Zhao, Dan - National University of Singapore - Department of Chemical and Biomolecular Engineering

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Zhao, W.; Wang, X. Y.; Bahri, M.; Zhu, Q.; Li, B. Y.; Wu, K.; Wang, Z. K.; Li, H.; Shi, X. S.; Shi, D. C.; Ji, C. Q.; Browning, N. D.; Sun, J. G.; Wang, J.*; Zhao, D.* Water-assisted microwave synthesis of imide-linked covalent organic frameworks in minutes. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.5c01990. Chen, T.; Li, H.; Shi, X. S.; Pu, Y. C.; Zhu, N. X.; Duan, Y. D.; Shi, D. C.; Zhao, W.; Imbrogno, J.; Zhao, D.* Microscopic mechanical force-driven amorphization of metal–organic frameworks. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.5c04101. Dilipkumar, A.; Shukla, A.; Zhao, D.*; Farooq, S.* Adsorption equilibrium and transport of CO2, N2, and H2O in CALF–20. Langmuir 2025, DOI: 10.1021/acs.langmuir.5c00292. Yang, H.; Zhang, H. Y.; Ji, Z. X.; Shi, D. C.; Ji, C. Q.; Yu, K. X.; Kang, C. J.; Zhao, D.* Isomeric separation of C6 alkanes via organic solvent reverse osmosis with covalent organic framework membranes. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.5c04063. Dilipkumar, A.; Shukla, A.; Zhao, D.*; Farooq, S.* Mixture equilibrium and kinetics of flue gas components in CALF-20. Chem. Eng. Sci. 2025, 121663. Wu, K.; Zhao, W.; Huang, L.; Zeng, W.-T.; Zhu, Q.; Wang, H.-B.; Wang, Q.-H.; Shi, X. S.; Li, H.; Lu, W. G.*; Ning, G.-H.*; Zhao, D.*; Li, D.* Aqueous-phase synthesis of cyclic trinuclear cluster-based metal–organic frameworks. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.5c01434. Zheng, H. R.; Ji, J.; Yusran, Y.; Chang, J. H.; Chen, F. Q.; Wang, Z. T.; Suo, J. Q.; Zhang, J.; Li, H.; Zhao, D.; Valtchev, V.; Qiu, S. L.; Fang, Q. R.* Three-dimensional covalent organic frameworks with jcg topology based on a trinodal strategy. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.5c00961. Mohamed, S. A.; Zheng, R.; Zhu, N. X.; Zhao, D.; Jiang, J. W.* A systematic approach for incorporating structural flexibility in high-throughput computational screening of metal–organic frameworks for xylene separation. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.5c01749. Duan, Y. D.; Li, H.; Shi, X. S.; Yu, X.; Zhu, N. X.; Imbrogno, J.; Zhao, D.* Influence of crystal growth on organic liquid phase separation efficiency in polycrystalline PCN-250 membranes. J. Membr. Sci. 2025, 123943. Liu, Q. X.; Ren, J. Y.; Zhang, Z. Q.; Li, H.; Zhu, N. X.; Zhao, D.* Mobile constituent-boosted dynamic separation of C2H2/C2H4/CO2 ternary mixtures in metal–organic frameworks. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.4c15141. Duan, Y. D.; Li, H.; Shi, X. S.; Ji, C. Q.; Imbrogno, J.; Zhao, D.* Stability of metal–organic frameworks in organic media with acids and bases. Ind. Eng. Chem. Res. 2025, DOI: 10.1021/acs.iecr.4c04326. Das, R.; Li, H.; Evans, H. A.; Deng, Z. Y.; Zhao, D.*; Cheetham, A. K.* Hydrophobic metal–formate composites for efficient CO2 capture. J. Am. Chem. Soc. 2025, DOI: 10.1021/jacs.4c16131. Zhang, J.; Zheng, H. R.; Chen, F. Q.; Wang, Z. T.; Li, H.*; Sun, F. X.*; Zhao, D.; Valtchev, V.; Qiu, S. L.; Fang, Q. R.* High-connectivity 3D covalent organic frameworks with pdp net for efficient C2H2/CO2 separation. Angew. Chem. Int. Ed. 2025, e202500161. Yang, Z. Q.; Peh, S. B.; Xi, S. B.; Lu, Y. Q.; Liu, Q. X.; Zhao, D.* Packing engineering of zirconium metal-organic cages in mixed matrix membranes for CO2/CH4 separation. Angew. Chem. Int. Ed. 2025, e202418098. Song, B.; Song, W. T.; Liang, Y. H.; Liu, Y.; Li, B. W.; Li, H.; Zhang, L.; Ma, Y. H.; Ye, R. Q.; Tang, B. Z.; Zhao, D.; Zhou, Y.*; Liu, B.* Direct synthesis of topology-controlled BODIPY and CO2-based zirconium metal-organic frameworks for efficient photocatalytic CO2 reduction. Angew. Chem. Int. Ed. 2025, e202421248. Zhu, N. X.; Wu, J. Y.; Zhao, D.* Nanospace engineering for C8 aromatic isomer separation. ACS Nano 2025, DOI: 10.1021/acsnano.4c15755. Yang, H.; Zhang, H. Y.; Kang, C. J.; Ji, C. Q.; Shi, D. C.; Zhao, D.* Solvent-responsive covalent organic framework membranes for precise and tunable molecular sieving. Sci. Adv. 2024, 10, eads0260. Shi, X. S.; Li, H.; Chen, T.; Ren, J. Y.; Zhao, W.; Patra, B. C.; Kang, C. J.; Zhang, Z. Q.; Zhao, D.* Precise separation of complex ultrafine molecules through solvating two-dimensional covalent organic framework membranes. Angew. Chem. Int. Ed. 2024, e202421661. (Very Important Paper) Li, H.; Zhao, D.* Heat up to catch carbon. Science 2024, 386, 727-728. Feng, Y.; Kang, Z. X.*; Wang, Z. K.; Liu, Z. N.; Niu, Q. J.; Fan, W. D.; Qiao, L.; Pang, J.; Chang, H.; Cui, X. L.; Fan, L. L.; Guo, H. L.; Wang, R. M.; Zhao, D.*; Sun, D. F.* Preprocessed monomer interfacial polymerization for scalable fabrication of high-valent cluster-based metal–organic framework membranes. J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c10241. Ren, J. Y.; Ji, C. Q.; Du, B. W.; Liu, Q. X.; Yu, K. X.; Ahn, D.; Zhang, Z. Y.; Ye, Y. X.; Göb, C. R.; Zhao, D.* A fully saturated covalent organic framework. J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c13256. (Editors’ Choice) Zhao, W.; Obeso, J. L.; López-Cervantes, V. B.; Bahri, M.; Sánchez-González, E.; Amador-Sánchez, Y. A.; Ren, J. Y.; Browning, N. D.; Peralta, R. A.; Barcaro, G.; Monti, S.*; Solis-Ibarra, D.*; Ibarra, I. A.*; Zhao, D.* Achieving sub-ppm sensitivity in SO2 detection with a chemically stable covalent organic framework. Angew. Chem. Int. Ed. 2024, e202415088. Peh, S. B.; Zhao, D. H.; Jiang, J. W.; Farooq, S.*; Zhao, D.* Direct contact TSA cycle based on a hydrophobic MOF sorbent for post-combustion CO2 capture from wet flue gas. Chem. Eng. Sci. 2024, 120744. Qiao, J. Y.; Zhao, D.* Ethane-gated MOFs meet industrial ethylene purification: tiny gates open big possibilities. Matter 2024, 7, 2780-2783. Tran, L. D.; Moore, D. C.; Patra, B. C.; Choi, J.; Hampton, C. M.; Loveday, M. E.; Bhagwandin, D. D.; Renggli, I.; Muratore, C.; Drummy, L. F.; Zhao, D.; Glavin, N. R.*; Baldwin, L. A.* Pore-wall decorated covalent organic frameworks for selective vapor sensing. Adv. Funct. Mater. 2024, 2402208. Shi, X. S.; Li, H.; Chen, T.; Duan, Y. D.; Shi, D. C.; Kang, C. J.; Zhang, Z. Q.; Zhao, D.* Selective liquid-phase molecular sieving via thin metal–organic framework membranes with topological defects. Nat. Chem. Eng. 2024, 1, 483-493. Pu, Y. C.; Zhao, D.* Ultrathin metal-organic framework membranes for molecular separations: a mini-review. Bull. Jpn. Soc. Coord. Chem. 2024, 83, 28-34. Pu, Y. C.; He, G. W.*; Zhao, M. G.; Yang, Z. Q.; Li, H.; Ren, Y. X.; Long, M. Y.; Wang, X. R.; Zhao, D.*; Jiang, Z. Y.* Polymer-functionalized metal-organic framework nanosheet membranes for efficient CO2 capture. J. Membr. Sci. 2024, 707, 123018. Zhao, W.; Zhu, Q.; Wu, X. F.; Zhao, D.* The development of catalysts and auxiliaries for the synthesis of covalent organic frameworks. Chem. Soc. Rev. 2024, DOI: 10.1039/D3CS00908D. Chen, T.; Li, H.; Shi, X. S.; Imbrogno, J.; Zhao, D.* Robust homochiral polycrystalline metal–organic framework membranes for high-performance enantioselective separation. J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c04164. Zhang, Z. Q.; Zhao, D.* Deciphering mechanisms of CO2-selective recognition over acetylene within porous materials. Chem Bio Eng. 2024, DOI: 10.1021/cbe.4c00035. Song, B.; Liang, Y. H.; Zhou, Y.; Zhang, L.; Li, H.; Zhu, N. X.; Tang, B. Z.; Zhao, D.; Liu, B.* CO2-based stable porous metal–organic frameworks for CO2 utilization. J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c03476. Liu, X. M.; Zhao, D.; Wang, J.* Challenges and opportunities in preserving key structural features of 3D-printed metal/covalent organic framework. Nano-Micro Lett. 2024, 16, 157. Shi, X. S.; Zhao, D.* Mastering the mass production of metal–organic framework membranes. Nat. Water 2024, DOI: 10.1038/s44221-023-00189-z. Liu, Y. T.; Chen, L. Y.; Yang, L. F.; Lan, T. H.; Wang, H.; Hu, C. H.; Han, X.; Liu, Q. X.; Chen, J. F.; Feng, Z. M.; Cui, X. L.; Fang, Q. R.; Wang, H. L.; Li, L. B.*; Li, Y. W.*; Xing, H. B.*; Yang, S. H.*; Zhao, D.*; Li, J. P.* Porous framework materials for energy & environment relevant applications: a systematic review. Green Energy Environ. 2024, 9, 217-310. Evans, H. A.*; Yildirim, T.; Peng, P.; Cheng, Y. Q.; Deng, Z. Y.; Zhang, Q.; Mullangi, D.; Zhao, D.; Canepa, P.; Breunig, H. M.; Cheetham, A. K.; Brown, C. M. ALF. Neutron News 2024, 35, 11-12. Ji, C. Q.; Kang, C. J.; Patra, B. C.; Zhao, D.* Flexible covalent organic frameworks: design, synthesis, and applications. CCS Chem. 2023, DOI: 10.31635/ccschem.023.202303415. Bui, T. D.; Chen, W. D.; Islam, M. R.; Zhao, D.; Chua, K. J.* Studying the performance of a pilot scale vacuum-based membrane dehumidifier. Appl. Energy 2023, 351, 121907. Zhao, Y.; Zhang, H. Y.; Ye, H. L.; Zhao, D.*; Lee, J. Y.*; Huang, L. M.* Phosphorous-based heterostructure for the effective catalysis of polysulfide reactions with phase changes in high-sulfur-loading lithium–sulfur batteries. Small Methods 2023, 2300610. Hu, P.; Hu, J. L.; Zhu, M.; Xiong, C.; Krishna, R.; Zhao, D.*; Ji, H. B.* Induced-fit-identification in a rigid metal-organic framework for ppm-level CO2 removal and ultra-pure CO enrichment. Angew. Chem. Int. Ed. 2023, 62, e202305944. Evans, H. A.*; Yildirim, T.*; Peng, P.; Cheng, Y. Q.; Deng, Z. Y.; Zhang, Q.; Mullangi, D.; Zhao, D.; Canepa, P.; Breunig, H. M.; Cheetham, A. K.; Brown, C. M.* Hydrogen storage with aluminum formate, ALF: experimental, computational, and technoeconomic studies. J. Am. Chem. Soc. 2023, 145, 22150-22157. (News in Science) Yang, Z. Q.; Zhao, D.* Ultrathin membranes to sieve gases. Science 2023, 381, 1288-1289. Chen, T.; Zhao, D.* Post-synthetic modification of metal-organic framework-based membranes for enhanced molecular separations. Coord. Chem. Rev. 2023, 491, 215259. Choi, J.; Kim, T.; Li, H.; Jung, H.-T.; Zhao, D.* Gas sensors with two-dimensional rGO@COF composite materials for fast NO2 detection under room temperature. ACS Appl. Mater. Interfaces 2023, 15, 44119-44126. Zhao, Y.; Huang, L. M.*; Zhao, D.*; Lee, J. Y.* Fast polysulfide conversion catalysis and reversible anode operation by a single cathode modifier in Li-metal anode-free lithium-sulfur batteries. Angew. Chem. Int. Ed. 2023, 62, e202308976. Shi, D. C.; Li, H.; Yu, X.; Zhang, Z. Q.; Yuan, Y. D.; Fan, W. D.; Yuan, H. Y.; Ying, Y. P.; Yang, H.; Shang, C. N.; Imbrogno, J.; Zhao, D.* Intercrystalline channels at subnanometer scale for precise molecular nanofiltration. J. Am. Chem. Soc. 2023, 145, 15848-15858. Zhang, Z. Q.; Chen, Y. L.; Chai, K. G.; Kang, C. J.; Peh, S. B.; Li, H.; Ren, J. Y.; Shi, X. S.; Han, X.; Dejoie, C.; Day, S. J.; Yang, S. H.*; Zhao, D.* Temperature-dependent rearrangement of gas molecules in ultramicroporous materials for tunable adsorption of CO2 and C2H2. Nat. Commun. 2023, 14, 3789. Ying, Y. P.*; Wang, D. C.; Zhao, D.* Two-dimensional material-based membranes for gas separation: current status and future direction. Curr. Opin. Chem. Eng. 2023, 40, 100918. Zhang, Z. Q.; Deng, Z. Y.; Evans, H. A.; Mullangi, D.; Kang, C. J.; Peh, S. B.; Wang, Y. X.; Brown, C. M.; Wang, J.; Canepa, P.*; Cheetham, A. K.*; Zhao, D.* Exclusive recognition of CO2 from hydrocarbons by aluminum formate with hydrogen-confined pore cavities. J. Am. Chem. Soc. 2023, 145, 11643-11649. Pu, Y. C.; Zhao, M. G.; Liang, X.; Wang, S. Y.; Wang, H. J.; Zhu, Z. T.; Ren, Y. X.; Zhang, Z. M.; He, G. W.*; Zhao, D.*; Jiang, Z. Y.* Growing ZIF-8 seeds on charged COF substrates toward efficient propylene-propane separation membranes. Angew. Chem. Int. Ed. 2023, 62, e202302355. Yang, H.; Xu, J. H.; Cao, H.; Wu, J.*; Zhao, D.* Recovery of homogeneous photocatalysts by covalent organic framework membranes. Nat. Commun. 2023, 14, 2726. Yuan, H. Y.*; Li, K. R.; Shi, D. C.; Yang, H.; Yu, X.; Fan, W. D.; Buenconsejo, P. J. S.; Zhao, D.* Large-area fabrication of ultrathin metal-organic framework membranes. Adv. Mater. 2023, 35, 2211859. Yang, F. X.; Cui, F. Y.; Yuan, Y. D.; Yu, X.; Zhao, D.* Mechanistic insights into the role of nanoparticles towards the enhanced performance of thin-film nanocomposite membranes. J. Membr. Sci. Lett. 2023, 3, 100046. Mullangi, D.; Evans, H. A.*; Yildirim, T.; Wang, Y. X.; Deng, Z. Y.; Zhang, Z. Q.; Mai, T. T.; Wei, F. X.; Wang, J.; Hight Walker, A. R.; Brown, C. M.; Zhao, D.*; Canepa, P.*; Cheetham, A. K.* Noncryogenic air separation using aluminum formate Al(HCOO)3 (ALF). J. Am. Chem. Soc. 2023, 145, 9850-9856. Kang, C. J.; Zhang, Z. Q.; Kusaka, S.; Negita, K.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, Y. X.; Zou, X. D.; Huang, Z. H.*; Matsuda, R.*; Zhao, D.* Covalent organic framework atropisomers with multiple gas-triggered structural flexibilities. Nat. Mater. 2023, 22, 636-643. Yang, Z. Q.; Wu, Z. J.; Peh, S. B.; Ying, Y. P.; Yang, H.; Zhao, D.* Mixed-matrix membranes containing porous materials for gas separation: from metal–organic frameworks to discrete molecular cages. Engineering 2023, 23, 40-55. Peh, S. B.; Farooq, S.*; Zhao, D.* Techno-economic analysis of MOF-based adsorption cycles for postcombustion CO2 capture from wet flue gas. Chem. Eng. Sci. 2023, 268, 118390. Kang, C. J.; Zhang, Z. Q.; Xi, S. B.; Li, H.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, Y. X.; Zhao, D.* Insertion of CO2 in metal ion-doped two-dimensional covalent organic frameworks. Proc. Natl. Acad. Sci. U. S. A. 2023, 120, e2217081120. Liu, G. L.*; Cai, Y. H.; Yuan, H. Y.; Zhang, J. L.; Zhang, Z. M.*; Zhao, D.* Mesh membranes coated with zirconium metal-organic framework nanosheets of optimized morphology for oil-water separation. J. Membr. Sci. 2023, 668, 121077. Chen, F. Q.; Huang, X. L.; Yang, L.; Zhang, Z. G.; Yang, Q. W.; Yang, Y. W.; Zhao, D.*; Ren, Q. L.; Bao, Z. B.* Boosting xenon adsorption with record capacity in microporous carbon molecular sieves. Sci. China Chem. 2023, 66, 601-610. Li, H.; Dilipkumar, A.; Abubakar, S.; Zhao, D.* Covalent organic frameworks for CO2 capture: from laboratory curiosity to industry implementation. Chem. Soc. Rev. 2023, 52, 6294-6329. Ren, J. Y.; Zhao, D.* Recent advances in reticular chemistry for clean energy, global warming, and water shortage solutions. Adv. Funct. Mater. 2023, 2307778. Yang, H.; Zhang, H. Y.; Zhao, D.* Functional covalent organic framework films based on surface and interfacial chemistry for molecular separations. Langmuir 2023, 39, 20-27. (Invited Perspective) Dong, J. Q.*; Wee, V.; Zhao, D.* Stimuli-responsive metal–organic frameworks enabled by intrinsic molecular motion. Nat. Mater. 2022, 21, 1334-1340. Zhao, Y.; Ye, H. L.; Zhang, H. Y.; Zhao, D.; Huang, L. M.*; Lee, J. Y.* The beneficial effects of black phosphorous modification of the anode current collector in Li-metal free Li2S-based batteries. Mater. Today Energy 2022, 30, 101179. Zhang, B.; Chen, H. W.; Jiang, L. M.; Shen, Y. Q.; Zhao, D.; Zhou, Z. X.* A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning. Chin. J. Chem. Eng. 2022, 52, 95-102. Zhang, Z. Q.; Peh, S. B.; Kang, C. J.; Yu, K. X.; Zhao, D.* Efficient splitting of alkane isomers by a bismuth-based metal-organic framework with auxetic reentrant pore structures. Angew. Chem. Int. Ed. 2022, 61, e202211808. (Inside Back Cover, Hot Paper) Evans, H. A.; Mullangi, D.; Deng, Z. Y.; Wang, Y. X.; Peh, S. B.; Wei, F. X.; Wang, J.; Brown, C. M.; Zhao, D.*; Canepa, P.*; Cheetham, A. K.* Aluminum formate, Al(HCOO)3: an earth-abundant, scalable, and highly selective material for CO2 capture. Sci. Adv. 2022, 8, eade1473. Kang, C. J.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Chai, K. G.; Wang, Y. X.; Zhao, D.* Tunable interlayer shifting in two-dimensional covalent organic frameworks triggered by CO2 sorption. J. Am. Chem. Soc. 2022, 144, 20363-20371. Hu, Z. G.*; Wang, Y. X.; Zhao, D.* Modulated hydrothermal chemistry of metal–organic frameworks. Acc. Mater. Res. 2022, 3, 1106-1114. (Supplementary Cover) Zhang, Z. Q.; Kang, C. J.; Peh, S. B.; Shi, D. C.; Yang, F. X.; Liu, Q. X.; Zhao, D.* Efficient adsorption of acetylene over CO2 in bioinspired covalent organic frameworks. J. Am. Chem. Soc. 2022, 144, 14992-14996. Dong, J. Q.*; Zhao, D.* Porous and permutable peptide frameworks. Nat. Chem. 2022, 14, 852-854. Chen, F. Q.; Huang, X. L.; Guo, K. Q.; Yang, L.; Sun, H. R.; Xia, W.; Zhang, Z. G.; Yang, Q. W.; Yang, Y. W.; Zhao, D.; Ren, Q. L.; Bao, Z. B.* Molecular sieving of propylene from propane in metal–organic framework-derived ultramicroporous carbon adsorbents. ACS Appl. Mater. Interfaces 2022, 14, 30443-30453. Zhao, J.; Ying, Y. P.; Wang, G. L.*; Hu, K. D.; Yuan, Y. D.; Ye, H. L.; Liu, Z. L.; Lee, J. Y.*; Zhao, D.* Covalent organic framework film protected zinc anode for highly stable rechargeable aqueous zinc-ion batteries. Energy Storage Mater. 2022, 48, 82-89. Ying, Y. P.; Peh, S. B.; Yang, H.; Yang, Z. Q.; Zhao, D.* Ultrathin covalent organic framework membranes via a multi-interfacial engineering strategy for gas separation. Adv. Mater. 2022, 34, 2104946. (Back Cover, Editor’s Choice, Invited Contribution in the Special Issue “Materials Science in Singapore”) El-Sayed, E.-S. M.; Yuan, Y. D.; Zhao, D.*; Yuan, D. Q.* Zirconium metal–organic cages: synthesis and applications. Acc. Chem. Res. 2022, 55, 1546-1560. (Supplementary Cover) Wang, D. C.; Ying, Y. P.; Zheng, Y. P.; Pu, Y. C.; Yang, Z. Q.; Zhao, D.* Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation. J. Membr. Sci. Lett. 2022, 2, 100017. Kang, C. J.; Yang, K. W.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, Y. X.; Jiang, J. W.; Zou, X. D.; Huang, Z. H.*; Zhao, D.* Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study. Nat. Commun. 2022, 13, 1370. Peh, S. B.; Farooq, S.*; Zhao, D.* A metal-organic framework (MOF)-based temperature swing adsorption cycle for postcombustion CO2 capture from wet flue gas. Chem. Eng. Sci. 2022, 250, 117399. Yang, Z. Q.; Ying, Y. P.; Pu, Y. C.; Wang, D. C.; Yang, H.; Zhao, D.* Poly(ionic liquid)-functionalized UiO-66-(OH)2: improved interfacial compatibility and separation ability in mixed matrix membranes for CO2 separation. Ind. Eng. Chem. Res. 2022, 61, 7626-7633. (Special Issue: Jim Yang Lee Festschrift) Martín-Illán, J. Á.; Suárez, J. A.; Gómez-Herrero, J.; Ares, P.; Gallego-Fuente, D.; Cheng, Y. D.; Zhao, D.; Maspoch, D.; Zamora, F.* Ultralarge free-standing imine-based covalent organic framework membranes fabricated via compression. Adv. Sci. 2022, 9, 2104643. Yu, X.; Fan, W. D.; Wee, V.; Shi, D. C.; Yuan, H. Y.; Ying, Y. P.; Yuan, Y. D.; Yang, Z. Q.; Feng, Y.; Sun, D. F.; Zhao, D.* Polycrystalline Iron(III) metal-organic framework membranes for organic solvent nanofiltration with high permeance. J. Membr. Sci. 2022, 644, 120130. Kang, C. J.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Yu, K. X.; Wang, Y. X.; Zhao, D.* Aggregated structures of two-dimensional covalent organic frameworks. J. Am. Chem. Soc. 2022, 144, 3192-3199. Yuan, H. Y.*; Li, N. X.; Fan, W. D.; Cai, H.; Zhao, D.* Metal-organic framework based gas sensors. Adv. Sci. 2022, 9, 2104374. Dong, J. Q.*; Pan, Y. T.; Yang, K. W.; Yuan, Y. D.; Wee, V.; Xu, S. D.; Wang, Y. X.; Jiang, J. W.*; Liu, B.*; Zhao, D.* Enhanced biological imaging via aggregation-induced emission active porous organic cages. ACS Nano 2022, 16, 2355-2368. Yuan, Y. D.; Zhang, X. M.; Yang, Z. Q.; Zhao, D.* Metal–organic cage incorporating thin-film nanocomposite membranes with antifouling properties. Chem. Commun. 2022, 58, 6865-6868. (Invited Contribution in the Themed Collection “2022 Pioneering Investigators”) Rouhani, H.; Ying, Y. P.; Zhao, D.* Smart two-dimensional membranes for molecular separations. ChemNanoMat 2022, 8, e202100377. Pu, Y. C.; Yang, Z. Q.; Wee, V.; Wu, Z. J.; Jiang, Z. Y.*; Zhao, D.* Amino-functionalized NUS-8 nanosheets as fillers in PIM-1 mixed matrix membranes for CO2 separations. J. Membr. Sci. 2022, 641, 119912. Wang, Y. X.; Kang, C. J.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Yuan, Y. D.; Zhao, D.* Evaluation of Schiff-base covalent organic frameworks for CO2 capture: structure–performance relationships, stability, and performance under wet conditions. ACS Sustainable Chem. Eng. 2022, 10, 332-341. (ACS Publications Recommended Reading) Zhao, D.*; Feng, X. L.* A special collection on 2D materials and their applications. Chem.-Asian J. 2021, 16, 4009-4009. Yang, Z. Q.; Liu, G. L.; Yuan, Y. D.; Peh, S. B.; Ying, Y. P.; Fan, W. D.; Yu, X.; Yang, H.; Wu, Z. J.; Zhao, D.* Homoporous hybrid membranes containing metal-organic cages for gas separation. J. Membr. Sci. 2021, 636, 119564. Fan, W. D.; Ying, Y. P.; Peh, S. B.; Yuan, H. Y.; Yang, Z. Q.; Yuan, Y. D.; Shi, D. C.; Yu, X.; Kang, C. J.; Zhao, D.* Multivariate polycrystalline metal–organic framework membranes for CO2/CH4 separation. J. Am. Chem. Soc. 2021, 143, 17716-17723. (Front Cover) Zhang, B.; Chen, H. W.; Hu, Q. H.; Jiang, L. M.; Shen, Y. Q.; Zhao, D.; Zhou, Z. X.* CelluMOFs: green, facile, and flexible metal-organic frameworks for versatile applications. Adv. Funct. Mater. 2021, 31, 2105395. Zhao, Y. J.; Liu, P.; Ying, Y. P.*; Wei, K. P.; Zhao, D.; Liu, D. H.* Heating-driven assembly of covalent organic framework nanosheets for gas separation. J. Membr. Sci. 2021, 632, 119326. Ying, Y. P.; Yang, Z. Q.; Shi, D. C.; Peh, S. B.; Wang, Y. X.; Yu, X.; Yang, H.; Chai, K. G.; Zhao, D.* Ultrathin covalent organic framework film as membrane gutter layer for high-permeance CO2 capture. J. Membr. Sci. 2021, 632, 119384. Fan, W. D.; Peh, S. B.; Zhang, Z. Q.; Yuan, H. Y.; Yang, Z. Q.; Wang, Y. X.; Chai, K. G.; Sun, D. F.; Zhao, D.* Tetrazole-functionalized zirconium metal-organic cages for efficient C2H2/C2H4 and C2H2/CO2 separations. Angew. Chem. Int. Ed. 2021, 60, 17338-17343. (Frontispiece) Zhang, Z. Q.; Peh, S. B.; Krishna, R.; Kang, C. J.; Chai, K. G.; Wang, Y. X.; Shi, D. C.; Zhao, D.* Optimal pore chemistry in an ultramicroporous metal–organic framework for benchmark inverse CO2/C2H2 separation. Angew. Chem. Int. Ed. 2021, 60, 17198-17204. Dong, J. Q.; Wee, V.; Peh, S. B.; Zhao, D.* Molecular-rotor-driven advanced porous materials. Angew. Chem. Int. Ed. 2021, 60, 16279-16292. Zhang, Z. Q.; Peh, S. B.; Kang, C. J.; Chai, K. G.; Zhao, D.* Metal-organic frameworks for C6–C8 hydrocarbon separations. EnergyChem 2021, 3, 100057. Yuan, H. Y.; Liu, G. L.; Qiao, Z. W.; Li, N. X.; Buenconsejo, P. J. S.; Xi, S. B.; Karmakar, A.; Li, M. S.; Cai, H.; Pennycook, S. J.; Zhao, D.* Solution-processable metal–organic framework nanosheets with variable functionalities. Adv. Mater. 2021, 33, 2101257. (Frontispiece) Shi, D. C.; Yu, X.; Fan, W. D.; Wee, V.; Zhao, D.* Polycrystalline zeolite and metal-organic framework membranes for molecular separations. Coord. Chem. Rev. 2021, 437, 213794. Li, N. X.; Yuan, H. Y.; Xu, L. F.; Zeng, Y. Q.; Qiang, B.; Wang, Q. J.; Zheng, S. N.; Cai, H.*; Lee, L. Y. T.; Singh, N.; Zhao, D.* Tailorable infrared emission of microelectromechanical system-based thermal emitters with NiO films for gas sensing. Opt. Express 2021, 29, 19084-19093. Chen, H. W.; Chen, H. Q.; Zhang, B.; Jiang, L. M.; Shen, Y. Q.; Fu, E. G.; Zhao, D.; Zhou, Z. X.* Tuning the release rate of volatile molecules by pore surface engineering in metal-organic frameworks. Chin. Chem. Lett. 2021, 32, 1988-1992. Ying, Y. P.; Zhang, Z. Q.; Peh, S. B.; Karmakar, A.; Cheng, Y. D.; Zhang, J.; Xi, L. F.; Boothroyd, C.; Lam, Y. M.; Zhong, C. L.*; Zhao, D.* Pressure-responsive two-dimensional metal–organic framework composite membranes for CO2 separation. Angew. Chem. Int. Ed. 2021, 60, 11318-11325. (Inside Back Cover) Wu, Z. J.; Wee, V.; Ma, X. B.*; Zhao, D.* Adsorbed natural gas storage for onboard applications. Adv. Sustainable Syst. 2021, 5, 2000200. Fan, D.; Ozcan, A.; Ramsahye, N. A.; Zhao, D.; Maurin, G.; Semino, R.* Is porosity at the MOF/polymer interface necessarily an obstacle to optimal gas-separation performances in mixed matrix membranes? ACS Materials Lett. 2021, 3, 344-350. Liu, G. L.; Zhang, X. M.; Yuan, Y. D.; Yuan, H. Y.; Li, N. X.; Ying, Y. P.; Peh, S. B.; Wang, Y. X.; Cheng, Y. D.; Cai, Y. H.; Gu, Z. H.; Cai, H.; Zhao, D.* Thin-film nanocomposite membranes containing water-stable zirconium metal–organic cages for desalination. ACS Materials Lett. 2021, 3, 268-274. Zhao, J.; Yuan, H. Y.; Wang, G. L.*; Lim, X. F.; Ye, H. L.; Wee, V.; Fang, Y. Z.; Lee, J. Y.*; Zhao, D.* Stabilization of lithium metal anodes by conductive metal–organic framework architectures. J. Mater. Chem. A 2021, 9, 12099-12108. Liu, G. L.; Yang, Z. Q.; Zhou, M.; Wang, Y. X.; Yuan, D. Q.*; Zhao, D.* Heterogeneous postassembly modification of zirconium metal–organic cages in supramolecular frameworks. Chem. Commun. 2021, 57, 6276-6279. Hu, Z. G.*; Wang, Y. X.; Zhao, D.* The chemistry and applications of hafnium and cerium(IV) metal–organic frameworks. Chem. Soc. Rev. 2021, 50, 4629-4683. Liu, X. M.; Lim, G. J. H.; Wang, Y. X.; Zhang, L.; Mullangi, D.; Wu, Y.; Zhao, D.; Ding, J.; Cheetham, A. K.; Wang, J.* Binder-free 3D printing of covalent organic framework (COF) monoliths for CO2 adsorption. Chem. Eng. J. 2021, 403, 126333. Cai, Y. H.; Shi, D. C.; Liu, G. L.; Ying, Y. P.; Cheng, Y. D.; Wang, Y. X.; Chen, D. Y.; Lu, J. M.*; Zhao, D.* Polycrystalline zirconium metal-organic framework membranes supported on flexible carbon cloth for organic solvent nanofiltration. J. Membr. Sci. 2020, 615, 118551. Hu, Z. G.*; Kundu, T.; Wang, Y. X.; Sun, Y.; Zeng, K. Y.; Zhao, D.* Modulated hydrothermal synthesis of highly stable MOF-808(Hf) for methane storage. ACS Sustainable Chem. Eng. 2020, 8, 17042-17053. Zhang, Z. Q.; Peh, S. B.; Wang, Y. X.; Kang, C. J.; Fan, W. D.; Zhao, D.* Efficient trapping of trace acetylene from ethylene in an ultramicroporous metal–organic framework: synergistic effect of high-density open metal and electronegative sites. Angew. Chem. Int. Ed. 2020, 59, 18927-18932. (Front Cover, Hot Paper) Yuan, Y. D.; Dong, J. Q.; Liu, J.; Zhao, D. H.; Wu, H.; Zhou, W.; Gan, H. X.; Tong, Y. W.; Jiang, J. W.*; Zhao, D.* Porous organic cages as synthetic water channels. Nat. Commun. 2020, 11, 4927. (Behind the Paper) Cheng, Y. D.; Shi, D. C.; Yuan, Y. D.; Zhao, D.* Facile synthesis of a metal–organic framework for removal of methyl blue from water: first-year undergraduate teaching lab. J. Chem. Educ. 2020, 97, 4145-4151. Zhai, L. Z.; Yu, X.; Wang, Y. X.; Zhang, J.; Ying, Y. P.; Cheng, Y. D.; Peh, S. B.; Liu, G. L.; Wang, X. R.; Cai, Y. H.; Zhao, D.* Polycrystalline rare-earth metal-organic framework membranes with in-situ healing ability for efficient alcohol dehydration. J. Membr. Sci. 2020, 610, 118239. Cheng, Y. D.; Pu, Y. C.; Zhao, D.* Two-dimensional membranes: new paradigms for high-performance separation membranes. Chem.-Asian J. 2020, 15, 2241-2270. (Front Cover, Invited Review in the Special Issue “The Chemistry of 2D Materials Membranes”) Peh, S. B.; Zhao, D.* Tying amines down for stable CO2 capture. Science 2020, 369, 372-373. Yuan, H. Y.; Cui, J. Q.; Li, N. X.; Li, M. S.; Yu, X.; Fan, W. D.; Karmakar, A.; Dong, J. Q.; Pennycook, S. J.; Cai, H.*; Zhao, D.* On-chip template-directed conversion of metal hydroxides to metal–organic framework films with enhanced adhesion. ACS Appl. Mater. Interfaces 2020, 12, 36715-36722. Dong, J. Q.; Shen, P. C.; Ying, S. M.; Li, Z. J.; Yuan, Y. D.; Wang, Y. X.; Zheng, X. Y.; Peh, S. B.; Yuan, H. Y.; Liu, G. L.; Cheng, Y. D.; Pan, Y. T.; Shi, L. L.; Zhang, J.; Yuan, D. Q.; Liu, B.; Zhao, Z. J.*; Tang, B. Z.*; Zhao, D.* Aggregation-induced emission-responsive metal–organic frameworks. Chem. Mater. 2020, 32, 6706-6720. Kang, C. J.; Zhang, Z. Q.; Wee, V.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, S.; Wang, Y. X.; Zhao, D.* Interlayer shifting in two-dimensional covalent organic frameworks. J. Am. Chem. Soc. 2020, 142, 12995-13002. (Supplementary Cover) Karmakar, A.; Prabakaran, V.; Zhao, D.; Chua, K. J.* A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications. Appl. Energy 2020, 269, 115070. Karmakar, A.; Mileo, P. G. M.; Bok, I.; Peh, S. B.; Zhang, J.; Yuan, H. Y.; Maurin, G.*; Zhao, D.* Thermo-responsive MOF/polymer composites for temperature-mediated water capture and release. Angew. Chem. Int. Ed. 2020, 59, 11003-11009. (Back Cover) Peh, S. B.; Xi, S. B.; Karmakar, A.; Yeo, J. Y.; Wang, Y. X.; Zhao, D.* Accelerated formation kinetics of a multicomponent metal–organic framework derived from preferential site occupancy. Inorg. Chem. 2020, 59, 9350-9355. Dong, J. Q.; Pan, Y. T.; Wang, H.; Yang, K. W.; Liu, L. M.; Qiao, Z. W.; Yuan, Y. D.; Peh, S. B.; Zhang, J.; Shi, L. L.; Liang, H.; Han, Y.; Li, X. P.; Jiang, J. W.; Liu, B.*; Zhao, D.* Self-assembly of highly stable zirconium(IV) coordination cages with aggregation induced emission molecular rotors for live-cell imaging. Angew. Chem. Int. Ed. 2020, 59, 10151-10159. (Dedicated to the 20 Anniversary of Aggregation Induced Emission) Yuan, H. Y.; Li, N. X.; Linghu, J. J.; Dong, J. Q.; Wang, Y. X.; Karmakar, A.; Yuan, J. R.; Li, M. S.; Buenconsejo, P. J. S.; Liu, G. L.; Cai, H.; Pennycook, S. J.; Singh, N.; Zhao, D.* Chip-level integration of covalent organic frameworks for trace benzene sensing. ACS Sens. 2020, 5, 1474-1481. Gu, Q. L.*; Ng, H. Y.; Zhao, D.; Wang, J.* Metal–organic frameworks (MOFs)-boosted filtration membrane technology for water sustainability. APL Mater. 2020, 8, 040902. Zhao, D.*; Cheetham, A.; Furukawa, S.; Kitagawa, S.; Xu, Q.; Zhang, W.; Zou, R. Q. Open framework materials for energy applications. APL Mater. 2020, 8, 040401. (Editorial in the Special Topic on Open Framework Materials for Energy Applications) Peh, S. B.; Karmakar, A.; Zhao, D.* Multiscale design of flexible metal–organic frameworks. Trends Chem. 2020, 2, 199-213. (Front Cover) Ying, Y. P.; Tong, M. M.; Ning, S. C.; Ravi, S. K.; Peh, S. B.; Tan, S. C.; Pennycook, S. J.; Zhao, D.* Ultrathin two-dimensional membranes assembled by ionic covalent organic nanosheets with reduced apertures for gas separation. J. Am. Chem. Soc. 2020, 142, 4472-4480. (Front Cover) Wang, J.; Zhang, J.; Peh, S. B.; Liu, G. L.; Kundu, T.; Dong, J. Q.; Ying, Y. P.; Qian, Y. H.; Zhao, D.* Cobalt-containing covalent organic frameworks for visible light-driven hydrogen evolution. Sci. China Chem. 2020, 63, 192-197. Zhang, Z. Q.; Ding, Q.; Peh, S. B.; Zhao, D.; Cui, J. Y.; Cui, X. L.*; Xing, H. B. Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture. Chem. Commun. 2020, 56, 7726-7729.

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