个人简介

PhD, Chemistry, University of Cambridge (UK) 2002 BSc, Chemistry and Biochemistry, University of Auckland, NZ (1997) Phi Beta Kappa, Recognition for Excellence in Teaching and Mentorship (2010) NSF Career Award (2009) Thieme Synlett/Synthesis Journal Award (2009) Lilly New Faculty Award (2005) Commonwealth Scholarship to the University of Cambridge (2001) Trinity College External Research Scholarship (2001)

研究领域

Organic Synthesis and Catalysis

CHEM 521: Advanced Organic Chemistry I (Grad) CHEM 190: Freshman Seminar: Herbal Remedies to Anticancer Drugs CHEM 221: Organic Chemistry I

近期论文

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A C-H Functionalization Protocol for the Direct Synthesis of Benzobisthiazole Derivatives Bon, J. L.; Feng, D.; Marder, S. R.; Blakey, S. B. J. Org. Chem. 2014. DOI: 10.1021/jo501416j Iridium(III)-bis(oxazolinyl)phenyl Catalysts for Enantioselective C-H Functionalization Owens C. P.; Varela-Álvarez, A.; Boyarskikh, V.; Musaev, D. G.; Davies, . M. L.; Blakey S. B. Chem. Sci. 2013, 4, 2590 Unveiling Latent α-Iminocarbene Reactivity from Alkynes Through Oxidative Amination/Intermolecular Cascade Reactions Mace, N.; Thornton, A. R.; Blakey, S. B. Angew. Chem. Int. Ed. 2013, 52, 5836 Insight into Mechanistic Features of Ruthenium(II)-Pybox-Catalyzed C–H Amination Musaev, D. G.; Blakey, S. B. Organometallics 2012, 31, 4950 Intramolecular Olefin Diamination for the Stereoselective Synthesis of 3-Aminopiperidines Kong, A.; Blakey, S. B. Synthesis 2012, 44, 1190 (Invited contribution for special issue on hypervalent iodine oxidants) Synthesis of Ruthenium(II) 2,6-Bis(imino)pyridyl Complexes for C-H Amination of Sulfamate Esters Bon, J. L.; Blakey, S. B.; Heterocycles 2012, 84, 1313 (Invited contribution honoring Prof. Padwa on his 75th birthday) Rhodium Catalyzed Allene Amination: A Facile Entry into 2‑Amidoallylcations for Unusual [3+3] Annulation Reactions Stoll, A. H.; Blakey, S. B. Chem. Sci. 2011, 2, 112 Copper-Catalyzed Olefin Aminoacetoxylation Mancheno, D. E.; Thornton, A. R.; Stoll, A. H.; Kong, A.; Blakey, S. B. Org. Lett. 2010, 13, 4110 Rhodium Catalyzed Allene Amination: Diastereoselective Synthesis of Aminocyclopropanes via a 2-Amidoallylcation Intermediate Stoll, A. H.; Blakey, S. B. J. Am. Chem. Soc. 2010, 132, 2108 (Featured on the cover of issue 7, Feb. 24th 2010) Cascade Annulation Reactions to Access the Structural Cores of Stereochemically Unusual Strychnos Alkaloids Delgado, R.; Blakey, S. B. Eur. J. Org. Chem. 2009, 1506 π-Nucleophile Traps for Metallonitrene/Alkyne Cascade Reactions: A Versatile Process for the Synthesis of α-Aminocyclopropanes and β‑Aminostyrenes Thornton, A. R.; Martin, V. I.; Blakey, S. B. J. Am. Chem. Soc. 2009, 131, 2434 Synthesis and Reactivity of an Unprecedented Os(VIII) Alkylidene Martin, V. I.; Blakey, S. B. Tetrahedron Lett., 2008, 49, 6800. Enantioselective C–H Amination Using Cationic Ru(II)-pybox Catalysts Milczek E.; Boudét, N.; Blakey, S. Angew. Chem., Int. Ed., 2008, 47, 6825. (Paper highlighted in Synfacts, 2008, 11, 1184) Catalytic Metallonitrene/Alkyne Metathesis: A Powerful Cascade Process for the Synthesis of Nitrogen-Containing Molecules Thornton, A. R.; Blakey, S. B. J. Am. Chem. Soc., 2008, 130, 5020. (Paper highlighted in Synfacts, 2008, 7, 691) Enantioselective C-H Amination Boudét, N.; Blakey, S. In "Chiral Amine Synthesis, Methods, Developments and Applications", T. C. Nugent Ed.; Wiley-VCH: Weinheim, 2010, p 377-396 Publications Prior to Emory Total Synthesis of Aplyronine C Paterson, I.; Fink, S. J.; Lee, L. Y. W.; Atkinson, S. J.; Blakey, S. B. Org. Lett. 2013, 15, 3118 Total Synthesis of Diazonamide A Knowles, R. R.; Carpenter, J.; Blakey, S. B.; Kayano, A.; Mangion, I. K.; Sinz, C. J.; MacMillan, D. W. C. M. Chem. Sci. 2011, 2, 308 The First Suzuki Cross-Couplings of Aryltrimethylammonium Salts Blakey, S. B.; MacMillan, D. W. C. J. Am. Chem. Soc. 2003, 125, 6046 Studies in marine macrolide synthesis: stereocontrolled synthesis of a C21-C34 subunit of the aplyronines Paterson, I.; Blakey, S. B.; Cowden, C. J. Tetrahedron Lett. 2002, 43, 6005 cis-1,2-Dihydrocatechols in Chemical Synthesis: First synthesis of L-ascorbic acid (vitamin C) from a non-carbohydrate source Banwell, M.; Blakey, S.; Harfoot, G.; Longmore, R. Aust. J. Chem. 1999, 52, 137 First synthesis of L-ascorbic acid (vitamin C) from a non-carbohydrate source Banwell, M.; Blakey, S.; Harfoot, G.; Longmore, R. J. Chem. Soc., Perkin Trans. 1, 1998, 3141.