.Img Stereoselective Synthesis of a Topologically Chiral Solomon Link Zheng Cui, Ye Lu, Xiang Gao, Hui-Jun Feng and Guo-Xin Jin* J. Am. Chem. Soc. 2020, 142, 32, 13667-13671.Img Self-assembly of metalla[3]catenanes, borromean rings and ring-in-ring complex using a simple π-donor unit Ye Lu, Dong Liu, Yue-Jian Lin, Zhen-Hua Li and Guo-Xin Jin* Nat. Sci. Rev. 2020, 7(10), 1548-1556.Img s-Block Metal Ions Induce Structural Transformations Between Figure-Eight and Double Trefoil Knots Li-Long Dang, Xiang Gao, Yue-Jian Lin and Guo-Xin Jin* Chem. Sci. 2020, 11, 1226-1232. (Cover Article)Img Selective synthesis and structural transformation between a molecular ring-in-ring architecture and an abnormal trefoil knot Li-Long Dang, Xiang Gao, Yue-Jian Lin and Guo-Xin Jin* Chem. Sci. 2020, 11, 8013-8019.Img A Hierarchical Assembly Strategy for Near-Infrared Photothermal Conversion: Unconventional Heterogeneous Metalla[2]catenanes Ye Lu, Dong Liu, Yue-Jian Lin and Guo-Xin Jin* Chem. Sci. 2020, 11, 11509-11513.Img Discrete Supramolecular Stacks based on Multinuclear Tweezer‐Type Rhodium Complexes Bei-Bei Guo, Mohammad Azam, Yue-Jian Lin, Saud I. Al-Resayes and Guo-Xin Jin* Chem. Eur. J. 2020, 26, 558-563. (HOT paper)Img Template-Free Self-Assembly of Molecular Trefoil Knots and Double Trefoil Knots Featuring Cp*Rh Building Blocks Wei-Long Shan, Xiang Gao, Yue-Jian Lin, Guo-Xin Jin* Chem. Eur. J. 2020, 26, 5093-5099.Img A template-free strategy for the synthesis of highly stable trefoil knots Xiang Gao, Bei-Bei Guo, Li-Long Dang, Guo-Xin Jin* J. Organomet. Chem. 2020, 912, 121172. Highly Selective Synthesis of Iridium(III) Metalla[2]catenanes Through Component Pre-Orientation by Pi-Pi Stacking Wei-Long Shan, Yue-Jian Lin, F. Ekkehardt Hahn* and Guo-Xin Jin* Angew. Chem. Int. Ed. 2019, 58, 5882-5886.(Inside Cover)Img Metalloradicals Supported by a meta-Carborane Ligand Peng-Fei Cui, Yang Gao, Shu-Ting Guo, Yue-Jian Lin, Zhen-Hua Li and Guo-Xin Jin* Angew. Chem. Int. Ed. 2019, 58, 8129-8133.Img Coordination-Driven Self-Assembly of a Molecular Figure-Eight Knot and Other Topologically Complex Architectures Li-Long Dang?, Zhen-Bo Sun?, Wei-Long Shan, Yue-Jian Lin, Zhen-Hua Li and Guo-Xin Jin* Nat. Commun. 2019, 10, 2057.Img Supramolecular catalysis based on discrete heterometallic coordination-driven metallacycles and metallacages Wen-Xi Gao, Hai-Ning Zhang and Guo-Xin Jin* Coord. Chem. Rev. 2019, 386, 69-84.Img Covalent Post-assembly Modification Triggers Structural Transformations of Borromean Rings Wen-Xi Gao, Hui-Jun Feng, Yue-Jian Lin and Guo-Xin Jin* J. Am. Chem. Soc. 2019, 141, 9160-9164.(Supplementary Cover)Img Reversibly Structural Transformation between a Molecular Solomon Link and an Unusual Unsymmetrical Trefoil Knot Hai-Ning Zhang, Wen-Xi Gao, Yue-Jian Lin and Guo-Xin Jin* J. Am. Chem. Soc. 2019, 141, 40, 16057-16063.Img Iridium-induced regioselective B–H and C–H activations at azo-substituted m-carboranes: facile access to polynuclear complexes Yang Gao, Shu-Ting Guo, Peng-Fei Cui, Francisco Aznareza and Guo-Xin Jin* Chem. Commun. 2019, 55, 210-213.Img Design and Stability Studies of Trefoil Knots Featuring RhCp* Building Blocks Bei-Bei Guo, Yue-Jian Lin and Guo-Xin Jin* Chem. Eur. J. 2019, 25, 9721-9727.Img Selective Synthesis of Discrete Mono-, Interlocked-, and Borromean Ring Ensembles based on a π-electron deficient ligand Hui-Jun Feng, Wen-Xi Gao, Yue-Jian Lin* and Guo-Xin Jin* Chem. Asian. J. 2019, 14, 2712-2718.Img Donor‐Acceptor [2]- and [3]Catenanes Assembled from Versatile Pre-Organized Cp*Rh/Ir-Directed Pseudo-Rotaxane Tectons Dong Liu, Ye Lu, Yue-Jian Lin and Guo-Xin Jin* Chem. Eur. J. 2019, 25, 14785-14789.Img Dynamic Interconversion between Solomon Link and Trapezoidal Metallacycle Ensembles Accompanying Conformational Change of the Linker Hui-Jun Feng, Wen-Xi Gao, Yue-Jian Lin and Guo-Xin Jin* Chem. Eur. J. 2019, 25, 15687-15693. Molecular Borromean Rings Based on Half-Sandwich Organometallic Rectangles Ye Lu, Hai-Ning Zhang, and Guo-Xin Jin* Acc. Chem. Res. 2018, 51, 2148-2158.Img Stacking-interaction-induced host-guest chemistry and Borromean rings based on a polypyridyl ligand Hai-Ning Zhang, Wen-Xi Gao, Yu-Xin Deng, Yue-Jian Lin, and Guo-Xin Jin* Chem. Commun. 2018, 54, 1559-1562. (Front Cover)Img Iridium-Induced Regioselective B?H and C?C Activations at Azo-Substituted o-Carboranes Yang Gao, Peng-Fei Cui, Francisco Aznarez and Guo-Xin Jin* Chem. Eur. J. 2018, 24, 10357-10363. (Front Cover)Img Selective encapsulation and separation of dihalobenzene isomers with discrete heterometallic macrocages Hai-Ning Zhang, Ye Lu, Wen-Xi Gao, Yue-Jian Lin and Guo-Xin Jin* Chem. Eur. J. 2018, 24, 18913-18921.Img Control of Heterometallic Three-Dimensional Macrocycles with Aromatic Stacks in Tunable Host Cavities Wen-Xi Gao, Qi-Jia Fan, Yue-Jian Lin and Guo-Xin Jin* Chin. J. Chem. 2018, 36, 594-598. (Breaking Report)Img Highly Stable Molecular Borromean Rings Ye Lu, Yue-Jian Lin, Zhen-Hua Li, and Guo-Xin Jin* Chin. J. Chem. 2018, 36, 106-111. (Breaking Report)Img Host-Guest Capability of a Three-Dimensional Heterometallic Macrocycle Qi-Jia Fan, Yue-Jian Lin, F. Ekkehardt Hahn and Guo-Xin Jin* Dalton Trans. 2018, 47, 2240-2246.Img Light-Initiated Reversible Conversion of Macrocyclic Endoperoxides Derived from Half-Sandwich Rhodium-Based Metallarectangles Wei-Long Shan, Wen-Xi Gao, Yue-Jian Lin and Guo-Xin Jin* Dalton Trans. 2018, 47, 2769-2777.Img Construction of half-sandwich rhodium- and iridium-based metallamacrocycles with different space conformations via isomeric pyridyl-substituted ligands Yu-Xin Deng, Hai-Ning Zhang, Yue-Jian Lin and Guo-Xin Jin* J. Coord. Chem. 2018, 71, 1959-1970.Img Controllable assembly of rectangular macrocycles bearing different numbers of unsaturated sites based on half‐sandwich iridium fragments Li-Long Dang, Yue-Jian Lin and Guo-Xin Jin* Dalton Trans. 2018, 47, 6378-6385.Img Synthesis of Heterobimetallic Complexes by Coordination of Rhodium(III) and Iridium(III) Poly-N,O-NHC Complexes to Silver(I), Copper(II), and Zinc(II) Michael Tegethoff, Florian Roelfes, Christian Schulte to Brinke, Tristan Tsai Yuan Tan, Florian Kampert, Guo-Xin Jin* and F. Ekkehardt Hahn* Organometallics, 2018, 37, 1801-1812.Img Construction of half-sandwich multinuclear complexes including tunnel architectures via C–H-activation-directed assembly Bei-Bei Guo, Wen-Xi Gao, Yue-Jian Lin and Guo-Xin Jin* Dalton Trans. 2018, 47, 7701-7708.Img Preparation of polynuclear NHC complexes by post-synthetic modification of half-sandwich rhodium and iridium complexes bearing C-azolato ligands Francisco Aznarez, Wen-Xi Gao, Yue-Jian Lin, F. Ekkehardt Hahn* and Guo-Xin Jin* Dalton Trans. 2018, 47, 9442-9452.Img Regioselective B–H/C–H activation and metal–metal bond formation induced by half-sandwich metals complexes at hydroxy-substituted o-carboranes Shu-Ting Guo, Peng-Fei Cui, Yang Gao, Yue-Jian Lin and Guo-Xin Jin* Dalton Trans. 2018, 47, 13641-13646.Img Rational Design and Self-Assembly of Molecular Squares Featuring Cp*M (M = Rh, Ir) Vertices Bridged by Phenanthroline-Derived Ligands Dong Liu, Yue-Jian Lin, Francisco Aznarez, and Guo-Xin Jin* Cryst. Growth Des. 2018, 18, 6911-6917.

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