个人简介

Dr. Metiu obtained his Ph.D. at MIT in 1974. After postdoctoral research at MIT and the University of Chicago, he came to Santa Barbara in 1976. His awards include an Alfred P. Sloan Fellowship (1978), a Camille and Henry Dreyfus Teacher-Scholar Award (1979), the Exxon Solid State Chemistry ACS award (1979), and the UCSB Faculty Research Lectureship (1987). He is a Fellow of the American Physical Society and of the Japan Association for the Promotion of Science.

研究领域

Materials Chemistry/Physical Chemistry/Theory & Computation/Energy/Catalysis & Green Chemistry/Devices/Assembly & Nanochemistry/Structural Chemistry/Spectroscopy & Advanced Analysis

My group is performing quantum mechanical computations and experiments (in collaboration with Professors McFarland, Seshadri, and Stucky) to search for new catalysts for converting natural gas or CO2 into useful chemicals. We are also involved in experimental and computational work to use electrochemistry to find a good system for energy storage.

近期论文

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CO2 methanation by Ru-doped ceria: the role of the oxidation state of the surface, D. Chester Upham, Alan R. Derk, Sudanshu Sharma, Horia Metiu, and Eric W. McFarland, Catalysis Science and Technology (published online 7 January 2015) DOI: 10.1039/c4cy01106 Acid-base interaction and its role in alkane dissociative chemisorption on oxide surfaces, Steeve Chrétien and Horia Metiu, J. Phys. Chem. C 118, 27336 - 27342 (2014) DOI: 10.1021/jp507207b Oxygen adsorption on irreducible oxides doped with higher-valence ions: O2 binding to the dopant, Steeve Chrétien and Horia Metiu, J. Phys. Chem. C 118, 23070 - 23082 (2014) DOI: 10.1021/jp505918e Investigation of the electrocatalytic activity of rhodium sulfide for hydrogen evolution and hydrogen oxidation, Nirala Singh, John Hiller, Horia Metiu, and Eric W. McFarland, Electrochimica Acta 145, 224 - 230 (2014) DOI: 10.1016/j.electacta.2014.09.012 Investigation of the active sites of rhodium sulfide for hydrogen evolution/oxidation using carbon monoxide as a probe, Nirala Singh, David Chester Upham, Ru-Fen Liu, Jonathan Burk, Nick Economou, Steven Buratto, Horia Metiu, and Eric W. McFarland, Langmuir 30, 5662 - 5668 (2014) DOI: 10.1021/la500723y Catalytic oxidation of methanol to formaldehyde by mass-selected vanadium oxide clusters supported on a TiO2(110) surface, Scott P. Price, Xiao Tong, Claron Ridge, Hunter L. Neilson, Joshua W. Buffon, Jeremy Robins, Horia Metiu, Michael T. Bowers, and Steven K. Buratto, J. Phys. Chem. A 118, 8309 - 8313 (2014) DOI: 10.1021/jp5011378 Stable electrocatalysts for autonomous photoelectrolysis of hydrobromic acid using single-junction solar cells, Nirala Singh, Syed Mubeen, Joun Lee, Horia Metiu, Martin Moskovits, and Eric W. McFarland, Energy and Environmental Science 7, 978 - 981 (2014) DOI: 10.1039/C3EE43709 Catalytic dry reforming of methane on ruthenium-doped ceria and ruthenium supported on ceria, Alan R. Derk, George M. Moore, Sudhanshu Sharma, Eric W. McFarland, and Horia Metiu, Topics in Catalysis 57, 118 - 124 (2014) DOI: 10.1007/s11244-013-0167-2 Ethane activation by Nb-doped NiO, XiaoYing Sun, Bo Li, and Horia Metiu, J. Phys. Chem. C 117, 23597 - 23608 (2013) DOI: 10.1021/jp402980d Oxidative dehydrogenation of methane by isolated vanadium oxide clusters supported on Au (111) and Ag (111) surfaces, Jie Yu, Matthias Scheffler, and Horia Metiu, J. Phys. Chem. C 117, 18475 - 18483 (2013) DOI: 10.1021/jp4052962 Gas-phase chemistry to understand electrochemical hydrogen evolution and oxidation on doped transition metal sulfides, Nirala Singh, David Chester Upham, Horia Metiu, and Eric W. McFarland, J. Electrochemical Society 160, A1902 - A1906 (2013) DOI: 10.1149/2.002311jes Interplay between bromine and iodine in oxidative dehydrogenation, Kunlun Ding, Horia Metiu, and Galen D. Stucky, ChemCatChem 5, 1906 - 1910 (2013) DOI: 10.1002/cctc.201200913 Methane dissociation on Li-, Na-, K-, and Cu-doped flat and stepped CaO(001), XiaoYing Sun, Bo Li, and Horia Metiu, J. Phys. Chem. C 117, 7114 - 7122 (2013) DOI: 10.1021/jp4002803 Methane oxidation by lanthanum oxide doped with Cu, Zn, Mg, Fe, Nb, Ti, Zr, or Ta: The connection between the activation energy and the energy of oxygen-vacancy formation, Alan R. Derk, Bo Li, Sudhanshu Sharma, George M. Moore, Eric W. McFarland, and Horia Metiu, Catalysis Letters 143, 406 - 410 (2013) DOI: 10.1007/s10562-013-0985-7 The selective high-yield conversion of methane using iodine-catalyzed methane bromination, Kunlun Ding, Horia Metiu, and Galen D. Stucky, ACS Catalysis 3, 474 - 477 (2013) DOI: 10.1021/cs300775m Catalysis by doped oxides, Eric W. McFarland and Horia Metiu, Chemical Reviews 113, 4391 - 4427 (2013) DOI: 10.1021/cr300418s Transition metal sulfide hydrogen evolution catalysts for hydrobromic acid electrolysis, Anna Ivanovskaya, Nirala Singh, Ru-Fen Liu, Haley Kreutzer, Jonas Baltrusaitis, Trung Van Nguyen, Horia Metiu, and Eric W. McFarland, Langmuir 29, 480 - 492 (2013) DOI: 10.1021/la3032489 Preface: Special Topic Section on Photochemistry at Surfaces, Horia Metiu, J. Chem. Phys. 137, 091501 (2012) DOI: 10.1063/1.4746797 Chemistry of Lewis acid-base pairs on oxide surfaces (Feature Article), Horia Metiu, Steeve Chrétien, Bo Li, Zhenpeng Hu, and Xiao Ying Sun, J. Phys. Chem. C. 116 (19), 10439 - 10450 (2012) DOI: 10.1021/jp301341t Halogen adsorption on CeO2: The role of Lewis acid-base pairing, Zhenpeng Hu and Horia Metiu, J. Phys. Chem. C 116, 6664 - 6671 (2012) DOI: 10.1021/jp211693v