个人简介

B.A., Johns Hopkins University (1964); Ph.D., University of California, Los Angeles (1968); NATO Postdoctoral Fellowship, Southampton, England (1968-69); Visiting professorships: Wisconsin (1974), Rennes (1981,1987), Oxford (1982-83), Bordeaux (1989), Toulouse (1989), U.C. Berkeley (1996), Seville (1997), Marburg (2001), MPI Muelheim (2003);Associate Editor, Organometallics, January (1990-1996); ACS Award in Organometallic Chemistry (1992); North Carolina Section ACS Distinguished Speaker Award (1992); ACS A. C. Cope Scholar Award (1994); Japan Society for the Promotion of Science (JSPS) Fellowship (1995); American Academy of Arts and Sciences Fellow, (1996); Medicinal Chemistry Study Section, DRG, NIH (1997-2001); ACS Cooperative Research Award in Polymer Science and Engineering with L. K. Johnson (1998); Charles H. Stone Award (Piedmont Section, ACS) (1998); Royal Society of Chemistry Centenary Lecturer (2000); Honorary Doctorate, University of Rennes, France (2000); Member of National Academy of Sciences (2001); ACS Award in Polymer Chemistry (2003); North Carolina Award in Science (2008), Willard Gibbs Medal (2010); Current Editorial Advisory Boards: Organic Letters, Journal of Polymer Science, Advanced Synthesis and Catalysis

研究领域

Inorganic & Organometallic/Materials/Polymers & Nanoscience

Synthetic Organometallic Chemistry, Catalysis

近期论文

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Findlater, M., Bernskoetter, W. H., Brookhart, M., "Proton-Catalyzed Hydrogenation of a d8 Ir(I) Complex Yields a trans Ir(III) Dihydride", J. Am. Chem. Soc., 2010, 132, 4534-4535. O’Connor, A. R., White, P. S., Brookhart, M., "Synthesis, Characterization, and Reactivity Studies of (Cyclohexenyl)Ni(II) Complexes", Organometallics, 2010, 29, 5382-5389. Huang, Z., White, P. S., Brookhart, M., "Ligand Exchanges and Selective Catalytic Hydrogenation in Molecular Single Crystals", Nature, 2010, 465, 598-601. Park, S., Brookhart, M., "Hydrosilation of Carbonyl-Containing substrates Catalyzed by an Electrophilic η1-Silane Iridium(III) Complex", Organometallics, 2010, 29, 6057-6064. Ahuja, R., Punji, B., Findlater, M., Supplee., C., Schinski, W., Brookhart, M., Goldman, A. S., "Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes", Nature Chemistry, 2011, 3, 167-171. Urbin, S. A., Pintauer, T., White, P., Brookhart, M., "Synthesis, Characterization, and Reactivity of (π-Allyl)Palladium(II) Wrap-Around Complexes with 1,3-Dienes", Inorganica Chimica Acta, 2011, 150-158. (R. G. Bergman tribute issue). Vicente, B. C., Huang, Z., Brookhart, M., Goldman, A. S., Scott, S. L., "Reactions of Phosphinites With Alumina and Silica: A New Method for Anchoring Organic and Organometallic Complexes on Oxide Surfaces", Dalton Trans., 2011, 40, 4268-4274. Park, S., Brookhart, M., "Hydrosilylation of epoxides catalyzed by a cationic η1-silane iridium(III) Complex", Chem. Commun., 2011, 47, 3643-3645. Choi, J., MacArthur, A. H. R., Brookhart, M., Goldman, A. S., "Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes", Chem. Rev., 2011, 1761-1779. Cheng, C., Guironnet, D., Barborak, J., Brookhart, M., "Preparation and characterization of conjugated polymers made by post-polymerization reaction of alternating polyketones", J. Am. Chem. Soc., 2011, 133, 9658-9661. Findlater, M., Cartwright-Sykes, A., White, P. S., Schauer, C. K., Brookhart, M., "Role of Coordination Geometry in Dictating the Barrier to Hydride Migration in d6 Square Pyramidal Iridium and Rhodium Pincer Complexes", J. Am. Chem. Soc., 2011, 133, 12274-12284. Walter, M. D., White, P. S., Schauer, C. K., Brookhart, M., "The Quest for Stable σ-Methane Complexes: Computational and Experimental Studies", New J. Chem., 2011, 35, 2884-2893. Chen, Z., Chuncheng, C., Weinberg, D. R., Kang, P., Concepcion, J. J., Harrison, D. P., Brookhart, M., Meyer, T. J., "Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes", Chem. Commun., 2011, 47, 12607-12609. Cochrane, N. A., Brookhart, M. S., Gagné, M. R., "Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors", Organometallics, 2011, 30, 2457-2460. Park, S., Kim, B. G., Gottker-Schnetmann, I., Brookhart, M., "Redistribution of Trialkyl Silanes Catalyzed by Iridium Silyl Complexes", ACS Catal., 2012, 2, 307-316. Park, S., Brookhart, M., "Development and Mechanistic Investigation of a Highly Efficient Ir(V) Silyl Complex for the Reduction of Tertiary Amides to Amines", J. Am. Chem. Soc., 2012, 134, 640-653. Findlater, M., Schultz, D. M., Bernskoetter, W. H., Cartwright-Sykes, A., Heinekey, D. M., Brookhart, M., "Dihydrogen Complexes of Iridium and Rhodium", Inorg. Chem. 2012, 51, 4672-4678. Kang, P., Cheng, C., Chen, Z., Schauer, C. K., Meyer, T. J., Brookhart, M., "Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes", J. Am. Chem. Soc., 2012, 134, 5500-5503. Cheng, C., Brookhart, M., "Iridium-Catalyzed Reduction of Secondary Amides to Secondary Amines and Imines by Diethylsilane", J. Am. Chem. Soc., 2012, 134, 11304-11307. Biswas, S., Huang, Z., Choliy,Y., Wang, D., Brookhart, M., Krogh-Jespersen, K., Goldman, A. S., "Olefin Isomerization by Iridium Pincer Catalysts. Experimental Evidence for an η3-Ally Pathway And an Unconventional Mechanism Predicted by DFT Calculation", J. Am. Chem. Soc., 2012, submitted. Haibach, M. C., Kundu, S., Brookhart, M., Goldman, A. S., "Alkane Metathesis by Tandem Alkane−Dehydrogenation-Olefin- Metathesis Catalysis and Related Chemistry", Acc. Chem. Res., 2012, 45, 947-958. Cheng, C., Brookhart, M., "Efficient Reduction of Esters to Aldehydes via Iridium-Catalyzed Hydrosilyation", Angewandte Chemie, 2012, 51, 9422-9424. Park, S., Bezier, D., Brookhart, M., " An Efficient Iridium Catalyst for Reduction of Carbon Dioxide to Methane with Trialkylsilanes" J. Am. Chem. Soc., 2012, 134, 11404-11407. Lyons, T. W., Guironnet, D., Findlater, M., Brookhart, M., "Synthesis of p-Xylene from Ethylene", J. Am. Chem. Soc., 2012, 134, 15708-15711. Findlater, M., Choi, J, Goldman, A. S., Brookhart, M., "Alkane Dehydrogenation in Alkane C-H Activation by Single-Site Metal Catalysis", Perez, P. J., Ed.; Springer: New York, 2012, Catalysis By Metal Complexes, Vol. 38. Wingard, L. A., Finnis, M. C., White, P. S., Brookhart, M., Templeton, J. L., "Synthesis, Structure, and Reactivity of Iridium(III) Complexes Containing a 4,6-Dimethyl-1, 3- benzenediphenylimine Pincer Ligand", Inorganic Chemistry, 2013, 52, 515-526. Campos, J., Kundu, S., Pahls, D. R., Brookhart, M., Carmona, E., Cundari, T. R., "Mechanism of Hydrogenolysis of an Iridium-Methyl Bond: Evidence for a Methane Complex Intermediate", J. Am. Chem. Soc., 2013, 135, 1217-1220. Bezier, D., Park, S., Brookhart, M., "Selective Reduction of Carboxylic AcidsTo Aldehydes catalyzed by B(C6F5)3", Organic Letters, 2013, 15, No. 3, 496-499. Walter, M. D., White, P. S., Brookhart, M., "Synthesis, Structure and Computational Studies on a Cationic T-shaped Pd-Complex, New J. Chem., 2013, accepted.