个人简介

B.S. in Chemistry, Wuhan University, Hubei, The People’s Republic of China, 1982 M.S. in Physical and Inorganic Chemistry, Chinese Science Academy, Fuzhou, the People’s Republic of China, 1985 M.S. in Organometallic Chemistry, University of California, San Diego, CA, 1987 Ph. D. in Organic and Inorganic Chemistry, Stanford University, Stanford, CA, 1992 Postdoctoral and Research Associate, Department of Chemistry, Stanford University, Stanford, CA, 1992-1994 Assistant Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 1994-1999 Associate Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 1999-2003 Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 2003-2006 Professor of Organic Chemistry, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, NJ, 2007 AWARDS & HONORS Franklin Veatch Graduate Fellowship, 1991, Stanford University The Camille and Henry Dreyfus Foundation New Faculty Award, 1994 DuPont Young Faculty Award, 1996 Office of Naval Research Young Investigator Award, 1996 The Camille and Henry Dreyfus Foundation Teacher-Scholar Award, 1998 The John Simon Guggenheim Foundation Fellow, 2000 The Outstanding Oversea Chinese Young Scientist B, Chinese Academy of Sciences, 2000 The Penn State Faculty Scholar Medal, 2001 The Young Innovation Award of ChiTec (Chinese High Tech) in Chemistry, 2001 The American Chemical Society Arthur C. Cope Scholar Award, 2002 The SDCA (San Diego Chinese Association) Achievement Award, 2002

研究领域

Inorganic Chemistry/Organic Chemistry

Synthetic organic, inorganic and organometallic chemistry, transition metal catalyzed asymmetric reactions for the synthesis of biologically active compounds, biomimetic chemistry, molecular recognition and material chemistry.

近期论文

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(109) " Rhodium-catalyzed direct oxidative carbonylation of aromatic C-H bond with CO and alcohols" Guan, Z.; Ren, Z.; Spinella, S. M.; Yu, S.; Liang, Y.; Zhang, X. J. Am. Chem. Soc. 2009, 131, 729-733. " Highly Efficient and Highly Enantioselective Asymmetric Hydrogenation of Ketones with TunePhos/1,2-Diamine-Ruthenium(II) Complexes" Li, W.; Sun, X.; Zhou, L.; Hou, G.; Yu, S.; Zhang, X. J. Org. Chem. 2009, 74, 1397-1399. " Efficient synthesis of chiral b-arylisopropylamines by using catalytic asymmetric hydrogenation" Chen, J.; Zhang, W.; Geng, H.; Li, W.; Hou, G.; Zhang, X. Angew. Chem. Int. Ed. 2009, 48, 800-802. " Axially 4,4'-di-tert-butyl TunePhos-type chiral diphosphine ligand: synthesis and applications in asymmetric hydrogenation" Wang, C.-J.; Wang, C.-B.; Chen, D; Yang, G.; Wu, Z.; Zhang, X. Tetrahedron Lett. 2009, 50, 1038-1040. " Highly regioselective and rapid hydroformylation of alkyl acrylates catalyzed by a rhodium complex with a tetraphosphorus ligand" (113) Yu, S.; Chie, Y.-M.; Zhang, X. Adv. Syn. Cat. 2009, 351, 537-540. " Axially Enantioselective Hydrogenation of N-H Imines" Hou, G.; Gosselin, F.; Li, W.; McWilliams, J. C.; Sun, Y.; Weisel, M.; O'Shea, P. D.; Chen, C.; Davies, I. W.; Zhang, X. J. Am. Chem. Soc. 2009, 131, 9882-9883. " Spiro[4,4]-1,6-nonadiene-based phosphine-oxazoline ligands for iridium-catalyzed enantioselective Hydrogenation of Ketimines" Han, Z.; Wang, Z.; Zhang, X.; Ding, K. Angew. Chem. Int. Ed. 2009, 48, 5345-5349. " Matching and mismatching effects of hybrid chiral biaxial bisphosphine ligands in enantioselective hydrogenation of ketoesters" Sun, X.; Li, W.; Zhou, L.; Zhang, X. Chem. Eur. J. 2009, 15, 7302-7305 " Rhodium-catalyzed enantioselective and diastereoselective hydrogenation of beta-ketoenamides: Efficient access to anti 1,3-amino alcohols" Geng, H.; Zhang, W.; Chen, J.; Hou, G.; Zhou, L.; Zou, Y.; Wu, W.; Zhang, X. Angew. Chem. Int. Ed. 2009, 48, 6052-6054. " Highly regioselective hydroformylation of 1,5-hexadiene to linear dialdehyde catalyzed by rhodium complexes with tetraphosphorus ligands" Yu, S.; Chie, Y.-M.; Zhang, X.; Dai, L.; Zhang, X. Tetrahedron Lett. 2009, 50, 5575-5577. " Axially chiral electron-rich TunePhos-type ligand: synthesis and applications in asymmetric hydrogenation" Zou, Y.; Geng, H.; Zhang, W.; Yu, S.; Zhang, X. Tetrahedron Lett. 2009, 50, 5777-5779. " Suzuki coupling of heteroaromatic chlorides using highly electron-donating ClickPhos ligands" Spinella, S. M.; Guan, Z.-H.; Chen, J.; Zhang, X. Synthesis 2009, 18, 3094-3098. " Axial chirality control by 2,4-pentanediol for the alternative synthesis of C3*-TunePhos chiral diphosphine ligands and their applications in highly enantioselective ruthenium-catalyzed hydrogenation of beta-keto esters." Sun, X.; Li, W.; Hou, G.; Zhou, L.; Zhang, X. Adv. Syn. Cat. 2009, 351, 2553-2557. " Highly efficient and enantioselective iridium-catalyzed asymmetric hydrogenation of N-arylimines" Li, W.; Hou, G.; Chang, M.; Zhang, X. Adv. Syn. Cat. 2009, 351, 3123-3127. " Synthesis and application of modular phosphine-phosphoramidite ligands in asymmetric hydroformylation: Structure-selectivity relationship" Zhang, X.; Cao, B.; Yan, Y.; Yu, S.; Ji, B.; Zhang, X. Chem. Eur. J. 2010, 16, 871-877. " Mechanistic investigation of chiral phosphoric acid catalyzed asymmetric Baeyer-Villiger reaction of 3-Ssubstituted cyclobutanones with H2O2 as the oxidant" Xu, S.; Wang, Z.; Li, Y.; Zhang, X.; Wang, H.; Ding, K. Chem. Eur. J. 2010, 16, 3021-3035. " Iridium-monodentate phosphoramidite-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines" Hou, G.; Tao, R.; Sun, Y.; Zhang, X.; Gosselin, F. J. Am. Chem. Soc. 2010, 132, 2124-2125. " Synthesis and application of tetraphosphane ligands in rhodium-catalyzed hydroformylation of terminal olefins: High regioselectivity at high temperature" Yu, S.; Zhang, X.; Yan, Y.; Cai, C.; Dai, L.; Zhang, X. Chem. Eur. J. 2010, 16, 4938-4943. " Highly efficient Rh-catalyzed asymmetric hydrogenation of beta-amino acrylonitriles" Ma, M.; Hou, G.; Sun, T.; Zhang, X.; Li, W.; Wang, J.; Zhang, X. Chem. Eur. J. 2010, 16, 5301-5304. " Enantioselective hydrogenation of beta-dehydroamino acid esters catalyzed by rhodium complexes with chiral bisaminophosphine ligands" Sun, X.; Li, W.; Zhou, L.; Zhang, X. Adv. Syn. Cat. 2010, 352, 1150-1154.