熊仁根 - 东南大学 - 化学化工学院

个人简介

Prof. Ren-Gen Xiong ( 熊仁根教授 ) Education 1991-1994 Ph. D. in Mechanical Lubrication Engineering, Logistical Engineering College 1985-1987 M. S. in Chemistry, Yanbian University 1978-1982 B. S. in Chemistry, Jiangxi University Academic Career 2006-present Professor and Director of Order Matter Science Research Center, Southeast University. 1998-2006 Professor, Nanjing University. 1997-1998 Postdoctoral associate, Brandeis University. 1996-1997 Postdoctoral associate, University of Puerto Rico. 1994-1996 Postdoctoral associate, Nanjing University. Honors and Awards 2017 Second Prizes in China’s State Natural Science Award. 2004 Second Prizes in China’s State Natural Science Award. 2015 First Prize in Natural Science of the Ministry of Education. 2002 First Prize in Natural Science of the Ministry of Education 2004 Cheung Kong Scholar Professor. 2015 Jiangsu Province May 1 Labor Medal. 2005 National Excellent Postdoctoral Fellow.

近期论文

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1. Ai, Y.; Li, P.-F.; Yang, M.-J.; Xu, Y.-Q.; Li, M.-Z.; Xiong, R.-G. * "An organic plastic ferroelectric with high Curie point", Chem. Sci. 2022 , 13 (3), 748-753. 2. Liao, W.-Q.; Zeng, Y.-L.; Tang, Y.-Y.; Peng, H.; Liu, J.-C.; Xiong, R.-G.* "Multichannel Control of Multiferroicity in Single-Component Homochiral Organic Crystals", J. Am. Chem. Soc. 2021, 143 (51), 21685-21693. 3. Ai, Y.; Sun, R.; Zeng, Y.-L.; Liu, J.-C.; Tang, Y.-Y.; Wang, B.-W.; Wang, Z.-M.; Gao, S.*; Xiong, R.-G. * "Coexistence of magnetic and electric orderings in a divalent Cr 2+ -based multiaxial molecular ferroelectric", Chem. Sci. 2021 , 12 (28), 9742-9747. 4. Ai, Y.; Lv, H.-P.; Wang, Z.-X.*; Liao, W.-Q.; Xiong, R.-G. * "H/F substitution for advanced molecular ferroelectrics", Trends Chem. 2021 , 3 (12), 1088-1099. 5. Liao, W.-Q.*; Deng, B.-B.; Wang, Z.-X.*; Cheng, T.-T.; Hu, Y.-T.; Cheng, S.-P.; Xiong, R.-G. * "Optically Induced Ferroelectric Polarization Switching in a Molecular Ferroelectric with Reversible Photoisomerization", Adv. Sci. 2021 , 8 (24), 2102614. 6. Tang, Y.-Y.*; Liu, J.-C.; Zeng, Y.-L.; Peng, H.; Huang, X.-Q.; Yang, M.-J.; Xiong, R.-G. * "Optical Control of Polarization Switching in a Single-Component Organic Ferroelectric Crystal", J. Am. Chem. Soc. 2021 , 143 (34), 13816-13823. 7. Huang, C.-R.; Li, Y. * ; Xie, Y.; Du, Y.; Peng, H.; Zeng, Y.-L.; Liu, J.-C.; Xiong, R.-G. * "The First High-Temperature Supramolecular Radical Ferroics", Angew. Chem. Int. Ed. 2021 , 60 (30), 16668-16673. 8. Zhang, H.-Y.; Chen, X.-G.; Tang, Y.-Y. * ; Liao, W.-Q.; Di, F.-F.; Mu, X.; Peng, H.; Xiong, R.-G. * "PFM (piezoresponse force microscopy)-aided design for molecular ferroelectrics", Chem. Soc. Rev. 2021 , 50 (14), 8248-8278. 9. Song, X.-J.; Zhang, T.; Gu, Z.-X.; Zhang, Z.-X.; Fu, D.-W. * ; Chen, X.-G.; Zhang, H.-Y.; Xiong, R.-G. * "Record Enhancement of Curie Temperature in Host-Guest Inclusion Ferroelectrics", J. Am. Chem. Soc. 2021 , 143 (13), 5091-5098. 10. Zhang, H.-Y.; Zhang, Z.-X.; Chen, X.-G.; Song, X.-J.; Zhang, Y.; Xiong, R.-G. * "Large Electrostrictive Coefficient in a Two-Dimensional Hybrid Perovskite Ferroelectric", J. Am. Chem. Soc. 2021 , 143 (3), 1664-1672. 11. Huang, C.-R.; Luo, X.-Z.*; Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Xiong, R.-G. * "A multiaxial lead-free two-dimensional organic-inorganic perovskite ferroelectric", Natl. Sci. Rev. 2021 , 8 (5), nwaa232. 12. Tang, Y.-Y.*; Xie, Y.; Ai, Y.; Liao, W.-Q.; Li, P.-F.; Nakamura, T.; Xiong, R.-G. * "Organic Ferroelectric Vortex-Antivortex Domain Structure", J. Am. Chem. Soc. 2020 , 142 (52), 21932-21937. 13. Zhang, H.-Y.; Zhang, Z.-X.; Song, X.-J.; Chen, X.-G.; Xiong, R.-G. * "Two-Dimensional Hybrid Perovskite Ferroelectric Induced by Perfluorinated Substitution", J. Am. Chem. Soc. 2020 , 142 (47), 20208-20215. 14. Zhang, H.-Y.*; Chen, X.-G.; Zhang, Z.-X.; Song, X.-J.; Zhang, T.; Pan, Q.; Zhang, Y.; Xiong, R.-G. * "Methylphosphonium Tin Bromide: A 3D Perovskite Molecular Ferroelectric Semiconductor", Adv. Mater. 2020 , 32 (47), 2005213. 15. Zhang, Z.-X.; Zhang, H.-Y.*; Zhang, W.; Chen, X.-G.; Wang, H.; Xiong, R.-G. * "Organometallic-Based Hybrid Perovskite Piezoelectrics with a Narrow Band Gap", J. Am. Chem. Soc. 2020 , 142 (41), 17787-17794. 16. Liu, H.-Y.; Zhang, H.-Y.*; Chen, X.-G.; Xiong, R.-G. * "Molecular Design Principles for Ferroelectrics: Ferroelectrochemistry", J. Am. Chem. Soc. 2020 , 142 (36), 15205-15218. 17. Tang, Y.-Y.*; Xie, Y.; Zeng, Y.-L.; Liu, J.-C.; He, W.-H.; Huang, X.-Q.; Xiong, R.-G. * "Record Enhancement of Phase Transition Temperature Realized by H/F Substitution", Adv. Mater. 2020 , 32 (36), 2003530. 18. Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Zhang, H.-Y.; Pan, Q.; Yao, J.; You, Y.-M.*; Xiong, R.-G. * "Confinement-Driven Ferroelectricity in a Two-Dimensional Hybrid Lead Iodide Perovskite", J. Am. Chem. Soc. 2020 , 142 (22), 10212-10218. 19. Song, X.-J.; Zhang, Z.-X.; Chen, X.-G.; Zhang, H.-Y.; Pan, Q.; Yao, J.; You, Y.-M.*; Xiong, R.-G. * "Bistable State of Protons for Low-Voltage Memories", J. Am. Chem. Soc. 2020 , 142 (19), 9000-9006. 20. Xiong, R.-G. *; Lu, S.-Q.; Zhang, Z.-X.; Cheng, H.; Li, P.-F.*; Liao, W.-Q.*"A Chiral Thermochromic Ferroelastic with Seven Physical Channel Switches", Angew. Chem. Int. Ed. 2020 , 59 (24), 9574-9578. * Zhang, H.-Y.; Song, X.-J.; Chen, X.-G.; Zhang, Z.-X.; You, Y.-M.; Tang, Y.-Y.*; Xiong, R.-G. * "Observation of Vortex Domains in a Two-Dimensional Lead Iodide Perovskite Ferroelectric", J. Am. Chem. Soc. 2020 , 142 (10), 4925-4931. 22. Zhang, H.-Y.; Song, X.-J.; Cheng, H.; Zeng, Y.-L.; Zhang, Y.; Li, P.-F.; Liao, W.-Q.; Xiong, R.-G. * "A Three-Dimensional Lead Halide Perovskite-Related Ferroelectric", J. Am. Chem. Soc. 2020 , 142 (10), 4604-4608. 23. Zhang, Y.*; Song, X.-J.; Zhang, Z.-X.; Fu, D.-W.; Xiong, R.-G. * "Piezoelectric Energy Harvesting Based on Multiaxial Ferroelectrics by Precise Molecular Design", Matter 2020 , 2 (3), 697-710. 24. Liu, J.-C.; Liao, W.-Q.*; Li, P.-F.*; Tang, Y.-Y.; Chen, X.-G.; Song, X.-J.; Zhang, H.-Y.; Zhang, Y.; You, Y.-M.; Xiong, R.-G. * "A Molecular Thermochromic Ferroelectric", Angew. Chem. Int. Ed. 2020 , 59 (9), 3495-3499. 25. Zhang, H.-Y.; Hu, C.-L.; Hu, Z.-B.; Mao, J.-G.; Song, Y.; Xiong, R.-G. * "Narrow Band Gap Observed in a Molecular Ferroelastic: Ferrocenium Tetrachloroferrate", J. Am. Chem. Soc. 2020 , 142 (6), 3240-3245. 26. Wei, Z.-H.; Jiang, Z.-T.; Zhang, X.-X.; Li, M.-L.; Tang, Y.-Y.; Chen, X.-G.; Cai, H.*; Xiong, R.-G. * "Rational Design of Ceramic-Like Molecular Ferroelectric by Quasi-Spherical Theory", J. Am. Chem. Soc. 2020 , 142 (4), 1995-2000. 27. Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Li, P.-F.; Ge, J.-Z.; Tang, Y.-Y.; Gao, J.-X.; Zhang, W.-Y.; Fu, D.-W.*; You, Y.-M.; Xiong, R.-G. * "Two-Dimensional Layered Perovskite Ferroelectric with Giant Piezoelectric Voltage Coefficient", J. Am. Chem. Soc. 2020 , 142 (2), 1077-1082. 28. Shi, P.-P.; Lu, S.-Q.; Song, X.-J.; Chen, X.-G.; Liao, W.-Q.*; Li, P.-F.; Tang, Y.-Y.*; Xiong, R.-G. * "Two-Dimensional Organic-Inorganic Perovskite Ferroelectric Semiconductors with Fluorinated Aromatic Spacers", J. Am. Chem. Soc. 2019 , 141 (45), 18334-18340. 29. Tang, Y.-Y.*; Ai, Y.; Liao, W.-Q.; Li, P.-F.; Wang, Z.-X.; Xiong, R.-G. * "H/F‐Substitution‐Induced Homochirality for Designing High‐ T c Molecular Perovskite Ferroelectrics". Adv. Mater. 2019 , 31 (29), 1902163. 30. Zhang, H.-Y.; Tang, Y.-Y.; Shi, P.-P.; Xiong, R.-G. * "Toward the Targeted Design of Molecular Ferroelectrics: Modifying Molecular Symmetries and Homochirality", Acc. Chem. Res. 2019 , 52 (7), 1928-1938. 31. Xiong, Y.-A.; Sha, T.-T.; Pan, Q.; Song, X.-J.; Miao, S.-R.; Jing, Z.-Y.; Feng, Z.-J.; You, Y.-M.*; Xiong, R.-G. * "The First Nickel(II)-Nitrite-Based Molecular Perovskite Ferroelectric", Angew. Chem. Int. Ed. 2019 , 58 (26), 8857-8861. 32. Yang, C.-K.; Chen, W.-N.; Ding, Y.-T.; Wang, J.; Rao, Y.; Liao, W.-Q.*; Tang, Y.-Y.; Li, P.-F.; Wang, Z.-X.; Xiong, R.-G. * "The First Two-Dimensional Homochiral Lead Iodide Perovskite Ferroelectrics: [ R - and S -1-(4-chlorophenyl)ethylammonium] 2 PbI 4 ", Adv. Mater. 2019 , 31 (16), 1808088. 33. Li, P.-F.; Liao, W.-Q.; Tang, Y.-Y.; Qiao, W.; Zhao, D.*; Ai, Y.; Yao, Y.-F.*; Xiong, R.-G. * "Organic enantiomeric high- T c ferroelectrics", Proc. Natl. Acad. Sci. USA. 2019 , 116 (13), 5878-5885. 34. Liao, W.-Q.; Zhao, D.; Tang, Y.-Y.; Zhang, Y.; Li, P.-F.; Shi, P.-P.; Chen, X.-G.; You, Y.-M.; Xiong, R.-G. * "A molecular perovskite solid solution with piezoelectricity stronger than lead zirconate titanate", Science 2019 , 363 (6432), 1206-1210. 35. Ai, Y.; Chen, X.-G.; Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Xiong, R.-G. * "Fluorine Substitution Induced High T c of Enantiomeric Perovskite Ferroelectrics: ( R )- and ( S )-3-(Fluoropyrrolidinium)MnCl 3 ", J. Am. Chem. Soc. 2019 , 141 (10), 4474-4479. 36. Wang, Z.-X.; Zhang, Y.; Tang, Y.-Y.; Li, P.-F.; Xiong, R.-G. * "Fluoridation Achieved Antiperovskite Molecular Ferroelectric in [(CH 3 ) 2 (F-CH 2 CH 2 )NH] 3 (CdCl 3 )(CdCl 4 )", J. Am. Chem. Soc. 2019 , 141 (10), 4372-4378. 37. Yang, C.-K.; Chen, W.-N.; Ding, Y.-T.; Wang, J.; Rao, Y.; Liao, W.-Q.; Xie, Y.*; Zou, W.*; Xiong, R.-G. * "Directional Intermolecular Interactions for Precise Molecular Design of a High- T c Multiaxial Molecular Ferroelectric", J. Am. Chem. Soc. 2019 , 141 (4), 1781-1787. 38. Hua, X.-Ni.; Liao, W.-Q.*; Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Zhao, D.; Xiong, R.-G. * "A Room-Temperature Hybrid Lead Iodide Perovskite Ferroelectric", J. Am. Chem. Soc. 2018 , 140 (38), 12296-12302. 39. Li, P.-F.; Tang, Y.-Y.; Liao, W.-Q.; Shi, P.-P.; Hua, X.-N.; Zhang, Y.; Wei, Z.; Cai, H.; Xiong, R.-G. * "Experimental Evidence for a Triboluminescent Antiperovskite Ferroelectric: Tris(trimethylammonium) catena-Tri-μ-chloromanganate(II) Tetrachloromanganate(II)", Angew. Chem. Int. Ed. 2018 , 57 (37), 11939-11942. 40. Ye, H.-Y.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Gao, J.-X.; Hua, X.-N.; Cai, H.; Shi, P.-P.; You, Y.-M.*; Xiong, R.-G. * "Metal-free three-dimensional perovskite ferroelectrics", Science 2018 , 361 (6398), 151-155. 41. Wei, Z.; Liao, W.-Q.; Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Cai, H.; Xiong, R.-G. * "Discovery of an Antiperovskite Ferroelectric in [(CH 3 ) 3 NH] 3 (MnBr 3 )(MnBr 4 )", J. Am. Chem. Soc. 2018 , 140 (26), 8110-8113. 42. Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Shi, P.-P.; You, Y.-M.; Xiong, R.-G. * "Multiaxial Molecular Ferroelectric Thin Films Bring Light to Practical Applications", J. Am. Chem. Soc. 2018 , 140 (26), 8051-8059. 43. Zhang, H.-Y.; Wei, Z.; Li, P.-F.; Tang, Y.-Y.; Liao, W.-Q.; Ye, H.-Y.; Cai, H.*; Xiong, R.-G. * "The Narrowest Band Gap Ever Observed in Molecular Ferroelectrics: Hexane-1,6-diammonium Pentaiodobismuth(III)", Angew. Chem. Int. Ed. 2018 , 57 (2), 526-530. 44. Liao, W.-Q.; Tang, Y.-Y.; Li, P.-F.; You, Y.-M.*; Xiong, R.-G. * "Large Piezoelectric Effect in a Lead-Free Molecular Ferroelectric Thin Film", J. Am. Chem. Soc. 2017 , 139 (49), 18071-18077. 45. Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Zhang, W.-Y.; Wang, Z.-X.; You, Y.-M.*; Ye, H.-Y.; Nakamura, T.; Xiong, R.-G. * "Visualization of room-temperature ferroelectricity and polarization rotation in the thin film of quinuclidinium perrhenate", Phys. Rev. Lett. 2017 , 119 (20), 207602. 46. Jornet-Mollá, V.; Duan, Y.; Giménez-Saiz, C.; Tang, Y.-Y.; Li, P.-F.; Romero, F. M.*; Xiong, R.-G. * "A Ferroelectric Iron(II) Spin Crossover Material", Angew. Chem. Int. Ed. 2017 , 56 (45), 14052-14056. 47. Tang, Y.-Y.; Li, P.-F.; Zhang, W.-Y.; Ye, H.-Y.; You, Y.-M.*; Xiong, R.-G. * "A Multiaxial Molecular Ferroelectric with Highest Curie Temperature and Fastest Polarization Switching", J. Am. Chem. Soc. 2017 , 139 (39), 13903-13908. 48. Zhang, W.-Y.; Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Liao, W.-Q.; Fu, D.-W.*; Ye, H.-Y.; Zhang, Y.; Xiong, R.-G. * "Precise Molecular Design of High T c 3D Organic-Inorganic Perovskite Ferroelectric: [MeHdabco]RbI 3 (MeHdabco = N-Methyl-1,4-diazoniabicyclo[2.2.2]octane)", J. Am. Chem. Soc. 2017 , 139 (31), 10897-10902. 49. Pan, Q.; Liu, Z.-B.; Zhang, H.-Y.; Zhang, W.-Y.; Tang, Y.-Y.; You, Y.-M.*; Li, P.-F.; Liao, W.-Q.; Shi, P.-P.; Ma, R.-W.; Wei, R.-Y.; Xiong, R.-G. * "A Molecular Polycrystalline Ferroelectric with Record-High Phase Transition Temperature", Adv. Mater. 2017 , 29 (29), 1700831. 50. Zhang, Z.; Li, P.-F.; Tang, Y.-Y.; Wilson, A.-J.; Willets, K.; Wuttig, M.*; Xiong, R.-G. *; Ren S.* "Tunable electroresistance and electro-optic effects of transparent molecular ferroelectrics", Sci. Adv. 2017 , 3 (8), e1701008. 51. You, Y.-M.*; Liao, W.-Q.; Zhao, D.; Ye, H.-Y.; Zhang, Y.; Zhou, Q.; Niu, X.; Wang, J.; Li, P.-F.; Fu, D.-W.; Wang, Z.; Gao, S.; Yang, K.; Liu, J.-M.; Li, J.*; Yan, Y.*; Xiong, R.-G. * "An organic-inorganic perovskite ferroelectric with large piezoelectric response", Science 2017 , 357 (6348), 306-309. 52. Li, P.-F.; Liao, W.-Q.; Tang, Y.-Y.; Ye, H.-Y.; Zhang, Y.*; Xiong, R.-G. * "Unprecedented Ferroelectric-Antiferroelectric-Paraelectric Phase Transitions Discovered in an Organic-Inorganic Hybrid Perovskite", J. Am. Chem. Soc. 2017 , 139 (25), 8752-8757. 53. You, Y.-M.* Tang, Y.-Y.; Li, P.-F.; Zhang, H.-Y.; Zhang, W.-Y.; ferroelectric thin-film with duodecuple rotational polarization-directions", Nat. Commun. 2017 , 8 , 14934. 54. Pan, Q.; Liu, Z.-B.; Tang, Y.-Y.; Li, P.-F.; Ma, R.-W.; Wei, R.-Y.; Zhang, Y.; You, Y.-M.; Ye, H.-Y.*; Xiong, R.-G. * "A Three-Dimensional Molecular Perovskite Ferroelectric: (3-Ammoniopyrrolidinium)RbBr 3 ", J. Am. Chem. Soc. 2017 , 139 (11), 3954-3957. 55. Ye, H.-Y.; Liao, W.-Q.; Zhou, Q.; Zhang, Y.; Wang, J.; You, Y.-M.*; Wang, J.-Y.; Chen, Z.-N.; Li, P.-F.; Fu, D.-W.; Huang, S.-D.; Xiong, R.-G. * "Dielectric and ferroelectric sensing based on molecular recognition in Cu(1,10-phenlothroline) 2 SeO 4 · (diol) systems", Nat. Commun. 2017 , 8 , 14551. 56. Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Ye, H.-Y.*; Xiong, R.-G. * "De Novo Discovery of [Hdabco]BF 4 Molecular Ferroelectric Thin Film for Nonvolatile Low-Voltage Memories", J. Am. Chem. Soc. 2017 , 139 (3), 1319-1324. 57. Tang, Y.-Y.; Zhang, W.-Y.; Li, P.-F.; Ye, H.-Y.; You, Y.-M.*; Xiong, R.-G. * "Ultrafast Polarization Switching in a Biaxial Molecular Ferroelectric Thin Film: [Hdabco]ClO 4 ", J. Am. Chem. Soc. 2016 , 138 (48), 15784-15789. 58. Li, P.-F.; Tang, Y.-Y.; Wang, Z.-X.; Ye, H.-Y.*; You, Y.-M.; Xiong, R.-G. * "Anomalously rotary polarization discovered in homochiral organic ferroelectrics", Nat. Commun. 2016 , 7 , 13635. 59. Liao, W.-Q.; Zhao, D.*; Yu, Y.; Grice, C. R.; Wang, C.; Cimaroli, A. J.; Schulz, P.; Meng, W.; Zhu, K.; Xiong, R.-G. *; Yan, Y.* "Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22%", Adv. Mater. 2016 , 28 (42), 9333-9340. 60. Ye, H.-Y.*; Ge, J.-Z.; Tang, Y.-Y.; Li, P.-F.; Zhang, Y.; You, Y.-M.*; Xiong, R.-G. * "Molecular Ferroelectric with Most Equivalent Polarization Directions Induced by the Plastic Phase Transition", J. Am. Chem. Soc. 2016 , 138 (40), 13175-13178. 61. Liao, W.; Zhao, D.*; Yu, Y.; Shrestha, N.; Ghimire, K.; Grice, C. R.; Wang, C.; Xiao, Y.; Cimaroli, A. J.; Ellingson, R. J.; Podraza, N. J.; Zhu, K.; Xiong, R.-G. *; Yan, Y.* "Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide", J. Am. Chem. Soc. 2016 , 138 (38), 12360-12363. 62. Ye, H.-Y.; Liao, W.-Q.; Hu, C.-L.; Zhang, Y.; You, Y.-M.*; Mao, J.-G.; Li, P.-F.; Xiong, R.-G. * "Bandgap Engineering of Lead-Halide Perovskite-Type Ferroelectrics", Adv. Mater. 2016 , 28 (13), 2579-2586. 63. Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Wang, Z.-X.; Ye, Q.; Xiong, R.-G. * "Symmetry breaking in molecular ferroelectrics", Chem. Soc. Rev. 2016 , 45 (14), 3811-3827. 64. Ye, H.-Y.; Zhou, Q.; Niu, X.; Liao, W.-Q.; Fu, D.-W.; Zhang, Y.; You, Y.-M.*; Wang, J.*; Chen, Z.-N.; Xiong, R.-G. * "High-Temperature Ferroelectricity and Photoluminescence in a Hybrid Organic-Inorganic Compound: (3-Pyrrolinium)MnCl 3 ", J. Am. Chem. Soc. 2015 , 137 (40), 13148-13154. 65. Wu, J.; Fan, C.; Xue, G.; Ye, T.; Liu, S.; Lin, R.; Chen, H.; Xin, H.-L.; Xiong, R.-G. *; Li, H.* "Interfacing Solution-Grown C-60 and (3-Pyrrolinium)(CdCl 3 ) Single Crystals for High-Mobility Transistor-Based Memory Devices", Adv. Mater. 2015 , 27 (30), 4476-4480. 66. Zhang, Y.; Liao, W.-Q.; Fu, D.-W.; Ye, H.-Y.; Liu, C.-M.; Chen, Z.-N.; Xiong, R.-G. * "The First Organic-Inorganic Hybrid Luminescent Multiferroic: (Pyrrolidinium)MnBr 3 ", Adv. Mater. 2015 , 27 (26), 3942-3946. 67. Liao, W.-Q.; Zhang, Y.; Hu, C.-L.; Mao, J.-G.; Ye, H.-Y.; Li, P.-F.; Huang, S. D.; Xiong, R.-G. * "A lead-halide perovskite molecular ferroelectric semiconductor", Nat. Commun. 2015 , 6 , 7338. 68. Zhang, Y.; Liao, W.-Q.; Fu, D.-W.; Ye, H.-Y.; Chen, Z.-N.; Xiong, R.-G. * "Highly Efficient Red-Light Emission in An Organic-Inorganic Hybrid Ferroelectric: (Pyrrolidinium)MnCl 3 ", J. Am. Chem. Soc. 2015 , 137 (15), 4928-4931. 69. Ye, H.-Y.; Zhang, Y.; Fu, D.-W.; Xiong, R.-G. * " An Above-Room-Temperature Ferroelectric Organo-Metal Halide Perovskite: (3-Pyrrolinium)(CdCl 3 ) " , Angew. Chem. Int. Ed. 2014 , 53 (42), 11242-11247. 70. Ye, H.-Y.; Li, S.-H.; Zhang, Y.; Zhou, L.; Deng, F.; Xiong, R.-G. * " Solid State Molecular Dynamic Investigation of An Inclusion Ferroelectric: [(2,6-Diisopropylanilinium) ([18]crown-6)]BF 4 " , J. Am. Chem. Soc. 2014 , 136 (28), 10033-10040. 71. Zhang, Y.; Ye, H.-Y.; Cai, H.-L.; Fu, D.-W.; Ye, Q.; Zhang, W.; Zhou, Q.; Wang, J.; Yuan, G.-L.; Xiong, R.-G. * " Switchable Dielectric, Piezoelectric, and Second-Harmonic Generation Bistability in a New Improper Ferroelectric above Room Temperature " , Adv. Mater. 2014 , 26 (26), 4515-4516. 72. Ye, H.-Y.; Zhang, Y.; Fu, D.-W.; Xiong, R.-G. * " A Displacive-Type Metal Crown Ether Ferroelectric Compound: Ca(NO 3 ) 2 (15-crown-5) " , Angew. Chem. Int. Ed. 2014 , 53 (26), 6724-6729. 73. Zhang, Y.; Liu, Y.; Ye, H.-Y.; Fu, D.-W.; Gao, W.; Ma, H.; Liu, Z.; Liu, Y.; Zhang, W.; Li, J.; Yuan, G.-L.*; Xiong, R.-G. * " A Molecular Ferroelectric Thin Film of Imidazolium Perchlorate That Shows Superior Electromechanical Coupling " , Angew. Chem. Int. Ed. 2014 , 53 (20), 5064-5068. 74. Zhang, Y.; Ye, H.-Y.; Fu, D.-W.; Xiong, R.-G. * " An Order-Disorder Ferroelectric Host-Guest Inclusion Compound " , Angew. Chem. Int. Ed. 2014 , 53 (8), 2114-2118. 75. Fu, D.-W.; Cai, H.-L.; Li, S.-H.; Ye, Q.; Zhou, L.; Zhang, W.; Zhang, Y.; Deng, F.; Xiong, R.-G. * "4-Methoxyanilinium Perrhenate 18-Crown-6: A New Ferroelectric with Order Originating in Swinglike Motion Slowing Down", Phys. Rev. Lett. 2013 , 110 (25), 257601. 76. Fu, D.-W.; Cai, H.-L.; Liu, Y.; Ye, Q.; Zhang, W.; Zhang, Y.; Chen, X.-Y.; Giovannetti, G.; Capone, M.; Li, J.*; Xiong, R.-G. * "Diisopropylammonium Bromide Is a High-Temperature Molecular Ferroelectric Crystal", Science 2013 , 339 (6118), 425-428. 77. Zhang, W.*; Xiong, R.-G. * "Ferroelectric Metal Organic Frameworks", Chem. Rev. 2012 , 112 (2), 1163-1195. 78. Zhang, Y.; Zhang, W.*; Li, S.-H.*; Ye, Q.; Cai, H.-L.; Deng, F.*; Xiong, R.-G. *; Huang, S. D. "Ferroelectricity Induced by Ordering of Twisting Motion in a Molecular Rotor", J. Am. Chem. Soc . 2012 , 134 (26), 11044-11049. 79. Cai, H.-L.; Zhang, Y.; Fu, D.-W.; Zhang, W.; Liu, T.; Yoshikawa, H.; Awaga, K.; Xiong, R.-G. * "Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)", J. Am. Chem. Soc. 2012 , 134 (45), 18487-18490. 80. Cai , H.-L.; Fu , D.-W.; Zhang , Y.; Zhang , W.; Xiong , R.-G. * "Comment on "Ferroelectric Order of Parallel Bistable Hydrogen Bonds"", Phys. Rev. Lett. 2012 , 109 (15), 169601. 81. Fu, D.-W.; Zhang, W.*; Cai, H.-L.; Ge, J.-Z.; Zhang, Y.; Xiong, R.-G. * "Diisopropylammonium Chloride: A Ferroelectric Organic Salt with Highest Phase Transition Temperature and Practical Utilization Level Spontaneous Polarization", Adv. Mater. 2011 , 23 (47), 5658-5662. 82. Xu, G.-C.; Zhang, W.; Ma, X.-M.; Chen, Y.-H.; Zhang, L.; Cai, H.-L.; Wang, Z.-M.*; Xiong, R.-G. *; Gao S.* " Coexistence of Magnetic and Electric Orderings in the Metal-Formate Frameworks of [NH 4 ][M(HCOO) 3 ]", J. Am. Chem. Soc. 2011 , 133 (38), 14948-14951. 83. Cai, H.-L.; Zhang, W.*; Ge, J.-Z.; Zhang, Y.; Awaga, K.; Nakamura, T.; Xiong, R.-G. * "4-(cyanomethyl)anilinium Perchlorate: A New Displacive-Type Molecular Ferroelectric", Phys. Rev. Lett. 2011 , 107 (14), 147601. 84. Fu, D.-W.; Zhang, W.*; Cai, H.-L.; Zhang, Y.; Ge, J.-Z.; Xiong, R.-G. *; Huang, S. D. "Supramolecular Bola-Like Ferroelectrics: 4-Methoxyanilinium Tetrafluoroborate-18- Crown-6", J. Am. Chem. Soc. 2011 , 133 (32), 12780-12786. 85. Fu, D.-W.; Zhang, W.*; Cai, H.-L.; Zhang, Y.; Ge, J.-Z.; Xiong, R.-G. *; Huang, S. D.; Nakamura, T. " A Multiferroic Perdeutero Metal-Organic Framework " , Angew. Chem. Int. Ed. 2011 , 50 (50), 11947-11951. 86. 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