研究领域

Synthetic Organic Chemistry

Development of organocatalysts

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Metal-free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine T. Kano, F. Shirozu, K. Maruoka, J. Am. Chem. Soc. 2013, 135, 18036-18039. Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-transfer Conditions T. Kano, Y. Hayashi, K. Maruoka, J. Am. Chem. Soc. 2013, 135, 7134-7137. Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc-Imines from N-Boc-Aminals T. Kano, T. Yurino, D. Asakawa, K. Maruoka, Angew. Chem. Int. Ed. 2013, 52, 5532-5534. Powerful Amino Diol Catalyst for Effecting the Direct Asymmetric Conjugate Addition of Aldehydes to Acrylates T. Kano, F. Shirozu, M. Akakura, K. Maruoka, J. Am. Chem. Soc. 2012, 134, 16068-16073. Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction of N-Protected Aminoacetaldehydes: Formal Synthesis of (–)-Agelastatin A T. Kano, R. Sakamoto, M. Akakura, K. Maruoka, J. Am. Chem. Soc. 2012, 134, 7516-7520. Efficient Organocatalytic Cross-aldol Reaction between Aliphatic Aldehydes through Their Functional Differentiation T. Kano, H. Sugimoto, K. Maruoka, J. Am. Chem. Soc. 2011, 133, 18130-18133. Metal-Free Direct Asymmetric Aminoxylation of Aldehydes Catalyzed by a Binaphthyl-Based Chiral Amine T. Kano, H. Mii, K. Maruoka, Angew. Chem. Int. Ed. 2010, 49, 6638-6641. Direct Asymmetric Benzoyloxylation of Aldehydes Catalyzed by 2-Tritylpyrrolidine T. Kano, H. Mii, K. Maruoka, J. Am. Chem. Soc. 2009, 131, 3450-3451. Direct Asymmetric Iodination of Aldehydes Using an Axially Chiral Bifunctional Amino Alcohol Catalyst T. Kano, M. Ueda, K. Maruoka, J. Am. Chem. Soc. 2008, 130, 3728-3729. syn-Selective and Enantioselective Direct Cross-Aldol Reactionsbetween Aldehydes Catalyzed by an Axially Chiral Amino Sulfonamide T. Kano, Y. Yamaguchi, Y. Tanaka, K. Maruoka, Angew. Chem., Int. Ed. 2007, 46, 1738-1740. Direct Asymmetric Hydroxyamination Reaction Catalyzed by an Axially Chiral Secondary Amine Catalyst T. Kano, M. Ueda, J. Takai, K. Maruoka, J. Am. Chem. Soc. 2006, 128, 6046-6047. anti-Selective Direct Asymmetric Mannich Reactions Catalyzed by Axially Chiral Amino Sulfonamide as an Organocatalyst T. Kano, Y. Yamaguchi, O. Tokuda, K. Maruoka, J. Am. Chem. Soc. 2005, 127, 16408-16409. Design of an Axially Chiral Amino Acid with a Binaphthyl Backbone as an Organocatalyst for a Direct Asymmetric Aldol Reaction T. Kano, J. Takai, O. Tokuda, K. Maruoka, Angew. Chem., Int. Ed. 2005, 44, 3055-3057.