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Positions 06/2018 – 05/2023 Chair, Department of Chemistry, McGill University, Canada 04/2014 – Professor, McGill University, Canada 06/2010 – 03/2014 Associate Professor, McGill University, Canada 10/2005 – 05/2010 Assistant Professor, McGill University, Canada 01/2003 – 09/2005 Assistant Professor, Institut National de la Recherche Scientifique, Canada 09/2001 – 12/2002 Postdoctoral Researcher, UCLA, U.S.A (with Prof. F. Wudl) 07/1999 – 07/2001 Postdoctoral Researcher, University of Durham, U.K. (with Prof. M.R. Bryce) Education 06/1999 PhD in Organic Chemistry, Institute of Physical Organic Chemistry, Nat. Acad. Sci. Ukraine (with Prof. A.F. Popov) 07/1994 Diploma in Chemistry, Donetsk State University, Ukraine Honors/Awards (selected) 2018 Peng Chen Scholar Award (Peking University – Shenzhen) 2017 Premio Venezia for Scientific Collaboration (Italian Chamber of Commerce) 2017-2024 Sir William C. MacDonald Chair in Chemistry (McGill) 2015-2016 Fulbright Visiting Research Chair (Fulbright/California Nanosystems Institute) 2015 Award for Research Excellence in Materials Chemistry (Canadian Soc. of Chemistry) 2012 Tomlinson Science Award (McGill University) 2009 Feinberg Foundation Visiting Faculty Fellow (Weizmann Inst. Science, Israel) 2008 CNC-IUPAC Travel Award 2006 DuPont Young Professor (DuPont USA)


CURRENT RESEARCH PROJECTS The main research theme in our group is discovering new electronic properties in organic and hybrid materials. En route to this goal, we are engaged in design and synthesis of novel pi-conjugated molecules and polymers, and study of their optical and electronic behavior, in solution, in thin films and crystals, and in semiconducting devices. Organic synthesis accounts for about 70% of our research activity, but the essence of these efforts is “making” novel properties, not merely new molecules. Thus, the new members of the group should also expect to develop expertise in one (or more) of the following: quantum-chemical calculations; supramolecular chemistry; photophysical and electrochemical measurements; semiconducting device fabrication; thin films and surface characterization techniques, scanning probe microscopy. NOVEL PI-CONJUGATED SYSTEMS ORGANIC SEMICONDUCTOR DEVICES SUPRAMOLECULAR CONTROL OF ORGANIC ELECTRONIC MATERIALS TWO-DIMENSIONAL CONJUGATED POLYMERS NANOCHEMISTRY


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Thiele’s Fluorocarbons: Stable Diradicaloids with Efficient Vis-NIR Fluorescence from a Zwitterionic Excited State C.-H. Liu, Z. He, C. Ruchlin, Y. Che, K. Somers, D. F. Perepichka, J. Am. Chem. Soc. 2023 (DOI: 10.1021/jacs.3c05009) Improving Environmental and Operational Stability of Polymer Field-Effect Transistors by Doping with Tetranitrofluorenone P. Ghamari, M. R. Niazi, D. F. Perepichka, ACS. Appl. Mater. Interfaces 2023 (DOI: 10.1021/acsami.3c01034) Silver nanoparticle enhanced metal-organic matrix with interface-engineering for efficient photocatalytic hydrogen evolution Y. Liu, C.-H. Liu, T. Debnath, Y. Wang, D. Pohl, L. V. Besteiro, D. M. Meira, S. Huang, F. Yang, B. Rellinghaus, M. Chaker, D. F. Perepichka, D. Ma, Nat. Commun. 2023 (DOI: 10.1038/s41467-023-35981-8) Rational Control of Near-Infrared Colloidal Thick-Shell Eco-Friendly Quantum Dots for Solar Energy Conversion L. Jin, J. Liu, X. Liu, D. Benetti, G. S. Slopal, X. Tong, E. Hamzehpoor, F. Li, D. F. Perepichka, Z. M. Wang, F. Rosei, Small Methods 2023 (DOI: 10.1002/smtd.202300133) Two Dimensional Supramolecular Polymerization of DNA Amphiphiles is Driven by Sequence?Dependent DNA?Chromophore Interactions M. G. Rafique, J. M. Remington, F. Clark, H. Bai, V. Toader, D. F. Perepichka, J. Li, H. F. Sleiman, Angew. Chem. Int. Ed. 2023 (DOI: 10.1002/anie.202217814) Triarylamines as catalytic donors in light-mediated electron donor–acceptor complexes D. J. Castillo-Pazos, J. D. Lasso, E. Hamzehpoor, J. Ramos-Sánchez, J. M. Salgado, G. Cosa, D. F. Perepichka, C.-J. Li, Chem. Sci. 2023 (DOI: 10.1039/D2SC07078B) Nitrofluorene-based A–D–A electron acceptors for organic photovoltaics Y. Che, M. R. Niazi, T. Yu, T. Maris, C.-H. Liu, D. Ma, R. Izquierdo, I. F. Perepichka, D. F. Perepichka, J. Mater. Chem. C 2023 (DOI: 10.1039/D2TC05127C) Miscibility driven morphology modulation in ternary solar cells T. Yu, F. Tintori, Y. Zhang, W. He, E. Cieplechowicz, R. S. Bobba, P. I. Kaswekar, M. Jafari, Y. Che, Y. Wang, M. Siaj, R. Izquierdo, D. F. Perepichka, Q. Qiao, G. C. Welch, D. Ma, J. Mater. Chem. A 2023 (DOI: 10.1039/D2TA09928D) Trifluoroacetic acid prompted unexpected visible to NIR switching of ketoenamine-substituted triphenylamines K. Laxman, Y. Che, K. A. Raj, D. F. Perepichka, M. R. Rao, J. Chem. Mater. C 2023 (DOI: 10.1039/D2TC04959G) Efficient room-temperature phosphorescence of covalent organic frameworks through covalent halogen doping E. Hamzehpoor, C. Ruchlin, Y. Tao, C.-H. Liu, H. M. Titi, D. F. Perepichka, Nat. Chem. 2022 (DOI: 10.1038/s41557-022-01070-4) A 2D perchlorinated sp2-carbon framework C.-H. Liu, Y. Sakai-Otsuka, P. Richardson, M. R. Niazi, E. Hamzehpoor, T. Jadhav, A. Michels-Gualteri, Y. Fang, M. Murugesu, D. F. Perepichka, Cell Rep. Phys. Sci. 2022 (DOI: 10.1016/j.xcrp.2022.100858) Vanishing Electronic Band Gap in Two-Dimensional Hydrogen-Bonded Organic Frameworks C.-H. Liu, A. Wei, M.F. Cheung D. F. Perepichka, Chem. Mater. 2022 (DOI: 10.1021/acs.chemmater.2c00294) Tandem Desulfurization/C–C Coupling Reaction of Tetrathienylbenzenes on Cu(111): Synthesis of Pentacene and an Exotic Ladder Polymer P. Ji, D. Dettmann, Y.-H. Liu, G. Berti, N. P. Genesh, D. Cui, O. MacLean, D. F. Perepichka, L. Chi, and F. Rosei, ACS Nano 2022 (DOI: 10.1021/acsnano.2c00831) Probing the Thermodynamics of Moiré Patterns in Molecular Self-Assembly at the Liquid–Solid Interface D. Cui, N. P. Genesh, O. MacLean, P. Ji, J. M, MacLeod, M. Ebrahimi, A. V. Lunchev, A. C. Grimsdale, D. F. Perepichka, F. Rosei, Chem. Mater. 2022 (DOI: 10.1021/acs.chemmater.2c00089) Bidirectional Phase Transformation of Supramolecular Networks Using Two Molecular Signals D. Cui, C.-H. Liu, D. F., Perepichka, ACS Nano 2022 (DOI: 10.1021/acsnano.1c10122) Adatoms in the Surface-Confined Ullmann Coupling of Phenyl Groups Z. Zhang, D. F. Perepichka, R. Khaliullin, J. Phys. Chem. Lett. 2021 (DOI: 10.1021/acs.jpclett.1c02914) Halogen bonding vs. pi-stacking interactions in new bis(acenaphthylene)dione semiconductors Y.-H. Liu, A. Dadvand, H. M. Titi, E. Hamzehpoor, D. F. Perepichka, CrystEngComm 2021 (DOI: 10.1039/D1CE01047F) Mechanism of the Photodegradation of A-D-A Acceptors for Organic Photovoltaics Y. Che, M. R. Niazi, R. Izquierdo, D. F. Perepichka, Angew. Chem. Int. Ed. 2021 (DOI: 10.1002/anie.202109357) Recent advances in room temperature phosphorescence of crystalline boron containing organic compounds H. H. Hackney, D. F. Perepichka, Aggregate 2021 (DOI: 10.1002/agt2.123) Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface Y. Fang, Z. Heydari, C.-H. Liu, N. Zhang, L. A. Cuccia, O. Ivasenko, D. F. Perepichka, Chem. Res. Chin. Uni. 2021 (DOI: 10.1007/s40242-021-1324-y). Invited contribution for special issue ‘Women in Chemistry’. Identification of Topotactic Surface-Confined Ullmann-Polymerization D. Dettmann, G. Galeotti, O. MacLean, M. Tomellini, M. Di Giovannantonio, J. Lipton-Duffin, A. Verdini, L. Floreano, Y. Fagot-Revurat, D. F. Perepichka, F. Rosei, G. Contini, Small 2021 (DOI: 10.1002/smll.202103044) Acenaphthylene as a Building Block for pi-Electron Functional Materials Y.-H. Liu, D. F. Perepichka, J. Mater. Chem. C 2021 (DOI: 10.1039/D1TC02826J) Synthesis of Boroxine and Dioxaborole Covalent Organic Frameworks via Transesterification and Metathesis of Pinacol Boronates E. Hamzehpoor, A. Jonderian, E. McCalla, D. F. Perepichka, J. Am. Chem. Soc. 2021 (DOI: 10.1021/jacs.1c05987) Room Temperature Phosphorescence vs Triplet–Triplet Annihilation in N-Substituted Acridone Solids E. Hamzehpoor, C. Ruchlin, Y. Tao, J. E. Ramos-Sanchez, H. M. Titi, G. Cosa, D. F. Perepichka, J. Phys. Chem. Lett. 2021 (DOI: 10.1021/acs.jpclett.1c01552) Controlling Structural and Energetic Disorder in High-Mobility Polymer Semiconductors via Doping with Nitroaromatics P. Ghamari, M.R. Niazi, and D. F. Perepichka, Chem. Mater. 2021 (DOI: 10.1021/acs.chemmater.1c00448) Hydrogen Bonding Versus pi-Stacking in Charge-Transfer Co-crystals N. Yee, A. Dadvand, E. Hamzehpoor, H. M. Titi, D. F. Perepichka, Cryst. Growth Des. 2021 (DOI: 10.1021/acs.cgd.1c00309) Electrically Conductive Covalent Organic Frameworks: Bridging the Fields of Organic Metals and 2D Materials M. Souto, D. F. Perepichka, J. Mater. Chem. C 2021 (DOI: 10.1039/D1TC00750E) Alternating-current-Driven Color-Tunable Organic Light-Emitting Triodes C. Zhao, M.U. Ali, J. Ji, M. Liu, A. Li, J. Bai, J. Miao, T. Wang, D. F. Perepichka, C. Yan, K.-F. C. Shen, H. Meng, Adv. Opt. Mater. 2021 (DOI: 10.1002/adom.202001655) Band Gap Engineering of Donor–Acceptor Co-crystals by Complementary Two-point Hydrogen Bonding N. Yee, A. Dadvand, D. F. Perepichka, Mater. Chem. Front. 2020 (DOI: 10.1039/D0QM00500B) Quantifying Planarity in Design of Organic Electronic Materials Y. Che, D. F. Perepichka, Angew. Chem. Int. Ed. 2020 (DOI: 10.1002/anie.202011521) 90% Quantum Yield Pure-Red Doublet Emission from Stable, Colorless, Iodinated Triphenylmethane Solid C.-H. Liu, E. Hamzehpoor, Y. Otsuka-Sakai, T. Jadhav, D. F. Perepichka, Angew. Chem. Int. Ed. 2020 (DOI: 10.1002/anie.202009867) Fluorination of a Polymer Donor through the Trifluoromethyl Group for High-performance Polymer Solar Cells C. Yao, Y. Zhu, K. Gu, J. Zhao, J. Ning, D. F. Perepichka, Y.-L. Loo, H. Meng, J. Mater. Chem. A 2020 (DOI: 10.1039/D0TA00098A) Synthesis of Mesoscale Ordered Two-dimensional pi-conjugated Polymers with Semiconducting Properties G. Galeotti, F. De Marchi, E. Hamzehpoor, O. MacLean, M. Rajeswara Rao, Y. Chen, L. V. Besteiro, D. Dettmann, L. Ferrari, F. Frezza, P. M. Sheverdyaeva, R. Liu, A. K. Kundu, P. Moras, M. Ebrahimi, M. C. Gallagher, F. Rosei, D. F. Perepichka, G. Contini, Nat. Mater. 2020 (DOI: 10.1038/s41563-020-0682-z) PEDOT Encapsulated and Mechanochemically Engineered Silicate Nanocrystals for High Energy Density Cathodes M. Rasool, H.-C. Chiu, B. Zank, Y. Zeng, J. Zhou, K. Zghib, D. F. Perepichka, G. P. Demopoulos, Adv. Mater. Interfaces 2020 (DOI: 10.1002/admi.202000226) Nitroaromatics as n-type Organic Semiconductors for Field Effect Transistors M. R. Niazi, E. Hamzehpoor, P. Ghamari, I. F. Perepichka, D. F. Perepichka, Chem. Commun. 2020 (DOI: 10.1039/D0CC01236J) Transformation between 2D and 3D Covalent Organic Frameworks via Reversible [2+2] Cycloaddition T. Jadhav, Y. Fang, C.-H. Liu, A. Dadvand, E. Hamzehpoor, W. Patterson, A. Jonderian, R. S. Stein, D. F. Perepichka, J. Am. Chem. Soc. 2020 (DOI: 10.1021/jacs.0c01990) Stereospecific Epitaxial Growth of Bilayered Porous Molecular Networks Y. Fang, B. D. Lindner, I. Destoop, T. Tsuji, Z. Zhang, R. Z. Khaliullin, D. F. Perepichka, K. Tahara, S. De Feyter, Y. Tobe, J. Am. Chem. Soc. 2020 (DOI: 10.1021/jacs.0c00108) Boosting the Efficiency and Curtailing the Efficiency Roll-off in Green Perovskite Light-Emitting Diodes via Incorporating Ytterbium as Cathode Interface Layer M. U. Ali, J. Miao, J. Cai, D. F. Perepichka, H. Yang, H. Meng, ACS Appl. Mater. Interfaces 2020 (DOI: 10.1021/acsami.0c00950) Serendipitous Formation of Semiconducting semi-NINDIGO Indigoid by Degradation of Diindolopyrrole N. Yee, A. Dadvand, D. F. Perepichka, J. Org. Chem. 2020 (DOI: 10.1021/acs.joc.0c00054) Surface-confined Single-layer Covalent Organic Frameworks: Design, Synthesis and Application D. Cui, D. F. Perepichka, J. M., MacLeod, F. Rosei, Chem. Rev. Soc. 2020 (DOI: 10.1039/C9CS00456D) A Trifluoromethyl Group Modified Non-fullerene Acceptor Towards Improved Power Conversion Efficiency Over 13% in Polymer Solar Cells C. Yao, J. Zhao, Y. Zhu, B. Liu, C. Yan, D. F. Perepichka, H. Meng, ACS Appl. Mater. Interfaces 2020 (DOI: 10.1021/acsami.9b20544) Surface-Confined Macrocyclization via Dynamic Covalent Chemistry C. Fu, J. Mikšátko, L. Assies, V. Vrkoslav, S. Orlandi, M. Kalbác, P. Kovarícek, X. Zeng, B. Zhou, L. Muccioli, D. F. Perepichka, E. Orgiu, ACS Nano 2020 (DOI: 10.1021/acsnano.9b07671) A Two-dimensional Poly(azatriangulene) Covalent Organic Framework with Semiconducting and Paramagnetic State V. Lakshmi, C.-H. Liu, M.R. Rao, Y. Chen, F. Yuan, Dadvand A., E. Hamzehpoor, Y. Sakai-Otsuka, R.S. Stein, D.F. Perepichka, J. Am. Chem. Soc. 2020 (DOI: 10.1021/jacs.9b11528)