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Shuxiang Zhu, Zhipeng Guan, Yanlong Liu, Heng Zhang,* Aiwen Lei,* and Hong Yi* Unveiling the Switchable Chemoselectivity Mechanism in Electrochemical Nickel-Catalyzed C(sp2)-O Coupling of Phenols and Aliphatic Alcohols J. Am. Chem. Soc. 2025, 147, 31603–31617.
Haozhe Dong, Xuejie Wang, Pingsen Shi, Nian Chen, Zhiqiang Zhang, Jia Yan, Aiwen Lei* and Hong Yi* N-Heterocyclic Carbene-Ligated Mixed-valent Linear Cu3 Cluster for Enhanced Electrocatalytic Nitrite Reduction. J. Am. Chem. Soc. 2025,147, 29423-29430.
S. Liu, H. Lin, T. Peng, Z. Yang, P. Wan, J. Li, L. Yang, X. Dai, S. Tu, X. Long, A. Lei*, T. Wang*, H. Yi*. Electrochemical Amino‐Oxygenation Cyclization via Alkene Radical Cation/Bisnucleophile Engagement to Saturated N/O‐Heterocycles. Angew. Chem. Int. Ed. 2025, 64, e202501424.
Demin RenYuan WangZhao LiuYatao WangWei DingFengze YaoXiaotian Qi* Aiwen Lei* Hong Yi* Cobaloxime-Catalyzed Radical Allylic C–H Sulfonylation Through Synergistic XAT/HAT Processes ACS Catal. 2025, 15, 13127–13135
S. Wang, X. Luo, Y. Wang, Z. Liu, Y. Yu, X. Wang, D. Ren, P. Wang, Y. H. Chen, X. Qi*, H. Yi*, A. Lei*. Radical-triggered translocation of C-C double bond and functional group. Nat. Chem. 2024, 16, 1621-1629.
J. Hu, H. He, M. Xu, X. Qi, C. Fu, H. Yi*, A. Lei*. Adduct-catalyzed tandem electro-thermal synthesis of organophosphorus (III) compounds from white phosphorus. Natl. Sci. Rev. 2025, 12, nwaf008.
L. Nie, J. Yang, Z. Liu, S. Zhou, S. Chen, X. Qi,* A. Lei,* and H. Yi*. Linear Paired Electrolysis Enables Redox-Neutral (3 + 2) Annulation of Benzofuran with Vinyldiazo Compounds, J. Am. Chem. Soc. 2024, 146, 31330-31338.
X. Liu, J. Chen, Z. Wei*, H. Yi*, A. Lei*. Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry. Chem. 2024, 10, 2131-2146.
J. Zhang, Z. Yang*, C. Liu, H. Wan, Z. Hao, X. Ji, P. Wang, H. Yi*, A. Lei*. Tailoring photocatalysts to modulate oxidative potential of anilides enhances para-selective electrochemical hydroxylation. Nat. Commun. 2024, 15, 6954.
X. Liu, D. Yang, Z. Liu, Y. Wang, Y. Liu, S. Wang, P. Wang, H. Cong, Y. H. Chen*, L. Lu*, X. Qi*,H. Yi*, A. Lei*. Unraveling the Structure and Reactivity Patterns of the Indole Radical Cation in Regioselective Electrochemical Oxidative Annulations. J. Am. Chem. Soc. 2023, 145, 3175-3186.
X. Luo, D. Yang, X. He, S. Wang, D. Zhang, J. Xu, C. W. Pao, J. L. Chen, J. F. Lee, H. Cong, Y. Lan, H. Alhumade, J. Cossy*, R. Bai*, Y. H. Chen*, H. Yi*, A. Lei*. Valve turning towards on-cycle in cobalt-catalyzed Negishi-type cross-coupling. Nat. Commun. 2023, 14, 4638.
D. Yang, Z. Guan, Y. Peng, S. Zhu, P. Wang, Z. Huang, H. Alhumade, D. Gu*, H. Yi*, A. Lei*. Electrochemical oxidative difunctionalization of diazo compounds with two different nucleophiles. Nat. Commun. 2023, 14, 1476.
Z. Yang, W. Shi, H. Alhumade, H. Yi*, A. Lei*. Electrochemical oxidative C(sp3)–H cross-coupling with hydrogen evolution. Nat. Synth. 2023, 2, 217-230.
Q. Wan, K. Chen, X. Dong, X. Ruan, H. Yi*, S. Chen*. Elucidating the Underlying Reactivities of Alternating Current Electrosynthesis by Time-Resolved Mapping of Short-Lived Reactive Intermediates. Angew. Chem. Int. Ed. 2023, 62, e202306460.
L. Zeng, J. Wang, D. Wang, H. Yi*, A. Lei*. Comprehensive Comparisons between Directing and Alternating Current Electrolysis in Organic Synthesis. Angew. Chem. Int. Ed. 2023, 62, e202309620.
K. Liang, D. Zhang, Y. Su, L. Lu, J. Hu, Y. H. Chen*, X. Zhang*, A. Lei*, H. Yi*. Fragile intermediate identification and reactivity elucidation in electrochemical oxidative alpha-C(sp3)-H functionalization of tertiary amines. Chem. Sci. 2023, 14, 4152-4157.
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