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From a mononuclear FeIIL2 complex to a spin crossover FeII4L6 cage by symmetric ligand architecture modification: insights into the ammonia gas sensing mechanism W. Li, A. Rotaru, M. Wolff, S. Demeshko, F. Meyer, Y. Garcia J. Mater. Chem. C 2023, 11, 11175–11184
Cu4S Cluster in "0-Hole" and "1-Hole" States: Geometric and Electronic Structure Variations for the Active CuZ* Site of N2O Reductase Y. Liu, S. Chatterjee, G. E. Cutsail III, S. Peredkov, S. K. Gupta, S. Dechert, S. DeBeer, F. Meyer J. Am. Chem. Soc. 2023, 145, 18477−18486
Tailoring activity and stability: Effects of electronic variations on iron-NHC epoxidation catalysts T. P. Schlachta, G. G. Zámbó, M. J. Sauer, I. Rüter, C. A. Hoefer, S. Demeshko, F. Meyer, F. E. Kühn Journal of Catalysis 2023, 426, 234–246
Chemical Synthesis of Alpha-Synuclein Proteins via Solid-Phase Peptide Synthesis and Native Chemical Ligation L. M. Gatzemeier, F. Meyer, U. Diederichsen, T. F. Outeiro Chem. Eur. J. 2023, 29, e202300649
Synthesis, Properties, and Reactivity of a Linear NHC-Based Chromium(I) Silylamide A. Gonzalez, T.-Y. Chen, S. Demeshko, F. Meyer, C. G. Werncke Organometallics 2023, 42, 1198−1204
Air-stable four-coordinate cobalt(II) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic anisotropy S. K. Gupta, S. V. Rao, S. Demeshko, S. Dechert, E. Bill, M. Atanasov, F. Neese, F. Meyer Chem. Sci. 2023,14, 6355–6374
Ligand Modulation of the Structures and Magnetic Relaxation in Triangular Dy3 Complexes Based on a Tricompartmental Scaffold J. Wu, F. Zhang, G.-L. Wang, S. Demeshko, S. Dechert, Y.-Q. Zhang, F. Meyer Chem. Eur. J. 2023, 29, e202203494
Janus-type emission from a cyclometalated iron(iii) complex J. Steube , A. Kruse , O. S. Bokareva , T. Reuter, S. Demeshko, R. Schoch, M. A. Argüello Cordero , A. Krishna , S. Hohloch , F. Meyer , K. Heinze , O. Kühn, S. Lochbrunner , M. Bauer Nature Chemistry 2023, 15, 468−474
Multi-Technique Experimental Benchmarking of the Local Magnetic Anisotropy of a Cobalt(II) Single-Ion Magnet S. K. Gupta, H. H. Nielsen, A. M. Thiel, E. A. Klahn, E. Feng, H. B. Cao, T. C. Hansen, E. Lelièvre-Berna, A. Gukasov, I. Kibalin, S. Dechert, S. Demeshko, J. Overgaard, F. Meyer JACS Au 2023, 3, 429−440
Fully Delocalized Mixed-Valent Cu1.5Cu1.5 Complex: Strong Cu-Cu interaction and Fast Electron Self-Exchange Rate Despite Large Structural Changes Y. Liu, S. G. Resch, H. Chen, S. Dechert, S. Demeshko, E. Bill, S. Ye, F. Meyer Angew. Chem. Int. Ed. 2023, 62, e202215840
On the Single-Molecule Magnetic Behavior of Linear Iron(I) Arylsilylamides R. Weller, M. Atanasov, S. Demeshko, T.-Y. Chen, I. Mohelsky, E. Bill, M. Orlita, F. Meyer, F. Neese, C. G. Werncke Inorg. Chem. 2023, 62, 3153−3161
Iodoarene mediated efficient aerobic oxidation of aldehydes for carboxylic acids K. Zeng, A. C. Stückl, J. Qin, M. Simon, C.-J. Spyra, J. Li, F. Meyer, K. Zhang Molecular Catalysis 2023, 537, 112919
Ruthenium Complexes of Rigid, Dianionic, Tetradentate N-Donor Ligands and their Potential as Catalysts for Water Oxidation S. Rajabi, F. Rüttger J. Lücken, S. Dechert, M. John, F. Meyer Eur. J. Inorg. Chem. 2023, 26, e202200597
Short- vs. long-range elastic distortion: structural dynamics of a [2 × 2] tetrairon(II) spin crossover grid complex observed by time-resolved X-Ray crystallography J. de Jesus Velazquez-Garcia, K. Basuroy, D. Storozhuk, J. Wong, S. Demeshko, F. Meyer, R. Henning, S. Techert Dalton Trans. 2022, 51, 17558–17566
A spin crossover FeII4L6 cage based on pyridyl-hydrazone sites W. Li, C. Liu, J. Kfoury, J. Oláh, K. Robeyns, M. L. Singleton, S. Demeshko, F. Meyer, Y. Garcia Chem. Commun. 2022, 58, 11653–11656
Borylation in the Second Coordination Sphere of FeII Cyanido Complexes and Its Impact on Their Electronic Structures and Excited-State Dynamics L. Schmid, P. Chábera, I. Rüter, A. Prescimone, F. Meyer, A. Yartsev, P. Persson, O. S. Wenger Inorg. Chem. 2022, 61, 15853−15863
Luminescent Iridium Complexes with a Sulfurated Bipyridine Ligand: PCET Thermochemistry of the Disulfide Unit and Photophysical Properties M. Oelschlegel, S.-A. Hua, L. Schmid, P. Marquetand, A. Bäck, J.-H. Borter, J. Lücken, S. Dechert, O. S. Wenger, I. Siewert, D. Schwarzer, L. González, F. Meyer Inorg. Chem. 2022, 61, 13944–13955,
Between imide, imidyl and nitrene –an imido iron complex in two oxidation states S. Reith, S. Demeshko, B. Battistella, A. Reckziegel, C.Schneider, A. Stoy, C. Lichtenberg, F. Meyer, D. Munz, C. G. Werncke Chem. Sci. 2022, 13, 7907–7913
Antisymmetric Spin Exchange in a μ‑1,2-Peroxodicopper(II) Complex with an Orthogonal Cu−O−O−Cu Arrangement and S = 1 Spin Ground State Characterized by THz-EPR T. Lohmiller, C.-J. Spyra, S. Dechert, S. Demeshko, E. Bill, A. Schnegg, F. Meyer JACS Au. 2022, 2, 134−1143.
Organometallic μ‑Nitridodiiron Complexes in Oxidation States Ranging from (III/III) to (IV/IV) C. Cordes (née Kupper), I. Klawitter, I. Rüter, S. Dechert, S. Demeshko, S. Ye, F. Meyer Inorg. Chem. 2022, 61, 7153−7164.
Polynuclear Iron(II) Pyridonates: Synthesis and Reactivity of Fe4 and Fe5 Clusters A. Fedulin, S. K. Gupta, I. Rüter, F. Meyer, A. Jacobi von Wangelin Inorg. Chem. 2022, 61, 6149−6159.
Solar Light-Assisted Oxidative Degradation of Ciprofloxacin in Aqueous Solution by Iron(III) Chelated Cross-Linked Chitosan Immobilized on a Glass Plate S. Saha, T. Kumar Saha, S. Karmaker, Z. Islam, S. Demeshko, H. Frauendorf, F. Meyer Catalysts. 2022, 12, 475.
Iron(III) Complexes of a Hexadentate Thioether-Appended 2 Aminophenol Ligand: Redox-Driven Spin State Switchover A. Ali, S. Bhowmik, S. K. Barman, N. Mukhopadhyay, C. E. Glüer (née Schiewer), F. Lloret, F. Meyer, R. Mukherjee Inorg. Chem. 2022, 61, 5292−5308.
Metal-to-metal communication during the spin state transition of a [2 × 2] Fe(II) metallogrid at equilibrium and out-of-equilibrium conditions J. de Jesus Velazquez-Garcia, K. Basuroy, D. Storozhuk, J. Wong, S. Demeshko, F. Meyer, R. Henning, S. Techert Dalton Trans. 2022, 51, 6036–6045.
Combining Valence-to-Core X‑ray Emission and Cu K‑edge X‑ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes B. L. Geoghegan, Y. Liu, S. Peredkov, S. Dechert, F. Meyer, S. DeBeer, G. E. Cutsail III J. Am. Chem. Soc. 2022, 144, 2520−2534.
Macrocycle based dinuclear dysprosium(III) single molecule magnets with local D5h coordination geometry J. Wu, S. Demeshko, S. Dechert, F. Meyer Dalton Trans. 2021, 50, 17573–17582
Single-molecule magnets within polyoxometalate-based frameworks M. Babaei Zarch, M. Mirzaei, M. Bazargan, S. K. Gupta, F. Meyer, J. T. Mague Dalton Trans. 2021, 50, 15047–15056
A Monohydrosulfidodinitrosyldiiron Complex That Generates N2O as a Model for Flavodiiron Nitric Oxide Reductases: Reaction Mechanism and Electronic Structure N. Pal, C. J. White, S. Demeshko, F. Meyer, N. Lehnert, A. Majumdar Inorg. Chem. 2021, 60, 15890−15900
Modulation of a μ 1,2-Peroxo Dicopper(II) Intermediate by Strong Interaction with Alkali Metal Ions A. Brinkmeier,K. E. Dalle, L. D’Amore, R. A. Schulz, S. Dechert, S. Demeshko, M. Swart, F. Meyer J. Am. Chem. Soc. 2021, 143, 17751−17760
Synthesis and characterisation of a very low-coordinate diferrous [2Fe–2S]0 unit C. Schneider, S. J. Groß, S. Demeshko, S. Bontemps, F. Meyer, C. G. Werncke Chem. Commun. 2021, 57, 10751–10754
Oxidative Degradation of Azo Dyes in Aqueous Solution by Water-Soluble Iron Porphyrin Catalyst T. Kumar Saha, H. Frauendorf, F. Meyer Eur. J. Inorg. Chem. 2021, 2870 – 2881
Structurally Characterized μ-1,2-Peroxo/Superoxo Dicopper(II) Pair A. Brinkmeier, R. A. Schulz, M. Buchhorn, C-J.Spyra, S. Dechert, S. Demeshko, V. Krewald, and F. Meyer J. Am. Chem. Soc. 2021,27, 10361–10366
Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N2 to N(SiMe3)3 M. Li, S. K. Gupta, S. Dechert, S. Demeshko, F. Meyer Angew.Chem. Int.Ed. 2021, 60, 14480 –14487
A Bioinspired Disulfide/Dithiol Redox Switch in a Rhenium Complex as Proton, H Atom, and Hydride Transfer Reagent S-A. Hua, L. A. Paul, M. Oelschlegel, S. Dechert, F. Meyer, and I. Siewert J. Am. Chem. Soc. 2021, 16, 6238–6247
A Molecular Low-Coordinate [Fe-S-Fe] Unit in Three Oxidation States C. Schneider, S. Demeshko,F. Meyer, C. G. Werncke Chem. Eur.J. 2021, 27, 6348 –6353
Selective Electrocatalytic CO2 Reduction to CO by an NHC-Based Organometallic Heme Analogue A. A. Massie, C. Schremmer, I. Rüter, S. Dechert, I. Siewert, F. Meyer ACS Catal., 2021, 11, 3257–3267
Iron(II), Cobalt(II), and Nickel(II) Complexes of Bis(sulfonamido)benzenes: Redox Properties, Large Zero-Field Splittings, and Single-Ion Magnets H. Bamberger, U. Albold, J. D. Midlíková, C-Y. Su, N. Deibel, D. Hunger, P. P. Hallmen, P. Neugebauer, J. Beerhues, S. Demeshko, F. Meyer, B. Sarkar, and J. v. Slageren Inorg. Chem., 2021, 60, 2953–2963
Widening the Window of Spin-Crossover Temperatures in Bis(formazanate)iron(II) Complexes via Steric and Noncovalent Interactions F. Milocco, F. de Vries, H. S. Siebe, S. Engbers, S. Demeshko, F. Meyer, E. Otten Inorg. Chem., 2021, 60, 2045−2055
Excited-State Dynamics of [Ru(S−S bpy)(bpy)2] 2+ to Form Long-Lived Localized Triplet States M. Heindl, J. Hongyan, S.-A. Hua, M. Oelschlegel, F. Meyer, D. Schwarzer, L. Gonzalez Inorg. Chem., 2021, 60, 1672−1682
Iron-Catalyzed Triazole-Enabled C−H Activation with Bicyclopropylidenes J. Mo, A. M. Messinis, J. C. A. Oliveira, S. Demeshko, F. Meyer, L. Ackermann ACS Catal., 2021, 11, 1053−1064
Ligand Protonation Triggers H2 Release from a Dinickel Dihydride Complex to Give a Doubly "T"-Shaped Dinickel(I) Metallodiradical P.-C. Duan, R. A. Schulz, A. Römer, B. E. Van Kuiken, S. Dechert, Se. Demeshko, G. E. Cutsail III, S. DeBeer, R. A. Mata, F. Meyer Angew. Chem. Int. Ed., 2021, 60, 1891– 1896
Time-Resolved Spectroscopy of Photoinduced Electron Transfer in Dinuclear and Tetranuclear Fe/Co Prussian Blue Analogues J. Zimara, H. Stevens, R. Oswald, S. Demeshko, S. Dechert, R. A. Mata, F. Meyer, D. Schwarzer Inorg. Chem., 2021, 60, 449-459
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