个人简介

(a). Professional Preparation University of Puget Sound Biology B.Sc. 1971 University of Puget Sound Chemistry M.Sc. 1974 University of British Columbia Chemistry Ph.D. 1980 (b). Appointments Professor, University of Rhode Island, Kingston, RI, 2002-present Associate Research Professor, University of Rhode Island, Kingston, RI, 1995-2002 Associate Professor, New Mexico Institute of Mining and Technology, Socorro, NM, 1986-95 Assistant Professor, New Mexico Institute of Mining and Technology, Socorro, NM, 1981-1986 Research Chemist, National Oceanic and Atmospheric Administration, Seattle, WA, 1981 Senior Analytical Chemist, Trace Organics Monitoring Laboratory, Seattle, WA, 1980-81

研究领域

Physical/Analytical

The chemistry of thermal decomposition of highly energetic materials is of primary interest to our research team. These materials are characterized by the extremely rapid release of heat and gas. Among the materials we study are nitramines, nitrate esters, peroxides and energetic salts. Research projects involve identification of decomposition products, analytical chemistry method development, thermodynamic studies and kinetics studies of energetic materials in order to elucidate decomposition mechanisms and evaluate thermal stabilities. Development of quantitative analytical methods is a routine part of our work. We accomplish our objectives using a variety of chemical instruments including gas and liquid chromatrographs, mass spectrometers, NMR and microcalorimeters.

近期论文

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Oxley, J.C.; Smith, J.L.; Junqi, Y.; Moran, J. “Hypergolic Reactions of TNT,” Propellants Explos. Pyrotech. 2009, 34(5), 421-426. Oxley, J.C.; Smith, J.L.; Luo, W; Brady, J. “Determining the Vapor Pressure of Diacetone Diperoxide (DADP) and Hexamethylene Triperoxide Diamine (HMTD), ” Propellants Explos. Pyrotech., 2009, 34(6), 539-543. Oxley, J.C.; Smith, J.L.; Naik, S.; Brady, J. “Determination of Urea Nitrate and Guanidine Nitrate Vapor Pressures by Isothermal Thermogravimetry,” in press Propellants Explos. Pyrotech. Oxley, J.C.; Smith, J.L.; Moran, J.S. “Decomposition of Azo- and Hydrazo-Linked Bis Triazines,” J. Energetic Materials, 2009 27(2), 63-93. Oxley, J.C.; Smith, J.L. Naik, S.; Moran, J.S.; “Decomposition of Urea and Guanidine Nitrate,” J. Energetic Materials, 2009 27(1), 17-39. Oxley, J.C.; Smith, J.L.; Huang, J.; Luo, W. “Destruction of Peroxide Explosives,” J.Forensic Sci., 2009 54(5), 1029-33. Oxley, J.C.; Smith, J.L.; Higgins, C.; Bowden, P.; Moran, J.; Brady, J.; Aziz, C.E.; Cox, E. “Efficiency of Perchlorate Consumption in Road Flares, Propellants and Explosives,” J. Environ. Management, 2009 90(11), 3629-34. Oxley, J.C.; Smith, J.L.; Bernier, E.; Moran, J.S.; Luongo, J. “Hair as Forensic Evidence of Explosive Handling,” Propellants Explos. Pyrotech. 2009 34(4), 307-314. Oxley, J.C.; Smith, J.L.; Moran, J.S.; Canino, J.N.; Almog, J. “Aromatic Nitration using Nitroguanidine and EGDN,” Tetrahedron Lett. 2008 49(28), 4449-4451. Koppes, W.M.; Moran, J.S.; Oxley, J.C.; Smith, J.L.; “Azo Bond Hydrogenation with Hydrazine, RNHNH2, and Hydrazobenzene,” Tetrahedron Lett. 2008 49(20), 3234-3237. Oxley, J.C.; Smith, J.L.; Kirschenbaum, L/J.; Marimganti, S.; Vadlamannati, S.“Detection of Explosives in Hair Using Ion Mobility Spectrometry,” J. Forensic Sci.2008 53(3), 690-693. Oxley, J.; Smith, J.L.; Brady, J.; Dubnikova, F,; Kosloff, R.; Zeiri, L.; Zeiri, Y.; “Raman and Infrared Fingerprint Spectroscopy of Peroxide-Based Explosives,” Applied Spectroscopy 2008 62(8), 906-915. Oxley, J.C.; Smith, J.L.; Buco, R.; Huang, J. “A Study of Reduced-Sensitivity RDX,” J. Energetic Materials, 2007 25(3), 141-160. Oxley, J.C.; Smith, J.L.; Kirshenbaum, L.J.; Marimganti, S. “Accumulation of Explosives in Hair—Part II: Factors Affecting Sorption,” J. Forensic Sci. 2007 52(6), 1291-6.