何振宇 - 南方科技大学

个人简介

何振宇，南方科技大学化学系副教授、研究员；Grubbs 研究院双聘教授；何振宇博士于2000年-2005年在香港大学（the university of hong kong）化学系杨丹教授指导下从事有机不对称催化并获得博士学位，随后在麻省理工学院（M.I.T.） prof. timothy f. jamison研究组作为博士后从事过渡金属催化。从2007年底开始，在香港中文大学（the chinese university of hongkong）作为研究助理教授开始了独立的研究，从2013年起，加盟深圳南方科技大学(SUSTech)，入选深圳市孔雀计划b类人员，主要从事金属有机化学n-杂环卡宾及其在有机金属催化中的应用研究，在国内外学术刊物（angew. chem. int. ed, j. am.chem. soc，chem. commun., acs catal.等）发表论文多篇，并获the asian core program lectureship award (from japan)，the asian core program lectureship award (from singapore)等多项奖项。

研究领域

新材料产业—先进石化工新材料—专用化学品及材料制造—专用化学品及材料制造

近期论文

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Unsymmetric N-Aryl Substituent Effects on Chiral NHC-Cu: Enantioselectivity and Reactivity Enhancement by Ortho-H and Syn-Configuration. Xi, J.; Ng, E. W. H.; Ho, C.-Y.* ACS Catal. 2023, 13, 407. (NHC)Pd(II) hydride-catalyzed dehydroaromatization by Olefin Chain-Walking Isomerization and Transfer-Dehydrogenation. Chen. W.; Chen, Y.; Gu, X.; Chen, Z.; Ho, C.-Y.* Nat. Commun. 2022, 13, 5507. NHC-Ni(II)-Catalyzed Cyclopropene-Isocyanide [5+1] Benzannulation. Huang, J.-Q.; Yu, M.; Yong, X.; Ho, C.-Y.* Nat. Commun. 2022, 13, 4145. Diastereodivergent Hydrosilylative Enyne Cyclization Catalyzed by N-Heterocyclic Carbene-Ni(0). Yu, M.; Yong, X.; Gao, W.; Ho, C.-Y.* Chin. J. Chem. 2021, 39, 1587. NHC/Nickel(II)-Catalyzed [3+2] Cross-Dimerization of Unactivated Olefins and Methylenecyclopropanes. Huang, J.-Q.; Ho, C.- Y.* Angew. Chem. Int. Ed. 2020, 59, 5288. NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins. Chen, Y.; Dang, L.; Ho, C.- Y.* Nat. Commun. 2020, 11, 2269. NHC-Ni catalyzed 1,3- and 1,4-diastereodivergent heterocycle synthesis from hetero-substituted enyne. Yong, X.; Gao, W.; Lin, X.; Ho, C.- Y.* Comm. Chem. 2020, 3, 50. NHC-Ni(0) Catalyzed Diastereodivergent Hydroacylative Enyne Cyclization: Synthesis of Heterocycles bearing gamma-Enone. Yong, X.; Ng, E.; Zhen, Z.; Lin, X.; Gao, W.; Ho, C.-Y.* Adv. Synth. Cat. 2020, 362 , 4164. Applications of (NHC)Ni(II) Catalyzed [3+2] Hydroalkenylation-Rearrangement Cascades. Yong, X.; Huang, J.-Q., Ho, C.- Y.* Chin. J. Org. Chem. 2020, 40, 3327. [(NHC)Ni(II)H]-Catalyzed Cross-Hydroalkenylation of Cyclopropenes with Alkynes: Cyclopentadiene Synthesis by [(NHC)Ni(II)]-Assisted C-C Rearrangement. Huang, J.-Q.; Ho, C.-Y.* Angew. Chem. Int. Ed. 2019, 58, 5702. Electronic Effects on Chiral NHC–Transition-Metal. Yong, X., Thurston, R. & Ho, C.-Y.* Synthesis. 2019, 51, 2058. Synthesis and Study of Au(III)-Indolizine Derivatives: Turn-on Luminescence by Photo-induced Control Release. Yang, J.; Zhu, Y.; Tse, A. K.-W.; Zhou, X.; Chen, Y.; Tse, Y. C.;* Wong, K. M.-C.;* Ho, C.-Y.* Chem. Commun. 2019, 55, 4471. Intranasal delivery of a novel acetylcholinesterase inhibitor HLS-3 for treatment of Alzheimer’s disease. Qian, S.; He, .; Wang, Q.; Wong, Y. C.; Mak, M.; Ho, C.-Y.*; Han, Y.*; Zuo, Z*. Life Sciences 2018, 207, 428. (NHC)NiH-Catalyzed Regiodivergent Cross-Hydroalkenylation of Vinyl Ether with α-Olefin: 1,2- and 1,3-Disubstituted Allyl Ether Syntheses. Chen, W.; Li, Y.; Chen, Y.; Ho, C.-Y.* Angew. Chem. Int. Ed. 2018, 57, 2677. (NHC)NiH-Catalyzed Intermolecular Regio- and Diastereoselective Cross-Hydroalkenylation of Endocyclic Dienes with α-Olefins. Lian, X.; Chen, W.; Dang, L.; Li, Y.; Ho, C.-Y.* Angew. Chem. Int. Ed. 2017, 56, 9048. Mechanism and Regioselectivities of (NHC)Nickel(II)hydride-Catalyzed Cycloisomerization of Dienes: A Computational Study. Gao, Y.; Houk, K. N.;Ho, C.-Y.*; Hong, X.* Org. Biomol. Chem. 2017, 15, 7131. Themed Collections: Mechanistic Aspects of Organic Synthesis Catalytic Asymmetric Hydroalkenylation of Vinylarenes: Electronic Effects of Substrates and Chiral N-Heterocyclic Carbene Ligands Ho, C.-Y.*; Chan, C.-W.; He, L. Angew. Chem. Int. Ed. 2015, 54, 4512. Substituted 1,3-cyclohexadiene synthesis by NHC-Nickel(0) catalyzed [2+2+2] cycloaddition of 1,n-Enyne”. Zhao, J.-P.; Chan, S.-C.; Ho, C.-Y.* Tetrahedron 2015, 71, 4426. Invited Special Symposium-in-Print: Progress in organic synthesis: New reactions, strategies and targets. Computational Exploration of Mechanism and Selectivities of NHC-Ni(II)hydride Catalyzed Hydroalkenylations of Styrene with a-Olefins. Hong, X.; Wang, J.; Yang, Y.-F.; He, L.; Ho, C.-Y.*; Houk, K. N.*ACS Catal. 2015, 5, 5545. Nitrate-Enhanced NHC-NiH Catalyzed Tail-to-Tail Vinyl Ether Dimerization. He, L.; Ho, C.-Y.* Synlett 2014, 25, 2738.